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Aqua­(2,6-dihy­droxy­benzoato-κO (1))bis­(1,10-phenanthroline-κ(2) N,N′)manganese(II) 2,6-dihy­droxy­benzoate hemihydrate

In the complex cation of the title compound, [Mn(C(7)H(5)O(4))(C(12)H(8)N(2))(2)(H(2)O)](C(7)H(5)O(4))·0.5H(2)O, the Mn(II) atom has a six-coordinate octa­hedral environment defined by one carboxyl­ate O atom belonging to a 2,6-dihy­droxy­benzoate (DHB) ligand, four N atoms from two chelating 1,10-p...

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Detalles Bibliográficos
Autores principales: Li, Quanwei, He, Li, Jin, Hongxiao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379126/
https://www.ncbi.nlm.nih.gov/pubmed/22719347
http://dx.doi.org/10.1107/S1600536812022155
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author Li, Quanwei
He, Li
Jin, Hongxiao
author_facet Li, Quanwei
He, Li
Jin, Hongxiao
author_sort Li, Quanwei
collection PubMed
description In the complex cation of the title compound, [Mn(C(7)H(5)O(4))(C(12)H(8)N(2))(2)(H(2)O)](C(7)H(5)O(4))·0.5H(2)O, the Mn(II) atom has a six-coordinate octa­hedral environment defined by one carboxyl­ate O atom belonging to a 2,6-dihy­droxy­benzoate (DHB) ligand, four N atoms from two chelating 1,10-phenanthroline mol­ecules and one water mol­ecule. The lattice water mol­ecule lies on a twofold rotation axis. Intra­molecular O—H⋯O hydrogen bonds are present in the DHB anions and complex cations. Inter­molecular O—H⋯O hydrogen bonds link two cations, two anions and one water mol­ecule into a dimer. π–π inter­actions between the pyridine and benzene rings and between the benzene rings are also observed [centroid–centroid distances = 3.7774 (16), 3.7912 (16) and 3.7310 (17) Å].
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spelling pubmed-33791262012-06-20 Aqua­(2,6-dihy­droxy­benzoato-κO (1))bis­(1,10-phenanthroline-κ(2) N,N′)manganese(II) 2,6-dihy­droxy­benzoate hemihydrate Li, Quanwei He, Li Jin, Hongxiao Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the complex cation of the title compound, [Mn(C(7)H(5)O(4))(C(12)H(8)N(2))(2)(H(2)O)](C(7)H(5)O(4))·0.5H(2)O, the Mn(II) atom has a six-coordinate octa­hedral environment defined by one carboxyl­ate O atom belonging to a 2,6-dihy­droxy­benzoate (DHB) ligand, four N atoms from two chelating 1,10-phenanthroline mol­ecules and one water mol­ecule. The lattice water mol­ecule lies on a twofold rotation axis. Intra­molecular O—H⋯O hydrogen bonds are present in the DHB anions and complex cations. Inter­molecular O—H⋯O hydrogen bonds link two cations, two anions and one water mol­ecule into a dimer. π–π inter­actions between the pyridine and benzene rings and between the benzene rings are also observed [centroid–centroid distances = 3.7774 (16), 3.7912 (16) and 3.7310 (17) Å]. International Union of Crystallography 2012-05-26 /pmc/articles/PMC3379126/ /pubmed/22719347 http://dx.doi.org/10.1107/S1600536812022155 Text en © Li et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Quanwei
He, Li
Jin, Hongxiao
Aqua­(2,6-dihy­droxy­benzoato-κO (1))bis­(1,10-phenanthroline-κ(2) N,N′)manganese(II) 2,6-dihy­droxy­benzoate hemihydrate
title Aqua­(2,6-dihy­droxy­benzoato-κO (1))bis­(1,10-phenanthroline-κ(2) N,N′)manganese(II) 2,6-dihy­droxy­benzoate hemihydrate
title_full Aqua­(2,6-dihy­droxy­benzoato-κO (1))bis­(1,10-phenanthroline-κ(2) N,N′)manganese(II) 2,6-dihy­droxy­benzoate hemihydrate
title_fullStr Aqua­(2,6-dihy­droxy­benzoato-κO (1))bis­(1,10-phenanthroline-κ(2) N,N′)manganese(II) 2,6-dihy­droxy­benzoate hemihydrate
title_full_unstemmed Aqua­(2,6-dihy­droxy­benzoato-κO (1))bis­(1,10-phenanthroline-κ(2) N,N′)manganese(II) 2,6-dihy­droxy­benzoate hemihydrate
title_short Aqua­(2,6-dihy­droxy­benzoato-κO (1))bis­(1,10-phenanthroline-κ(2) N,N′)manganese(II) 2,6-dihy­droxy­benzoate hemihydrate
title_sort aqua­(2,6-dihy­droxy­benzoato-κo (1))bis­(1,10-phenanthroline-κ(2) n,n′)manganese(ii) 2,6-dihy­droxy­benzoate hemihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379126/
https://www.ncbi.nlm.nih.gov/pubmed/22719347
http://dx.doi.org/10.1107/S1600536812022155
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AT jinhongxiao aqua26dihydroxybenzoatoko1bis110phenanthrolinek2nnmanganeseii26dihydroxybenzoatehemihydrate