Tetra-μ(3)-iodido-tetra­kis­{[ethyl 2-(1H-benzimidazol-1-yl)acetate-κN (3)]copper(I)}

The complex mol­ecule of the tetra­nuclear cubane-type title compound, [Cu(4)I(4)(C(11)H(12)N(2)O(2))(4)], has crystallographically imposed fourfold inversion symmetry. The Cu(I) ions are coordinated in a distorted tetra­hedral geometry by an N atom of a benzimidazole ring system and three μ(3)-iodi...

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Detalles Bibliográficos
Autores principales: Yang, Lili, Zhang, Zhengyi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379124/
https://www.ncbi.nlm.nih.gov/pubmed/22719345
http://dx.doi.org/10.1107/S160053681202257X
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author Yang, Lili
Zhang, Zhengyi
author_facet Yang, Lili
Zhang, Zhengyi
author_sort Yang, Lili
collection PubMed
description The complex mol­ecule of the tetra­nuclear cubane-type title compound, [Cu(4)I(4)(C(11)H(12)N(2)O(2))(4)], has crystallographically imposed fourfold inversion symmetry. The Cu(I) ions are coordinated in a distorted tetra­hedral geometry by an N atom of a benzimidazole ring system and three μ(3)-iodide ions, forming a Cu(4)I(4) core. In the crystal, complex mol­ecules are connected into a three-dimensional network by C—H⋯O hydrogen bonds involving H and O atoms of adjacent eth­oxy­carbonyl groups.
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spelling pubmed-33791242012-06-20 Tetra-μ(3)-iodido-tetra­kis­{[ethyl 2-(1H-benzimidazol-1-yl)acetate-κN (3)]copper(I)} Yang, Lili Zhang, Zhengyi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The complex mol­ecule of the tetra­nuclear cubane-type title compound, [Cu(4)I(4)(C(11)H(12)N(2)O(2))(4)], has crystallographically imposed fourfold inversion symmetry. The Cu(I) ions are coordinated in a distorted tetra­hedral geometry by an N atom of a benzimidazole ring system and three μ(3)-iodide ions, forming a Cu(4)I(4) core. In the crystal, complex mol­ecules are connected into a three-dimensional network by C—H⋯O hydrogen bonds involving H and O atoms of adjacent eth­oxy­carbonyl groups. International Union of Crystallography 2012-05-26 /pmc/articles/PMC3379124/ /pubmed/22719345 http://dx.doi.org/10.1107/S160053681202257X Text en © Yang and Zhang 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yang, Lili
Zhang, Zhengyi
Tetra-μ(3)-iodido-tetra­kis­{[ethyl 2-(1H-benzimidazol-1-yl)acetate-κN (3)]copper(I)}
title Tetra-μ(3)-iodido-tetra­kis­{[ethyl 2-(1H-benzimidazol-1-yl)acetate-κN (3)]copper(I)}
title_full Tetra-μ(3)-iodido-tetra­kis­{[ethyl 2-(1H-benzimidazol-1-yl)acetate-κN (3)]copper(I)}
title_fullStr Tetra-μ(3)-iodido-tetra­kis­{[ethyl 2-(1H-benzimidazol-1-yl)acetate-κN (3)]copper(I)}
title_full_unstemmed Tetra-μ(3)-iodido-tetra­kis­{[ethyl 2-(1H-benzimidazol-1-yl)acetate-κN (3)]copper(I)}
title_short Tetra-μ(3)-iodido-tetra­kis­{[ethyl 2-(1H-benzimidazol-1-yl)acetate-κN (3)]copper(I)}
title_sort tetra-μ(3)-iodido-tetra­kis­{[ethyl 2-(1h-benzimidazol-1-yl)acetate-κn (3)]copper(i)}
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379124/
https://www.ncbi.nlm.nih.gov/pubmed/22719345
http://dx.doi.org/10.1107/S160053681202257X
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AT zhangzhengyi tetram3iodidotetrakisethyl21hbenzimidazol1ylacetatekn3copperi

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