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Di-μ-glutarato-κ(4) O (1):O (5)-bis­{aqua­[5,6-diphenyl-3-(pyridin-2-yl)-1,2,4-triazine-κ(2) N (2),N (3)]copper(II)}

In the centrosymmetric dinuclear title complex, [Cu(2)(C(5)H(6)O(4))(2)(C(20)H(14)N(4))(2)(H(2)O)(2)], the Cu atom displays a distorted square-pyramidal coordination environment with the basal plane occupied by two 5,6-diphenyl-3-(pyridin-2-yl)-1,2,4-triazine N atoms and two O atoms from different g...

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Detalles Bibliográficos
Autores principales: Xu, Wei, Feng, Lan-Jing-Qian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379125/
https://www.ncbi.nlm.nih.gov/pubmed/22719346
http://dx.doi.org/10.1107/S1600536812022969
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author Xu, Wei
Feng, Lan-Jing-Qian
author_facet Xu, Wei
Feng, Lan-Jing-Qian
author_sort Xu, Wei
collection PubMed
description In the centrosymmetric dinuclear title complex, [Cu(2)(C(5)H(6)O(4))(2)(C(20)H(14)N(4))(2)(H(2)O)(2)], the Cu atom displays a distorted square-pyramidal coordination environment with the basal plane occupied by two 5,6-diphenyl-3-(pyridin-2-yl)-1,2,4-triazine N atoms and two O atoms from different glutarate dianions, while a water mol­ecule is located at the apical position. Of the two water H atoms, one is engaged in an intra­molecular O—H⋯O hydrogen bond, whereas the second is engaged in an inter­molecular O—H⋯O hydrogen bond. The intermolecular hydrogen bonds lead to the formation of a chain along [010].
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spelling pubmed-33791252012-06-20 Di-μ-glutarato-κ(4) O (1):O (5)-bis­{aqua­[5,6-diphenyl-3-(pyridin-2-yl)-1,2,4-triazine-κ(2) N (2),N (3)]copper(II)} Xu, Wei Feng, Lan-Jing-Qian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the centrosymmetric dinuclear title complex, [Cu(2)(C(5)H(6)O(4))(2)(C(20)H(14)N(4))(2)(H(2)O)(2)], the Cu atom displays a distorted square-pyramidal coordination environment with the basal plane occupied by two 5,6-diphenyl-3-(pyridin-2-yl)-1,2,4-triazine N atoms and two O atoms from different glutarate dianions, while a water mol­ecule is located at the apical position. Of the two water H atoms, one is engaged in an intra­molecular O—H⋯O hydrogen bond, whereas the second is engaged in an inter­molecular O—H⋯O hydrogen bond. The intermolecular hydrogen bonds lead to the formation of a chain along [010]. International Union of Crystallography 2012-05-26 /pmc/articles/PMC3379125/ /pubmed/22719346 http://dx.doi.org/10.1107/S1600536812022969 Text en © Xu and Feng 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Xu, Wei
Feng, Lan-Jing-Qian
Di-μ-glutarato-κ(4) O (1):O (5)-bis­{aqua­[5,6-diphenyl-3-(pyridin-2-yl)-1,2,4-triazine-κ(2) N (2),N (3)]copper(II)}
title Di-μ-glutarato-κ(4) O (1):O (5)-bis­{aqua­[5,6-diphenyl-3-(pyridin-2-yl)-1,2,4-triazine-κ(2) N (2),N (3)]copper(II)}
title_full Di-μ-glutarato-κ(4) O (1):O (5)-bis­{aqua­[5,6-diphenyl-3-(pyridin-2-yl)-1,2,4-triazine-κ(2) N (2),N (3)]copper(II)}
title_fullStr Di-μ-glutarato-κ(4) O (1):O (5)-bis­{aqua­[5,6-diphenyl-3-(pyridin-2-yl)-1,2,4-triazine-κ(2) N (2),N (3)]copper(II)}
title_full_unstemmed Di-μ-glutarato-κ(4) O (1):O (5)-bis­{aqua­[5,6-diphenyl-3-(pyridin-2-yl)-1,2,4-triazine-κ(2) N (2),N (3)]copper(II)}
title_short Di-μ-glutarato-κ(4) O (1):O (5)-bis­{aqua­[5,6-diphenyl-3-(pyridin-2-yl)-1,2,4-triazine-κ(2) N (2),N (3)]copper(II)}
title_sort di-μ-glutarato-κ(4) o (1):o (5)-bis­{aqua­[5,6-diphenyl-3-(pyridin-2-yl)-1,2,4-triazine-κ(2) n (2),n (3)]copper(ii)}
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379125/
https://www.ncbi.nlm.nih.gov/pubmed/22719346
http://dx.doi.org/10.1107/S1600536812022969
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