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Tris(2-{[2-(4-meth­oxy­phen­yl)eth­yl]imino­meth­yl}phenolato-κ(2) N,O (1))cobalt(III)

In the title compound, [Co(C(16)H(16)NO(2))(3)], the Co(III) atom is six-coordinated in an irregular octa­hedral geometry by three N,O-chelating 2-{[2-(4-meth­oxy­phen­yl)eth­yl]imino­meth­yl}phenolate groups. One of the three meth­oxy group is disordered over two sets of sites with an occupancy rat...

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Detalles Bibliográficos
Autores principales: Ourari, Ali, Ouennoughi, Yasmina, Bouacida, Sofiane
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379129/
https://www.ncbi.nlm.nih.gov/pubmed/22719350
http://dx.doi.org/10.1107/S1600536812023033
Descripción
Sumario:In the title compound, [Co(C(16)H(16)NO(2))(3)], the Co(III) atom is six-coordinated in an irregular octa­hedral geometry by three N,O-chelating 2-{[2-(4-meth­oxy­phen­yl)eth­yl]imino­meth­yl}phenolate groups. One of the three meth­oxy group is disordered over two sets of sites with an occupancy ratio of 0.768 (5):0.232 (5). The crystal packing can be described by alternating zigzag layers of organic ligands and CoN(3)O(3) octa­hedra along the c axis. There are no classical hydrogen bonds in the structure, but C—H⋯π inter­actions occur.