Cargando…

Chlorido{μ-2,6-bis­[(2-amino­eth­yl)imino­meth­yl]-4-chloro­phenolato}-μ-oxido-dicopper(II) trihydrate

In the title dinuclear complex, [Cu(2)(C(14)H(20)ClN(4)O)ClO]·3H(2)O, one Cu(II) cation assumes a distorted square-planar coordination geometry and the other a distorted square-pyramidal coordination geometry. Both Cu(II) cations are N,N′,O-chelated by one arm of the 2,6-bis­[(2-amino­eth­yl)imino­m...

Descripción completa

Detalles Bibliográficos
Autores principales: Zhou, Jing-Jing, Xiao, Wei, Mao, Jia-Wei, Zhou, Hong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379123/
https://www.ncbi.nlm.nih.gov/pubmed/22719344
http://dx.doi.org/10.1107/S160053681202301X
_version_ 1782236131318824960
author Zhou, Jing-Jing
Xiao, Wei
Mao, Jia-Wei
Zhou, Hong
author_facet Zhou, Jing-Jing
Xiao, Wei
Mao, Jia-Wei
Zhou, Hong
author_sort Zhou, Jing-Jing
collection PubMed
description In the title dinuclear complex, [Cu(2)(C(14)H(20)ClN(4)O)ClO]·3H(2)O, one Cu(II) cation assumes a distorted square-planar coordination geometry and the other a distorted square-pyramidal coordination geometry. Both Cu(II) cations are N,N′,O-chelated by one arm of the 2,6-bis­[(2-amino­eth­yl)imino­meth­yl]-4-chloro­phenolate anion, and one oxide anion bridges the two Cu(II) cations, forming a dinuclear complex. One of the Cu(II) cations is further coordinated by an Cl(−) anion in the apical direction. In the crystal, lattice water mol­ecules are linked with the complex mol­ecule via O—H⋯Cl hydrogen bonds while O—H⋯O hydrogen bonding occurs between lattice water mol­ecules , forming three-dimensional network structure.
format Online
Article
Text
id pubmed-3379123
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-33791232012-06-20 Chlorido{μ-2,6-bis­[(2-amino­eth­yl)imino­meth­yl]-4-chloro­phenolato}-μ-oxido-dicopper(II) trihydrate Zhou, Jing-Jing Xiao, Wei Mao, Jia-Wei Zhou, Hong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title dinuclear complex, [Cu(2)(C(14)H(20)ClN(4)O)ClO]·3H(2)O, one Cu(II) cation assumes a distorted square-planar coordination geometry and the other a distorted square-pyramidal coordination geometry. Both Cu(II) cations are N,N′,O-chelated by one arm of the 2,6-bis­[(2-amino­eth­yl)imino­meth­yl]-4-chloro­phenolate anion, and one oxide anion bridges the two Cu(II) cations, forming a dinuclear complex. One of the Cu(II) cations is further coordinated by an Cl(−) anion in the apical direction. In the crystal, lattice water mol­ecules are linked with the complex mol­ecule via O—H⋯Cl hydrogen bonds while O—H⋯O hydrogen bonding occurs between lattice water mol­ecules , forming three-dimensional network structure. International Union of Crystallography 2012-05-26 /pmc/articles/PMC3379123/ /pubmed/22719344 http://dx.doi.org/10.1107/S160053681202301X Text en © Zhou et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhou, Jing-Jing
Xiao, Wei
Mao, Jia-Wei
Zhou, Hong
Chlorido{μ-2,6-bis­[(2-amino­eth­yl)imino­meth­yl]-4-chloro­phenolato}-μ-oxido-dicopper(II) trihydrate
title Chlorido{μ-2,6-bis­[(2-amino­eth­yl)imino­meth­yl]-4-chloro­phenolato}-μ-oxido-dicopper(II) trihydrate
title_full Chlorido{μ-2,6-bis­[(2-amino­eth­yl)imino­meth­yl]-4-chloro­phenolato}-μ-oxido-dicopper(II) trihydrate
title_fullStr Chlorido{μ-2,6-bis­[(2-amino­eth­yl)imino­meth­yl]-4-chloro­phenolato}-μ-oxido-dicopper(II) trihydrate
title_full_unstemmed Chlorido{μ-2,6-bis­[(2-amino­eth­yl)imino­meth­yl]-4-chloro­phenolato}-μ-oxido-dicopper(II) trihydrate
title_short Chlorido{μ-2,6-bis­[(2-amino­eth­yl)imino­meth­yl]-4-chloro­phenolato}-μ-oxido-dicopper(II) trihydrate
title_sort chlorido{μ-2,6-bis­[(2-amino­eth­yl)imino­meth­yl]-4-chloro­phenolato}-μ-oxido-dicopper(ii) trihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379123/
https://www.ncbi.nlm.nih.gov/pubmed/22719344
http://dx.doi.org/10.1107/S160053681202301X
work_keys_str_mv AT zhoujingjing chloridom26bis2aminoethyliminomethyl4chlorophenolatomoxidodicopperiitrihydrate
AT xiaowei chloridom26bis2aminoethyliminomethyl4chlorophenolatomoxidodicopperiitrihydrate
AT maojiawei chloridom26bis2aminoethyliminomethyl4chlorophenolatomoxidodicopperiitrihydrate
AT zhouhong chloridom26bis2aminoethyliminomethyl4chlorophenolatomoxidodicopperiitrihydrate