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A second triclinic polymorph of bis(μ-N-nitroso-N-phenylhydroxylaminato)-κ(3) O,O′:O′;κ(3) O′:O,O′-bis[(N-nitroso-N-phenylhydroxylaminato-κ(2) O,O′)lead(II)]
The cupferronate ions in the centrosymmetric dinuclear title compound, [Pb(2)(C(6)H(5)N(2)O(2))(4)], O,O′-chelate to the two Pb(II) atoms; two of the four nitroso O atoms are also involved in bridging. The geometries of the five-coordinate Pb(II) atoms in the two independent molecules are Ψ-octahe...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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International Union of Crystallography
2012
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379120/ https://www.ncbi.nlm.nih.gov/pubmed/22719341 http://dx.doi.org/10.1107/S1600536812021885 |
| _version_ | 1782236130617327616 |
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| author | Najafi, Ezzatollah Amini, Mostafa M. Ng, Seik Weng |
| author_facet | Najafi, Ezzatollah Amini, Mostafa M. Ng, Seik Weng |
| author_sort | Najafi, Ezzatollah |
| collection | PubMed |
| description | The cupferronate ions in the centrosymmetric dinuclear title compound, [Pb(2)(C(6)H(5)N(2)O(2))(4)], O,O′-chelate to the two Pb(II) atoms; two of the four nitroso O atoms are also involved in bridging. The geometries of the five-coordinate Pb(II) atoms in the two independent molecules are Ψ-octahedral; if more remote Pb⋯O interactions are also considered, the coordination number is increased to six for one molecule and to seven for the other. Their coordination polyhedra are ill defined in the chain motif, which runs along [100]. |
| format | Online Article Text |
| id | pubmed-3379120 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-33791202012-06-20 A second triclinic polymorph of bis(μ-N-nitroso-N-phenylhydroxylaminato)-κ(3) O,O′:O′;κ(3) O′:O,O′-bis[(N-nitroso-N-phenylhydroxylaminato-κ(2) O,O′)lead(II)] Najafi, Ezzatollah Amini, Mostafa M. Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The cupferronate ions in the centrosymmetric dinuclear title compound, [Pb(2)(C(6)H(5)N(2)O(2))(4)], O,O′-chelate to the two Pb(II) atoms; two of the four nitroso O atoms are also involved in bridging. The geometries of the five-coordinate Pb(II) atoms in the two independent molecules are Ψ-octahedral; if more remote Pb⋯O interactions are also considered, the coordination number is increased to six for one molecule and to seven for the other. Their coordination polyhedra are ill defined in the chain motif, which runs along [100]. International Union of Crystallography 2012-05-26 /pmc/articles/PMC3379120/ /pubmed/22719341 http://dx.doi.org/10.1107/S1600536812021885 Text en © Najafi et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Najafi, Ezzatollah Amini, Mostafa M. Ng, Seik Weng A second triclinic polymorph of bis(μ-N-nitroso-N-phenylhydroxylaminato)-κ(3) O,O′:O′;κ(3) O′:O,O′-bis[(N-nitroso-N-phenylhydroxylaminato-κ(2) O,O′)lead(II)] |
| title | A second triclinic polymorph of bis(μ-N-nitroso-N-phenylhydroxylaminato)-κ(3)
O,O′:O′;κ(3)
O′:O,O′-bis[(N-nitroso-N-phenylhydroxylaminato-κ(2)
O,O′)lead(II)] |
| title_full | A second triclinic polymorph of bis(μ-N-nitroso-N-phenylhydroxylaminato)-κ(3)
O,O′:O′;κ(3)
O′:O,O′-bis[(N-nitroso-N-phenylhydroxylaminato-κ(2)
O,O′)lead(II)] |
| title_fullStr | A second triclinic polymorph of bis(μ-N-nitroso-N-phenylhydroxylaminato)-κ(3)
O,O′:O′;κ(3)
O′:O,O′-bis[(N-nitroso-N-phenylhydroxylaminato-κ(2)
O,O′)lead(II)] |
| title_full_unstemmed | A second triclinic polymorph of bis(μ-N-nitroso-N-phenylhydroxylaminato)-κ(3)
O,O′:O′;κ(3)
O′:O,O′-bis[(N-nitroso-N-phenylhydroxylaminato-κ(2)
O,O′)lead(II)] |
| title_short | A second triclinic polymorph of bis(μ-N-nitroso-N-phenylhydroxylaminato)-κ(3)
O,O′:O′;κ(3)
O′:O,O′-bis[(N-nitroso-N-phenylhydroxylaminato-κ(2)
O,O′)lead(II)] |
| title_sort | second triclinic polymorph of bis(μ-n-nitroso-n-phenylhydroxylaminato)-κ(3)
o,o′:o′;κ(3)
o′:o,o′-bis[(n-nitroso-n-phenylhydroxylaminato-κ(2)
o,o′)lead(ii)] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379120/ https://www.ncbi.nlm.nih.gov/pubmed/22719341 http://dx.doi.org/10.1107/S1600536812021885 |
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