Tris(2-acetyl­cyclo­pentan-1-onato-κ(2) O,O′)aluminium

In the title compound, [Al(C(7)H(9)O(2))(3)], the Al(III) cation is coordinated by six O atoms from three 2-acetyl­cyclo­penta­nonate ligands in a slightly distorted octa­hedral environment, with Al—O bond lengths in the range 1.882 (2)–1.896 (2) Å. In the crystal, mol­ecules are linked together via...

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Detalles Bibliográficos
Autor principal: Perdih, Franc
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379111/
https://www.ncbi.nlm.nih.gov/pubmed/22719332
http://dx.doi.org/10.1107/S1600536812021848
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author Perdih, Franc
author_facet Perdih, Franc
author_sort Perdih, Franc
collection PubMed
description In the title compound, [Al(C(7)H(9)O(2))(3)], the Al(III) cation is coordinated by six O atoms from three 2-acetyl­cyclo­penta­nonate ligands in a slightly distorted octa­hedral environment, with Al—O bond lengths in the range 1.882 (2)–1.896 (2) Å. In the crystal, mol­ecules are linked together via C—H⋯O inter­actions. One of the C atoms in one ring has a large thermal motion compared to the other atoms, indicating some possible disorder. However, the treatment of this C atom as disordered over two positions did not give a significant improvement.
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spelling pubmed-33791112012-06-20 Tris(2-acetyl­cyclo­pentan-1-onato-κ(2) O,O′)aluminium Perdih, Franc Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Al(C(7)H(9)O(2))(3)], the Al(III) cation is coordinated by six O atoms from three 2-acetyl­cyclo­penta­nonate ligands in a slightly distorted octa­hedral environment, with Al—O bond lengths in the range 1.882 (2)–1.896 (2) Å. In the crystal, mol­ecules are linked together via C—H⋯O inter­actions. One of the C atoms in one ring has a large thermal motion compared to the other atoms, indicating some possible disorder. However, the treatment of this C atom as disordered over two positions did not give a significant improvement. International Union of Crystallography 2012-05-19 /pmc/articles/PMC3379111/ /pubmed/22719332 http://dx.doi.org/10.1107/S1600536812021848 Text en © Franc Perdih 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Perdih, Franc
Tris(2-acetyl­cyclo­pentan-1-onato-κ(2) O,O′)aluminium
title Tris(2-acetyl­cyclo­pentan-1-onato-κ(2) O,O′)aluminium
title_full Tris(2-acetyl­cyclo­pentan-1-onato-κ(2) O,O′)aluminium
title_fullStr Tris(2-acetyl­cyclo­pentan-1-onato-κ(2) O,O′)aluminium
title_full_unstemmed Tris(2-acetyl­cyclo­pentan-1-onato-κ(2) O,O′)aluminium
title_short Tris(2-acetyl­cyclo­pentan-1-onato-κ(2) O,O′)aluminium
title_sort tris(2-acetyl­cyclo­pentan-1-onato-κ(2) o,o′)aluminium
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379111/
https://www.ncbi.nlm.nih.gov/pubmed/22719332
http://dx.doi.org/10.1107/S1600536812021848
work_keys_str_mv AT perdihfranc tris2acetylcyclopentan1onatok2ooaluminium

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