Dibromidobis[1-(2-bromo­benz­yl)-3-(pyrimidin-2-yl)-1H-imidazol-2(3H)-one]copper(II)

In the title complex, [CuBr(2)(C(14)H(11)BrN(4)O)(2)], the Cu(II) ion is located on an inversion centre and is coordinated by two ketonic O atoms, two N atoms and two Br atoms, forming a distorted octahedral coordination environment. The two carbonyl groups are trans positioned with C=O bond lengths...

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Detalles Bibliográficos
Autor principal: Lu, Chun-Xin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379115/
https://www.ncbi.nlm.nih.gov/pubmed/22719336
http://dx.doi.org/10.1107/S1600536812021460
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author Lu, Chun-Xin
author_facet Lu, Chun-Xin
author_sort Lu, Chun-Xin
collection PubMed
description In the title complex, [CuBr(2)(C(14)H(11)BrN(4)O)(2)], the Cu(II) ion is located on an inversion centre and is coordinated by two ketonic O atoms, two N atoms and two Br atoms, forming a distorted octahedral coordination environment. The two carbonyl groups are trans positioned with C=O bond lengths of 1.256 (5) Å, in agreement with a classical carbonyl bond. The Cu—O bond length is 2.011 (3) Å. The two bromo­benzyl rings are approximately parallel to one another, forming a dihedral angle of 70.1 (4)° with the coordination plane.
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spelling pubmed-33791152012-06-20 Dibromidobis[1-(2-bromo­benz­yl)-3-(pyrimidin-2-yl)-1H-imidazol-2(3H)-one]copper(II) Lu, Chun-Xin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [CuBr(2)(C(14)H(11)BrN(4)O)(2)], the Cu(II) ion is located on an inversion centre and is coordinated by two ketonic O atoms, two N atoms and two Br atoms, forming a distorted octahedral coordination environment. The two carbonyl groups are trans positioned with C=O bond lengths of 1.256 (5) Å, in agreement with a classical carbonyl bond. The Cu—O bond length is 2.011 (3) Å. The two bromo­benzyl rings are approximately parallel to one another, forming a dihedral angle of 70.1 (4)° with the coordination plane. International Union of Crystallography 2012-05-19 /pmc/articles/PMC3379115/ /pubmed/22719336 http://dx.doi.org/10.1107/S1600536812021460 Text en © Chun-Xin Lu 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Lu, Chun-Xin
Dibromidobis[1-(2-bromo­benz­yl)-3-(pyrimidin-2-yl)-1H-imidazol-2(3H)-one]copper(II)
title Dibromidobis[1-(2-bromo­benz­yl)-3-(pyrimidin-2-yl)-1H-imidazol-2(3H)-one]copper(II)
title_full Dibromidobis[1-(2-bromo­benz­yl)-3-(pyrimidin-2-yl)-1H-imidazol-2(3H)-one]copper(II)
title_fullStr Dibromidobis[1-(2-bromo­benz­yl)-3-(pyrimidin-2-yl)-1H-imidazol-2(3H)-one]copper(II)
title_full_unstemmed Dibromidobis[1-(2-bromo­benz­yl)-3-(pyrimidin-2-yl)-1H-imidazol-2(3H)-one]copper(II)
title_short Dibromidobis[1-(2-bromo­benz­yl)-3-(pyrimidin-2-yl)-1H-imidazol-2(3H)-one]copper(II)
title_sort dibromidobis[1-(2-bromo­benz­yl)-3-(pyrimidin-2-yl)-1h-imidazol-2(3h)-one]copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379115/
https://www.ncbi.nlm.nih.gov/pubmed/22719336
http://dx.doi.org/10.1107/S1600536812021460
work_keys_str_mv AT luchunxin dibromidobis12bromobenzyl3pyrimidin2yl1himidazol23honecopperii

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