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Di-μ-hydroxido-bis[hemiaqua(N,N,N′,N′-tetramethylethane-1,2-diamine)copper(II)] bis(tetrafluoridoborate)
The title compound, [Cu(2)(OH)(2)(C(6)H(16)N(2))(2)(H(2)O)](BF(4))(2), consists of dinuclear centrosymmetric [Cu(2)(OH)(2)(tmen)(2)(H(2)O)](2+) complex cations (tmen = N,N,N′,N′-tetramethylethane-1,2-diamine) and tetrafluoridoborate anions. In the cation, the Cu(II) atom shows a slightly distorte...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379114/ https://www.ncbi.nlm.nih.gov/pubmed/22719335 http://dx.doi.org/10.1107/S1600536812021836 |
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author | Haníková, Jaroslava Kuchár, Juraj Trávníček, Zdeněk Černák, Juraj |
author_facet | Haníková, Jaroslava Kuchár, Juraj Trávníček, Zdeněk Černák, Juraj |
author_sort | Haníková, Jaroslava |
collection | PubMed |
description | The title compound, [Cu(2)(OH)(2)(C(6)H(16)N(2))(2)(H(2)O)](BF(4))(2), consists of dinuclear centrosymmetric [Cu(2)(OH)(2)(tmen)(2)(H(2)O)](2+) complex cations (tmen = N,N,N′,N′-tetramethylethane-1,2-diamine) and tetrafluoridoborate anions. In the cation, the Cu(II) atom shows a slightly distorted square-pyramidal coordination geometry provided by a pair of μ-OH(−) anions and by the N atoms of a chelate tmen ligand in the basal plane. The apical position is statistically occupied by the O atom of a half-occupancy water molecule. The F atoms of the anion are disordered over three sets of sites with occupancies of 0.598 (9):0.269 (6):0.134 (8). The crystal packing is governed by ionic forces as well as by O—H⋯F hydrogen bonds. |
format | Online Article Text |
id | pubmed-3379114 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33791142012-06-20 Di-μ-hydroxido-bis[hemiaqua(N,N,N′,N′-tetramethylethane-1,2-diamine)copper(II)] bis(tetrafluoridoborate) Haníková, Jaroslava Kuchár, Juraj Trávníček, Zdeněk Černák, Juraj Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cu(2)(OH)(2)(C(6)H(16)N(2))(2)(H(2)O)](BF(4))(2), consists of dinuclear centrosymmetric [Cu(2)(OH)(2)(tmen)(2)(H(2)O)](2+) complex cations (tmen = N,N,N′,N′-tetramethylethane-1,2-diamine) and tetrafluoridoborate anions. In the cation, the Cu(II) atom shows a slightly distorted square-pyramidal coordination geometry provided by a pair of μ-OH(−) anions and by the N atoms of a chelate tmen ligand in the basal plane. The apical position is statistically occupied by the O atom of a half-occupancy water molecule. The F atoms of the anion are disordered over three sets of sites with occupancies of 0.598 (9):0.269 (6):0.134 (8). The crystal packing is governed by ionic forces as well as by O—H⋯F hydrogen bonds. International Union of Crystallography 2012-05-19 /pmc/articles/PMC3379114/ /pubmed/22719335 http://dx.doi.org/10.1107/S1600536812021836 Text en © Haníková et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Haníková, Jaroslava Kuchár, Juraj Trávníček, Zdeněk Černák, Juraj Di-μ-hydroxido-bis[hemiaqua(N,N,N′,N′-tetramethylethane-1,2-diamine)copper(II)] bis(tetrafluoridoborate) |
title | Di-μ-hydroxido-bis[hemiaqua(N,N,N′,N′-tetramethylethane-1,2-diamine)copper(II)] bis(tetrafluoridoborate) |
title_full | Di-μ-hydroxido-bis[hemiaqua(N,N,N′,N′-tetramethylethane-1,2-diamine)copper(II)] bis(tetrafluoridoborate) |
title_fullStr | Di-μ-hydroxido-bis[hemiaqua(N,N,N′,N′-tetramethylethane-1,2-diamine)copper(II)] bis(tetrafluoridoborate) |
title_full_unstemmed | Di-μ-hydroxido-bis[hemiaqua(N,N,N′,N′-tetramethylethane-1,2-diamine)copper(II)] bis(tetrafluoridoborate) |
title_short | Di-μ-hydroxido-bis[hemiaqua(N,N,N′,N′-tetramethylethane-1,2-diamine)copper(II)] bis(tetrafluoridoborate) |
title_sort | di-μ-hydroxido-bis[hemiaqua(n,n,n′,n′-tetramethylethane-1,2-diamine)copper(ii)] bis(tetrafluoridoborate) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379114/ https://www.ncbi.nlm.nih.gov/pubmed/22719335 http://dx.doi.org/10.1107/S1600536812021836 |
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