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Poly[[tetra­aqua­bis­(μ(3)-5-carboxybenzene-1,2,4-tri­carboxyl­ato)tricadmium] tetra­hydrate]

There are three independent Cd(II) ions in the title complex, {[Cd(3)(C(10)H(3)O(8))(2)(H(2)O)(4)]·4H(2)O}(n), one of which is coordinated by four O atoms from three 5-carboxybenzene-1,2,4-tri­carboxyl­ate ligands and by two water mol­ecules in a distorted octa­hedral geometry. The second Cd(II) ion...

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Detalles Bibliográficos
Autores principales: Jia, Yong-Yan, Xie, Xin-Nian, Yang, Huai-Xia
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379128/
https://www.ncbi.nlm.nih.gov/pubmed/22719349
http://dx.doi.org/10.1107/S1600536812022726
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author Jia, Yong-Yan
Xie, Xin-Nian
Yang, Huai-Xia
author_facet Jia, Yong-Yan
Xie, Xin-Nian
Yang, Huai-Xia
author_sort Jia, Yong-Yan
collection PubMed
description There are three independent Cd(II) ions in the title complex, {[Cd(3)(C(10)H(3)O(8))(2)(H(2)O)(4)]·4H(2)O}(n), one of which is coordinated by four O atoms from three 5-carboxybenzene-1,2,4-tri­carboxyl­ate ligands and by two water mol­ecules in a distorted octa­hedral geometry. The second Cd(II) ion is coordinated by five O atoms from four 5-carboxybenzene-1,2,4-tri­carboxyl­ate ligands and by one water mol­ecule also in a distorted octa­hedral geometry while the third Cd(II) ion is coordinated by five O atoms from three 5-carboxybenzene-1,2,4-tri­carboxyl­ate ligands and by one water mol­ecule in a highly distorted octa­hedral geometry. The 5-carboxybenzene-1,2,4-tri­carboxyl­ate ligands bridge the Cd(II) ions, resulting in the formation of a three-dimensional structure. Intra- and inter­molecular O—H⋯O hydrogen bonds are present throughout the three-dimensional structure.
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spelling pubmed-33791282012-06-20 Poly[[tetra­aqua­bis­(μ(3)-5-carboxybenzene-1,2,4-tri­carboxyl­ato)tricadmium] tetra­hydrate] Jia, Yong-Yan Xie, Xin-Nian Yang, Huai-Xia Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers There are three independent Cd(II) ions in the title complex, {[Cd(3)(C(10)H(3)O(8))(2)(H(2)O)(4)]·4H(2)O}(n), one of which is coordinated by four O atoms from three 5-carboxybenzene-1,2,4-tri­carboxyl­ate ligands and by two water mol­ecules in a distorted octa­hedral geometry. The second Cd(II) ion is coordinated by five O atoms from four 5-carboxybenzene-1,2,4-tri­carboxyl­ate ligands and by one water mol­ecule also in a distorted octa­hedral geometry while the third Cd(II) ion is coordinated by five O atoms from three 5-carboxybenzene-1,2,4-tri­carboxyl­ate ligands and by one water mol­ecule in a highly distorted octa­hedral geometry. The 5-carboxybenzene-1,2,4-tri­carboxyl­ate ligands bridge the Cd(II) ions, resulting in the formation of a three-dimensional structure. Intra- and inter­molecular O—H⋯O hydrogen bonds are present throughout the three-dimensional structure. International Union of Crystallography 2012-05-26 /pmc/articles/PMC3379128/ /pubmed/22719349 http://dx.doi.org/10.1107/S1600536812022726 Text en © Jia et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Jia, Yong-Yan
Xie, Xin-Nian
Yang, Huai-Xia
Poly[[tetra­aqua­bis­(μ(3)-5-carboxybenzene-1,2,4-tri­carboxyl­ato)tricadmium] tetra­hydrate]
title Poly[[tetra­aqua­bis­(μ(3)-5-carboxybenzene-1,2,4-tri­carboxyl­ato)tricadmium] tetra­hydrate]
title_full Poly[[tetra­aqua­bis­(μ(3)-5-carboxybenzene-1,2,4-tri­carboxyl­ato)tricadmium] tetra­hydrate]
title_fullStr Poly[[tetra­aqua­bis­(μ(3)-5-carboxybenzene-1,2,4-tri­carboxyl­ato)tricadmium] tetra­hydrate]
title_full_unstemmed Poly[[tetra­aqua­bis­(μ(3)-5-carboxybenzene-1,2,4-tri­carboxyl­ato)tricadmium] tetra­hydrate]
title_short Poly[[tetra­aqua­bis­(μ(3)-5-carboxybenzene-1,2,4-tri­carboxyl­ato)tricadmium] tetra­hydrate]
title_sort poly[[tetra­aqua­bis­(μ(3)-5-carboxybenzene-1,2,4-tri­carboxyl­ato)tricadmium] tetra­hydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379128/
https://www.ncbi.nlm.nih.gov/pubmed/22719349
http://dx.doi.org/10.1107/S1600536812022726
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