Dichloridobis[ethyl 2-(2-amino-1,3-thia­zol-4-yl)acetate-κ(2) O,N (3)]cadmium

The asymmetric unit of the title compound, [CdCl(2)(C(7)H(10)N(2)O(2)S)(2)], contains two complex molecules with similar configurations. The Cd(II) atoms are each six-coordinated by two thiazole N and two carbonyl O atoms from the 2-(2-amino-1,3-thiazol-4-yl)acetate ligand, and by two Cl(−) anions i...

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Autores principales: Zhang, Lai-Jun, Chen, Fa-Yun, Liu, Guang-Yi, Chen, Xiao, Chen, Zhi-Feng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379118/
https://www.ncbi.nlm.nih.gov/pubmed/22719339
http://dx.doi.org/10.1107/S1600536812021976
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author Zhang, Lai-Jun
Chen, Fa-Yun
Liu, Guang-Yi
Chen, Xiao
Chen, Zhi-Feng
author_facet Zhang, Lai-Jun
Chen, Fa-Yun
Liu, Guang-Yi
Chen, Xiao
Chen, Zhi-Feng
author_sort Zhang, Lai-Jun
collection PubMed
description The asymmetric unit of the title compound, [CdCl(2)(C(7)H(10)N(2)O(2)S)(2)], contains two complex molecules with similar configurations. The Cd(II) atoms are each six-coordinated by two thiazole N and two carbonyl O atoms from the 2-(2-amino-1,3-thiazol-4-yl)acetate ligand, and by two Cl(−) anions in a distorted octa­hedral geometry. In the crystal, intra- and inter­molecular N—H⋯Cl hydrogen bonds create parallel chains along [1-10]. C—H⋯Cl inter­actions also occur.
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spelling pubmed-33791182012-06-20 Dichloridobis[ethyl 2-(2-amino-1,3-thia­zol-4-yl)acetate-κ(2) O,N (3)]cadmium Zhang, Lai-Jun Chen, Fa-Yun Liu, Guang-Yi Chen, Xiao Chen, Zhi-Feng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [CdCl(2)(C(7)H(10)N(2)O(2)S)(2)], contains two complex molecules with similar configurations. The Cd(II) atoms are each six-coordinated by two thiazole N and two carbonyl O atoms from the 2-(2-amino-1,3-thiazol-4-yl)acetate ligand, and by two Cl(−) anions in a distorted octa­hedral geometry. In the crystal, intra- and inter­molecular N—H⋯Cl hydrogen bonds create parallel chains along [1-10]. C—H⋯Cl inter­actions also occur. International Union of Crystallography 2012-05-26 /pmc/articles/PMC3379118/ /pubmed/22719339 http://dx.doi.org/10.1107/S1600536812021976 Text en © Zhang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Lai-Jun
Chen, Fa-Yun
Liu, Guang-Yi
Chen, Xiao
Chen, Zhi-Feng
Dichloridobis[ethyl 2-(2-amino-1,3-thia­zol-4-yl)acetate-κ(2) O,N (3)]cadmium
title Dichloridobis[ethyl 2-(2-amino-1,3-thia­zol-4-yl)acetate-κ(2) O,N (3)]cadmium
title_full Dichloridobis[ethyl 2-(2-amino-1,3-thia­zol-4-yl)acetate-κ(2) O,N (3)]cadmium
title_fullStr Dichloridobis[ethyl 2-(2-amino-1,3-thia­zol-4-yl)acetate-κ(2) O,N (3)]cadmium
title_full_unstemmed Dichloridobis[ethyl 2-(2-amino-1,3-thia­zol-4-yl)acetate-κ(2) O,N (3)]cadmium
title_short Dichloridobis[ethyl 2-(2-amino-1,3-thia­zol-4-yl)acetate-κ(2) O,N (3)]cadmium
title_sort dichloridobis[ethyl 2-(2-amino-1,3-thia­zol-4-yl)acetate-κ(2) o,n (3)]cadmium
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379118/
https://www.ncbi.nlm.nih.gov/pubmed/22719339
http://dx.doi.org/10.1107/S1600536812021976
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