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Poly[[tetraaquabis(μ(3)-5-carboxybenzene-1,2,4-tricarboxylato)tricadmium] tetrahydrate]
There are three independent Cd(II) ions in the title complex, {[Cd(3)(C(10)H(3)O(8))(2)(H(2)O)(4)]·4H(2)O}(n), one of which is coordinated by four O atoms from three 5-carboxybenzene-1,2,4-tricarboxylate ligands and by two water molecules in a distorted octahedral geometry. The second Cd(II) ion...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379128/ https://www.ncbi.nlm.nih.gov/pubmed/22719349 http://dx.doi.org/10.1107/S1600536812022726 |
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author | Jia, Yong-Yan Xie, Xin-Nian Yang, Huai-Xia |
author_facet | Jia, Yong-Yan Xie, Xin-Nian Yang, Huai-Xia |
author_sort | Jia, Yong-Yan |
collection | PubMed |
description | There are three independent Cd(II) ions in the title complex, {[Cd(3)(C(10)H(3)O(8))(2)(H(2)O)(4)]·4H(2)O}(n), one of which is coordinated by four O atoms from three 5-carboxybenzene-1,2,4-tricarboxylate ligands and by two water molecules in a distorted octahedral geometry. The second Cd(II) ion is coordinated by five O atoms from four 5-carboxybenzene-1,2,4-tricarboxylate ligands and by one water molecule also in a distorted octahedral geometry while the third Cd(II) ion is coordinated by five O atoms from three 5-carboxybenzene-1,2,4-tricarboxylate ligands and by one water molecule in a highly distorted octahedral geometry. The 5-carboxybenzene-1,2,4-tricarboxylate ligands bridge the Cd(II) ions, resulting in the formation of a three-dimensional structure. Intra- and intermolecular O—H⋯O hydrogen bonds are present throughout the three-dimensional structure. |
format | Online Article Text |
id | pubmed-3379128 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33791282012-06-20 Poly[[tetraaquabis(μ(3)-5-carboxybenzene-1,2,4-tricarboxylato)tricadmium] tetrahydrate] Jia, Yong-Yan Xie, Xin-Nian Yang, Huai-Xia Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers There are three independent Cd(II) ions in the title complex, {[Cd(3)(C(10)H(3)O(8))(2)(H(2)O)(4)]·4H(2)O}(n), one of which is coordinated by four O atoms from three 5-carboxybenzene-1,2,4-tricarboxylate ligands and by two water molecules in a distorted octahedral geometry. The second Cd(II) ion is coordinated by five O atoms from four 5-carboxybenzene-1,2,4-tricarboxylate ligands and by one water molecule also in a distorted octahedral geometry while the third Cd(II) ion is coordinated by five O atoms from three 5-carboxybenzene-1,2,4-tricarboxylate ligands and by one water molecule in a highly distorted octahedral geometry. The 5-carboxybenzene-1,2,4-tricarboxylate ligands bridge the Cd(II) ions, resulting in the formation of a three-dimensional structure. Intra- and intermolecular O—H⋯O hydrogen bonds are present throughout the three-dimensional structure. International Union of Crystallography 2012-05-26 /pmc/articles/PMC3379128/ /pubmed/22719349 http://dx.doi.org/10.1107/S1600536812022726 Text en © Jia et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Jia, Yong-Yan Xie, Xin-Nian Yang, Huai-Xia Poly[[tetraaquabis(μ(3)-5-carboxybenzene-1,2,4-tricarboxylato)tricadmium] tetrahydrate] |
title | Poly[[tetraaquabis(μ(3)-5-carboxybenzene-1,2,4-tricarboxylato)tricadmium] tetrahydrate] |
title_full | Poly[[tetraaquabis(μ(3)-5-carboxybenzene-1,2,4-tricarboxylato)tricadmium] tetrahydrate] |
title_fullStr | Poly[[tetraaquabis(μ(3)-5-carboxybenzene-1,2,4-tricarboxylato)tricadmium] tetrahydrate] |
title_full_unstemmed | Poly[[tetraaquabis(μ(3)-5-carboxybenzene-1,2,4-tricarboxylato)tricadmium] tetrahydrate] |
title_short | Poly[[tetraaquabis(μ(3)-5-carboxybenzene-1,2,4-tricarboxylato)tricadmium] tetrahydrate] |
title_sort | poly[[tetraaquabis(μ(3)-5-carboxybenzene-1,2,4-tricarboxylato)tricadmium] tetrahydrate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379128/ https://www.ncbi.nlm.nih.gov/pubmed/22719349 http://dx.doi.org/10.1107/S1600536812022726 |
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