[4-(Dimethyl­amino)­pyridine-κN (1)]tri­methyl(thio­cyanato-κN)tin(IV)

In the title monomeric trimethyl­tin(IV) isothio­cyanate–4,4-dimethyl­pyridine adduct, [Sn(CH(3))(3)(NCS)(C(7)H(10)N(2))], the Sn(IV) atom shows a trans-C(3)SnN(2) trigonal bipyramidal coordination. The Sn(IV) atom lies out of the equatorial plane by 0.033 (4) Å in the direction of the donor N atom...

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Detalles Bibliográficos
Autores principales: Najafi, Ezzatollah, Amini, Mostafa M., Ng, Seik Weng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379119/
https://www.ncbi.nlm.nih.gov/pubmed/22719340
http://dx.doi.org/10.1107/S1600536812022064
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author Najafi, Ezzatollah
Amini, Mostafa M.
Ng, Seik Weng
author_facet Najafi, Ezzatollah
Amini, Mostafa M.
Ng, Seik Weng
author_sort Najafi, Ezzatollah
collection PubMed
description In the title monomeric trimethyl­tin(IV) isothio­cyanate–4,4-dimethyl­pyridine adduct, [Sn(CH(3))(3)(NCS)(C(7)H(10)N(2))], the Sn(IV) atom shows a trans-C(3)SnN(2) trigonal bipyramidal coordination. The Sn(IV) atom lies out of the equatorial plane by 0.033 (4) Å in the direction of the donor N atom of the N-heterocycle. The crystal studied was a non-merohedral twin with a minor component of 48.8 (2)%.
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spelling pubmed-33791192012-06-20 [4-(Dimethyl­amino)­pyridine-κN (1)]tri­methyl(thio­cyanato-κN)tin(IV) Najafi, Ezzatollah Amini, Mostafa M. Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title monomeric trimethyl­tin(IV) isothio­cyanate–4,4-dimethyl­pyridine adduct, [Sn(CH(3))(3)(NCS)(C(7)H(10)N(2))], the Sn(IV) atom shows a trans-C(3)SnN(2) trigonal bipyramidal coordination. The Sn(IV) atom lies out of the equatorial plane by 0.033 (4) Å in the direction of the donor N atom of the N-heterocycle. The crystal studied was a non-merohedral twin with a minor component of 48.8 (2)%. International Union of Crystallography 2012-05-26 /pmc/articles/PMC3379119/ /pubmed/22719340 http://dx.doi.org/10.1107/S1600536812022064 Text en © Najafi et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Najafi, Ezzatollah
Amini, Mostafa M.
Ng, Seik Weng
[4-(Dimethyl­amino)­pyridine-κN (1)]tri­methyl(thio­cyanato-κN)tin(IV)
title [4-(Dimethyl­amino)­pyridine-κN (1)]tri­methyl(thio­cyanato-κN)tin(IV)
title_full [4-(Dimethyl­amino)­pyridine-κN (1)]tri­methyl(thio­cyanato-κN)tin(IV)
title_fullStr [4-(Dimethyl­amino)­pyridine-κN (1)]tri­methyl(thio­cyanato-κN)tin(IV)
title_full_unstemmed [4-(Dimethyl­amino)­pyridine-κN (1)]tri­methyl(thio­cyanato-κN)tin(IV)
title_short [4-(Dimethyl­amino)­pyridine-κN (1)]tri­methyl(thio­cyanato-κN)tin(IV)
title_sort [4-(dimethyl­amino)­pyridine-κn (1)]tri­methyl(thio­cyanato-κn)tin(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379119/
https://www.ncbi.nlm.nih.gov/pubmed/22719340
http://dx.doi.org/10.1107/S1600536812022064
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