(2,2′-Bipyridine-κ(2) N,N′){N-[(2-oxidonaphthalen-1-yl-κO)methyl­idene]-l-valinato-κO}copper(II) trihydrate

In the title complex, [Cu(C(16)H(15)NO(3))(C(10)H(8)N(2))]·3H(2)O, the Cu(II) atom is five coordinated by O,N,O′-donor atoms of the Schiff base ligand and by two N atoms of the 2,2′-bipyridine ligand in a distorted square-pyramidal geometry. In the crystal, mol­ecules are linked into a two-dimension...

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Detalles Bibliográficos
Autores principales: Zuo, Jian, Bi, Caifeng, Fan, Yuhua, Zhang, Nan, Zhang, Pengfei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379121/
https://www.ncbi.nlm.nih.gov/pubmed/22719342
http://dx.doi.org/10.1107/S1600536812022702
Descripción
Sumario:In the title complex, [Cu(C(16)H(15)NO(3))(C(10)H(8)N(2))]·3H(2)O, the Cu(II) atom is five coordinated by O,N,O′-donor atoms of the Schiff base ligand and by two N atoms of the 2,2′-bipyridine ligand in a distorted square-pyramidal geometry. In the crystal, mol­ecules are linked into a two-dimensional network parallel to (011) by O—H⋯O hydrogen bonds.

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