Bis(4′-chloro-2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)ruthenium(II) dichloride dihydrate

In the cation of the title compound, [Ru(C(15)H(10)ClN(3))(2)]Cl(2)·2H(2)O, the metal atom exhibits a distorted octa­hedral coordination geometry provided by the N atoms of two tridentate terpyridine ligands. The ligands are approximately planar [maximum deviation = 0.156 (5) Å] and form a dihedral...

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Detalles Bibliográficos
Autores principales: Wang, Ying, Jiao, Rui, Qiu, Xiang-Lei, Wang, Jian, Huang, Wei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379109/
https://www.ncbi.nlm.nih.gov/pubmed/22719330
http://dx.doi.org/10.1107/S1600536812021459
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author Wang, Ying
Jiao, Rui
Qiu, Xiang-Lei
Wang, Jian
Huang, Wei
author_facet Wang, Ying
Jiao, Rui
Qiu, Xiang-Lei
Wang, Jian
Huang, Wei
author_sort Wang, Ying
collection PubMed
description In the cation of the title compound, [Ru(C(15)H(10)ClN(3))(2)]Cl(2)·2H(2)O, the metal atom exhibits a distorted octa­hedral coordination geometry provided by the N atoms of two tridentate terpyridine ligands. The ligands are approximately planar [maximum deviation = 0.156 (5) Å] and form a dihedral angle of 87.0 (3)°. In the crystal, the cations, anions and water mol­ecules are linked into a three-dimensional network by C—H⋯Cl, C—H⋯O and O—H⋯Cl hydrogen bonds.
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spelling pubmed-33791092012-06-20 Bis(4′-chloro-2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)ruthenium(II) dichloride dihydrate Wang, Ying Jiao, Rui Qiu, Xiang-Lei Wang, Jian Huang, Wei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the cation of the title compound, [Ru(C(15)H(10)ClN(3))(2)]Cl(2)·2H(2)O, the metal atom exhibits a distorted octa­hedral coordination geometry provided by the N atoms of two tridentate terpyridine ligands. The ligands are approximately planar [maximum deviation = 0.156 (5) Å] and form a dihedral angle of 87.0 (3)°. In the crystal, the cations, anions and water mol­ecules are linked into a three-dimensional network by C—H⋯Cl, C—H⋯O and O—H⋯Cl hydrogen bonds. International Union of Crystallography 2012-05-16 /pmc/articles/PMC3379109/ /pubmed/22719330 http://dx.doi.org/10.1107/S1600536812021459 Text en © Wang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Ying
Jiao, Rui
Qiu, Xiang-Lei
Wang, Jian
Huang, Wei
Bis(4′-chloro-2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)ruthenium(II) dichloride dihydrate
title Bis(4′-chloro-2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)ruthenium(II) dichloride dihydrate
title_full Bis(4′-chloro-2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)ruthenium(II) dichloride dihydrate
title_fullStr Bis(4′-chloro-2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)ruthenium(II) dichloride dihydrate
title_full_unstemmed Bis(4′-chloro-2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)ruthenium(II) dichloride dihydrate
title_short Bis(4′-chloro-2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)ruthenium(II) dichloride dihydrate
title_sort bis(4′-chloro-2,2′:6′,2′′-terpyridine-κ(3) n,n′,n′′)ruthenium(ii) dichloride dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379109/
https://www.ncbi.nlm.nih.gov/pubmed/22719330
http://dx.doi.org/10.1107/S1600536812021459
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