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Tetrakis(pyridazine-κN)bis(thiocyanato-κN)nickel(II) pyridazine disolvate
The reaction of nickel(II) thiocyanate with an excess of pyridazine leads to single crystals of the title compound, [Ni(NCS)(2)(C(4)H(4)N(2))(4)]·2C(4)H(4)N(2). The Ni(II) cations are coordinated by two terminal N-bonded thiocyanate anions (trans) and four pyridazine ligands in a slightly distorte...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379122/ https://www.ncbi.nlm.nih.gov/pubmed/22719343 http://dx.doi.org/10.1107/S1600536812023306 |
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author | Wöhlert, Susanne Wriedt, Mario Jess, Inke Näther, Christian |
author_facet | Wöhlert, Susanne Wriedt, Mario Jess, Inke Näther, Christian |
author_sort | Wöhlert, Susanne |
collection | PubMed |
description | The reaction of nickel(II) thiocyanate with an excess of pyridazine leads to single crystals of the title compound, [Ni(NCS)(2)(C(4)H(4)N(2))(4)]·2C(4)H(4)N(2). The Ni(II) cations are coordinated by two terminal N-bonded thiocyanate anions (trans) and four pyridazine ligands in a slightly distorted octahedral geometry. The discrete complexes are arranged into layers parallel to the ab plane which are separated by additional non-coordinated pyridazine ligands. |
format | Online Article Text |
id | pubmed-3379122 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33791222012-06-20 Tetrakis(pyridazine-κN)bis(thiocyanato-κN)nickel(II) pyridazine disolvate Wöhlert, Susanne Wriedt, Mario Jess, Inke Näther, Christian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The reaction of nickel(II) thiocyanate with an excess of pyridazine leads to single crystals of the title compound, [Ni(NCS)(2)(C(4)H(4)N(2))(4)]·2C(4)H(4)N(2). The Ni(II) cations are coordinated by two terminal N-bonded thiocyanate anions (trans) and four pyridazine ligands in a slightly distorted octahedral geometry. The discrete complexes are arranged into layers parallel to the ab plane which are separated by additional non-coordinated pyridazine ligands. International Union of Crystallography 2012-05-26 /pmc/articles/PMC3379122/ /pubmed/22719343 http://dx.doi.org/10.1107/S1600536812023306 Text en © Wöhlert et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Wöhlert, Susanne Wriedt, Mario Jess, Inke Näther, Christian Tetrakis(pyridazine-κN)bis(thiocyanato-κN)nickel(II) pyridazine disolvate |
title | Tetrakis(pyridazine-κN)bis(thiocyanato-κN)nickel(II) pyridazine disolvate |
title_full | Tetrakis(pyridazine-κN)bis(thiocyanato-κN)nickel(II) pyridazine disolvate |
title_fullStr | Tetrakis(pyridazine-κN)bis(thiocyanato-κN)nickel(II) pyridazine disolvate |
title_full_unstemmed | Tetrakis(pyridazine-κN)bis(thiocyanato-κN)nickel(II) pyridazine disolvate |
title_short | Tetrakis(pyridazine-κN)bis(thiocyanato-κN)nickel(II) pyridazine disolvate |
title_sort | tetrakis(pyridazine-κn)bis(thiocyanato-κn)nickel(ii) pyridazine disolvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379122/ https://www.ncbi.nlm.nih.gov/pubmed/22719343 http://dx.doi.org/10.1107/S1600536812023306 |
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