[4-(Dimethyl­amino)­pyridine-κN (1)]tri­methyl(thio­cyanato-κN)tin(IV)

In the title monomeric trimethyl­tin(IV) isothio­cyanate–4,4-dimethyl­pyridine adduct, [Sn(CH(3))(3)(NCS)(C(7)H(10)N(2))], the Sn(IV) atom shows a trans-C(3)SnN(2) trigonal bipyramidal coordination. The Sn(IV) atom lies out of the equatorial plane by 0.033 (4) Å in the direction of the donor N atom...

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Detalles Bibliográficos
Autores principales: Najafi, Ezzatollah, Amini, Mostafa M., Ng, Seik Weng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379119/
https://www.ncbi.nlm.nih.gov/pubmed/22719340
http://dx.doi.org/10.1107/S1600536812022064
Descripción
Sumario:In the title monomeric trimethyl­tin(IV) isothio­cyanate–4,4-dimethyl­pyridine adduct, [Sn(CH(3))(3)(NCS)(C(7)H(10)N(2))], the Sn(IV) atom shows a trans-C(3)SnN(2) trigonal bipyramidal coordination. The Sn(IV) atom lies out of the equatorial plane by 0.033 (4) Å in the direction of the donor N atom of the N-heterocycle. The crystal studied was a non-merohedral twin with a minor component of 48.8 (2)%.

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