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Di-μ-glutarato-κ(4) O (1):O (5)-bis{aqua[5,6-diphenyl-3-(pyridin-2-yl)-1,2,4-triazine-κ(2) N (2),N (3)]copper(II)}
In the centrosymmetric dinuclear title complex, [Cu(2)(C(5)H(6)O(4))(2)(C(20)H(14)N(4))(2)(H(2)O)(2)], the Cu atom displays a distorted square-pyramidal coordination environment with the basal plane occupied by two 5,6-diphenyl-3-(pyridin-2-yl)-1,2,4-triazine N atoms and two O atoms from different g...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379125/ https://www.ncbi.nlm.nih.gov/pubmed/22719346 http://dx.doi.org/10.1107/S1600536812022969 |
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author | Xu, Wei Feng, Lan-Jing-Qian |
author_facet | Xu, Wei Feng, Lan-Jing-Qian |
author_sort | Xu, Wei |
collection | PubMed |
description | In the centrosymmetric dinuclear title complex, [Cu(2)(C(5)H(6)O(4))(2)(C(20)H(14)N(4))(2)(H(2)O)(2)], the Cu atom displays a distorted square-pyramidal coordination environment with the basal plane occupied by two 5,6-diphenyl-3-(pyridin-2-yl)-1,2,4-triazine N atoms and two O atoms from different glutarate dianions, while a water molecule is located at the apical position. Of the two water H atoms, one is engaged in an intramolecular O—H⋯O hydrogen bond, whereas the second is engaged in an intermolecular O—H⋯O hydrogen bond. The intermolecular hydrogen bonds lead to the formation of a chain along [010]. |
format | Online Article Text |
id | pubmed-3379125 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33791252012-06-20 Di-μ-glutarato-κ(4) O (1):O (5)-bis{aqua[5,6-diphenyl-3-(pyridin-2-yl)-1,2,4-triazine-κ(2) N (2),N (3)]copper(II)} Xu, Wei Feng, Lan-Jing-Qian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the centrosymmetric dinuclear title complex, [Cu(2)(C(5)H(6)O(4))(2)(C(20)H(14)N(4))(2)(H(2)O)(2)], the Cu atom displays a distorted square-pyramidal coordination environment with the basal plane occupied by two 5,6-diphenyl-3-(pyridin-2-yl)-1,2,4-triazine N atoms and two O atoms from different glutarate dianions, while a water molecule is located at the apical position. Of the two water H atoms, one is engaged in an intramolecular O—H⋯O hydrogen bond, whereas the second is engaged in an intermolecular O—H⋯O hydrogen bond. The intermolecular hydrogen bonds lead to the formation of a chain along [010]. International Union of Crystallography 2012-05-26 /pmc/articles/PMC3379125/ /pubmed/22719346 http://dx.doi.org/10.1107/S1600536812022969 Text en © Xu and Feng 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Xu, Wei Feng, Lan-Jing-Qian Di-μ-glutarato-κ(4) O (1):O (5)-bis{aqua[5,6-diphenyl-3-(pyridin-2-yl)-1,2,4-triazine-κ(2) N (2),N (3)]copper(II)} |
title | Di-μ-glutarato-κ(4)
O
(1):O
(5)-bis{aqua[5,6-diphenyl-3-(pyridin-2-yl)-1,2,4-triazine-κ(2)
N
(2),N
(3)]copper(II)} |
title_full | Di-μ-glutarato-κ(4)
O
(1):O
(5)-bis{aqua[5,6-diphenyl-3-(pyridin-2-yl)-1,2,4-triazine-κ(2)
N
(2),N
(3)]copper(II)} |
title_fullStr | Di-μ-glutarato-κ(4)
O
(1):O
(5)-bis{aqua[5,6-diphenyl-3-(pyridin-2-yl)-1,2,4-triazine-κ(2)
N
(2),N
(3)]copper(II)} |
title_full_unstemmed | Di-μ-glutarato-κ(4)
O
(1):O
(5)-bis{aqua[5,6-diphenyl-3-(pyridin-2-yl)-1,2,4-triazine-κ(2)
N
(2),N
(3)]copper(II)} |
title_short | Di-μ-glutarato-κ(4)
O
(1):O
(5)-bis{aqua[5,6-diphenyl-3-(pyridin-2-yl)-1,2,4-triazine-κ(2)
N
(2),N
(3)]copper(II)} |
title_sort | di-μ-glutarato-κ(4)
o
(1):o
(5)-bis{aqua[5,6-diphenyl-3-(pyridin-2-yl)-1,2,4-triazine-κ(2)
n
(2),n
(3)]copper(ii)} |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379125/ https://www.ncbi.nlm.nih.gov/pubmed/22719346 http://dx.doi.org/10.1107/S1600536812022969 |
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