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Aqua(2,6-dihydroxybenzoato-κO (1))bis(1,10-phenanthroline-κ(2) N,N′)manganese(II) 2,6-dihydroxybenzoate hemihydrate
In the complex cation of the title compound, [Mn(C(7)H(5)O(4))(C(12)H(8)N(2))(2)(H(2)O)](C(7)H(5)O(4))·0.5H(2)O, the Mn(II) atom has a six-coordinate octahedral environment defined by one carboxylate O atom belonging to a 2,6-dihydroxybenzoate (DHB) ligand, four N atoms from two chelating 1,10-p...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379126/ https://www.ncbi.nlm.nih.gov/pubmed/22719347 http://dx.doi.org/10.1107/S1600536812022155 |
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author | Li, Quanwei He, Li Jin, Hongxiao |
author_facet | Li, Quanwei He, Li Jin, Hongxiao |
author_sort | Li, Quanwei |
collection | PubMed |
description | In the complex cation of the title compound, [Mn(C(7)H(5)O(4))(C(12)H(8)N(2))(2)(H(2)O)](C(7)H(5)O(4))·0.5H(2)O, the Mn(II) atom has a six-coordinate octahedral environment defined by one carboxylate O atom belonging to a 2,6-dihydroxybenzoate (DHB) ligand, four N atoms from two chelating 1,10-phenanthroline molecules and one water molecule. The lattice water molecule lies on a twofold rotation axis. Intramolecular O—H⋯O hydrogen bonds are present in the DHB anions and complex cations. Intermolecular O—H⋯O hydrogen bonds link two cations, two anions and one water molecule into a dimer. π–π interactions between the pyridine and benzene rings and between the benzene rings are also observed [centroid–centroid distances = 3.7774 (16), 3.7912 (16) and 3.7310 (17) Å]. |
format | Online Article Text |
id | pubmed-3379126 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33791262012-06-20 Aqua(2,6-dihydroxybenzoato-κO (1))bis(1,10-phenanthroline-κ(2) N,N′)manganese(II) 2,6-dihydroxybenzoate hemihydrate Li, Quanwei He, Li Jin, Hongxiao Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the complex cation of the title compound, [Mn(C(7)H(5)O(4))(C(12)H(8)N(2))(2)(H(2)O)](C(7)H(5)O(4))·0.5H(2)O, the Mn(II) atom has a six-coordinate octahedral environment defined by one carboxylate O atom belonging to a 2,6-dihydroxybenzoate (DHB) ligand, four N atoms from two chelating 1,10-phenanthroline molecules and one water molecule. The lattice water molecule lies on a twofold rotation axis. Intramolecular O—H⋯O hydrogen bonds are present in the DHB anions and complex cations. Intermolecular O—H⋯O hydrogen bonds link two cations, two anions and one water molecule into a dimer. π–π interactions between the pyridine and benzene rings and between the benzene rings are also observed [centroid–centroid distances = 3.7774 (16), 3.7912 (16) and 3.7310 (17) Å]. International Union of Crystallography 2012-05-26 /pmc/articles/PMC3379126/ /pubmed/22719347 http://dx.doi.org/10.1107/S1600536812022155 Text en © Li et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Li, Quanwei He, Li Jin, Hongxiao Aqua(2,6-dihydroxybenzoato-κO (1))bis(1,10-phenanthroline-κ(2) N,N′)manganese(II) 2,6-dihydroxybenzoate hemihydrate |
title | Aqua(2,6-dihydroxybenzoato-κO
(1))bis(1,10-phenanthroline-κ(2)
N,N′)manganese(II) 2,6-dihydroxybenzoate hemihydrate |
title_full | Aqua(2,6-dihydroxybenzoato-κO
(1))bis(1,10-phenanthroline-κ(2)
N,N′)manganese(II) 2,6-dihydroxybenzoate hemihydrate |
title_fullStr | Aqua(2,6-dihydroxybenzoato-κO
(1))bis(1,10-phenanthroline-κ(2)
N,N′)manganese(II) 2,6-dihydroxybenzoate hemihydrate |
title_full_unstemmed | Aqua(2,6-dihydroxybenzoato-κO
(1))bis(1,10-phenanthroline-κ(2)
N,N′)manganese(II) 2,6-dihydroxybenzoate hemihydrate |
title_short | Aqua(2,6-dihydroxybenzoato-κO
(1))bis(1,10-phenanthroline-κ(2)
N,N′)manganese(II) 2,6-dihydroxybenzoate hemihydrate |
title_sort | aqua(2,6-dihydroxybenzoato-κo
(1))bis(1,10-phenanthroline-κ(2)
n,n′)manganese(ii) 2,6-dihydroxybenzoate hemihydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379126/ https://www.ncbi.nlm.nih.gov/pubmed/22719347 http://dx.doi.org/10.1107/S1600536812022155 |
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