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Chlorido{μ-2,6-bis[(2-aminoethyl)iminomethyl]-4-chlorophenolato}-μ-oxido-dicopper(II) trihydrate
In the title dinuclear complex, [Cu(2)(C(14)H(20)ClN(4)O)ClO]·3H(2)O, one Cu(II) cation assumes a distorted square-planar coordination geometry and the other a distorted square-pyramidal coordination geometry. Both Cu(II) cations are N,N′,O-chelated by one arm of the 2,6-bis[(2-aminoethyl)iminom...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379123/ https://www.ncbi.nlm.nih.gov/pubmed/22719344 http://dx.doi.org/10.1107/S160053681202301X |
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author | Zhou, Jing-Jing Xiao, Wei Mao, Jia-Wei Zhou, Hong |
author_facet | Zhou, Jing-Jing Xiao, Wei Mao, Jia-Wei Zhou, Hong |
author_sort | Zhou, Jing-Jing |
collection | PubMed |
description | In the title dinuclear complex, [Cu(2)(C(14)H(20)ClN(4)O)ClO]·3H(2)O, one Cu(II) cation assumes a distorted square-planar coordination geometry and the other a distorted square-pyramidal coordination geometry. Both Cu(II) cations are N,N′,O-chelated by one arm of the 2,6-bis[(2-aminoethyl)iminomethyl]-4-chlorophenolate anion, and one oxide anion bridges the two Cu(II) cations, forming a dinuclear complex. One of the Cu(II) cations is further coordinated by an Cl(−) anion in the apical direction. In the crystal, lattice water molecules are linked with the complex molecule via O—H⋯Cl hydrogen bonds while O—H⋯O hydrogen bonding occurs between lattice water molecules , forming three-dimensional network structure. |
format | Online Article Text |
id | pubmed-3379123 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33791232012-06-20 Chlorido{μ-2,6-bis[(2-aminoethyl)iminomethyl]-4-chlorophenolato}-μ-oxido-dicopper(II) trihydrate Zhou, Jing-Jing Xiao, Wei Mao, Jia-Wei Zhou, Hong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title dinuclear complex, [Cu(2)(C(14)H(20)ClN(4)O)ClO]·3H(2)O, one Cu(II) cation assumes a distorted square-planar coordination geometry and the other a distorted square-pyramidal coordination geometry. Both Cu(II) cations are N,N′,O-chelated by one arm of the 2,6-bis[(2-aminoethyl)iminomethyl]-4-chlorophenolate anion, and one oxide anion bridges the two Cu(II) cations, forming a dinuclear complex. One of the Cu(II) cations is further coordinated by an Cl(−) anion in the apical direction. In the crystal, lattice water molecules are linked with the complex molecule via O—H⋯Cl hydrogen bonds while O—H⋯O hydrogen bonding occurs between lattice water molecules , forming three-dimensional network structure. International Union of Crystallography 2012-05-26 /pmc/articles/PMC3379123/ /pubmed/22719344 http://dx.doi.org/10.1107/S160053681202301X Text en © Zhou et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Zhou, Jing-Jing Xiao, Wei Mao, Jia-Wei Zhou, Hong Chlorido{μ-2,6-bis[(2-aminoethyl)iminomethyl]-4-chlorophenolato}-μ-oxido-dicopper(II) trihydrate |
title | Chlorido{μ-2,6-bis[(2-aminoethyl)iminomethyl]-4-chlorophenolato}-μ-oxido-dicopper(II) trihydrate |
title_full | Chlorido{μ-2,6-bis[(2-aminoethyl)iminomethyl]-4-chlorophenolato}-μ-oxido-dicopper(II) trihydrate |
title_fullStr | Chlorido{μ-2,6-bis[(2-aminoethyl)iminomethyl]-4-chlorophenolato}-μ-oxido-dicopper(II) trihydrate |
title_full_unstemmed | Chlorido{μ-2,6-bis[(2-aminoethyl)iminomethyl]-4-chlorophenolato}-μ-oxido-dicopper(II) trihydrate |
title_short | Chlorido{μ-2,6-bis[(2-aminoethyl)iminomethyl]-4-chlorophenolato}-μ-oxido-dicopper(II) trihydrate |
title_sort | chlorido{μ-2,6-bis[(2-aminoethyl)iminomethyl]-4-chlorophenolato}-μ-oxido-dicopper(ii) trihydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379123/ https://www.ncbi.nlm.nih.gov/pubmed/22719344 http://dx.doi.org/10.1107/S160053681202301X |
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