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Di-μ-hydroxido-bis­[hemiaqua­(N,N,N′,N′-tetra­methyl­ethane-1,2-diamine)­copper(II)] bis­(tetra­fluoridoborate)

The title compound, [Cu(2)(OH)(2)(C(6)H(16)N(2))(2)(H(2)O)](BF(4))(2), consists of dinuclear centrosymmetric [Cu(2)(OH)(2)(tmen)(2)(H(2)O)](2+) complex cations (tmen = N,N,N′,N′-tetra­methyl­ethane-1,2-diamine) and tetra­fluoridoborate anions. In the cation, the Cu(II) atom shows a slightly distorte...

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Autores principales: Haníková, Jaroslava, Kuchár, Juraj, Trávníček, Zdeněk, Černák, Juraj
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379114/
https://www.ncbi.nlm.nih.gov/pubmed/22719335
http://dx.doi.org/10.1107/S1600536812021836
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author Haníková, Jaroslava
Kuchár, Juraj
Trávníček, Zdeněk
Černák, Juraj
author_facet Haníková, Jaroslava
Kuchár, Juraj
Trávníček, Zdeněk
Černák, Juraj
author_sort Haníková, Jaroslava
collection PubMed
description The title compound, [Cu(2)(OH)(2)(C(6)H(16)N(2))(2)(H(2)O)](BF(4))(2), consists of dinuclear centrosymmetric [Cu(2)(OH)(2)(tmen)(2)(H(2)O)](2+) complex cations (tmen = N,N,N′,N′-tetra­methyl­ethane-1,2-diamine) and tetra­fluoridoborate anions. In the cation, the Cu(II) atom shows a slightly distorted square-pyramidal coordination geometry provided by a pair of μ-OH(−) anions and by the N atoms of a chelate tmen ligand in the basal plane. The apical position is statistically occupied by the O atom of a half-occupancy water mol­ecule. The F atoms of the anion are disordered over three sets of sites with occupancies of 0.598 (9):0.269 (6):0.134 (8). The crystal packing is governed by ionic forces as well as by O—H⋯F hydrogen bonds.
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spelling pubmed-33791142012-06-20 Di-μ-hydroxido-bis­[hemiaqua­(N,N,N′,N′-tetra­methyl­ethane-1,2-diamine)­copper(II)] bis­(tetra­fluoridoborate) Haníková, Jaroslava Kuchár, Juraj Trávníček, Zdeněk Černák, Juraj Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cu(2)(OH)(2)(C(6)H(16)N(2))(2)(H(2)O)](BF(4))(2), consists of dinuclear centrosymmetric [Cu(2)(OH)(2)(tmen)(2)(H(2)O)](2+) complex cations (tmen = N,N,N′,N′-tetra­methyl­ethane-1,2-diamine) and tetra­fluoridoborate anions. In the cation, the Cu(II) atom shows a slightly distorted square-pyramidal coordination geometry provided by a pair of μ-OH(−) anions and by the N atoms of a chelate tmen ligand in the basal plane. The apical position is statistically occupied by the O atom of a half-occupancy water mol­ecule. The F atoms of the anion are disordered over three sets of sites with occupancies of 0.598 (9):0.269 (6):0.134 (8). The crystal packing is governed by ionic forces as well as by O—H⋯F hydrogen bonds. International Union of Crystallography 2012-05-19 /pmc/articles/PMC3379114/ /pubmed/22719335 http://dx.doi.org/10.1107/S1600536812021836 Text en © Haníková et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Haníková, Jaroslava
Kuchár, Juraj
Trávníček, Zdeněk
Černák, Juraj
Di-μ-hydroxido-bis­[hemiaqua­(N,N,N′,N′-tetra­methyl­ethane-1,2-diamine)­copper(II)] bis­(tetra­fluoridoborate)
title Di-μ-hydroxido-bis­[hemiaqua­(N,N,N′,N′-tetra­methyl­ethane-1,2-diamine)­copper(II)] bis­(tetra­fluoridoborate)
title_full Di-μ-hydroxido-bis­[hemiaqua­(N,N,N′,N′-tetra­methyl­ethane-1,2-diamine)­copper(II)] bis­(tetra­fluoridoborate)
title_fullStr Di-μ-hydroxido-bis­[hemiaqua­(N,N,N′,N′-tetra­methyl­ethane-1,2-diamine)­copper(II)] bis­(tetra­fluoridoborate)
title_full_unstemmed Di-μ-hydroxido-bis­[hemiaqua­(N,N,N′,N′-tetra­methyl­ethane-1,2-diamine)­copper(II)] bis­(tetra­fluoridoborate)
title_short Di-μ-hydroxido-bis­[hemiaqua­(N,N,N′,N′-tetra­methyl­ethane-1,2-diamine)­copper(II)] bis­(tetra­fluoridoborate)
title_sort di-μ-hydroxido-bis­[hemiaqua­(n,n,n′,n′-tetra­methyl­ethane-1,2-diamine)­copper(ii)] bis­(tetra­fluoridoborate)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379114/
https://www.ncbi.nlm.nih.gov/pubmed/22719335
http://dx.doi.org/10.1107/S1600536812021836
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