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Tris(2-{[2-(4-methoxyphenyl)ethyl]iminomethyl}phenolato-κ(2) N,O (1))cobalt(III)
In the title compound, [Co(C(16)H(16)NO(2))(3)], the Co(III) atom is six-coordinated in an irregular octahedral geometry by three N,O-chelating 2-{[2-(4-methoxyphenyl)ethyl]iminomethyl}phenolate groups. One of the three methoxy group is disordered over two sets of sites with an occupancy rat...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379129/ https://www.ncbi.nlm.nih.gov/pubmed/22719350 http://dx.doi.org/10.1107/S1600536812023033 |
Sumario: | In the title compound, [Co(C(16)H(16)NO(2))(3)], the Co(III) atom is six-coordinated in an irregular octahedral geometry by three N,O-chelating 2-{[2-(4-methoxyphenyl)ethyl]iminomethyl}phenolate groups. One of the three methoxy group is disordered over two sets of sites with an occupancy ratio of 0.768 (5):0.232 (5). The crystal packing can be described by alternating zigzag layers of organic ligands and CoN(3)O(3) octahedra along the c axis. There are no classical hydrogen bonds in the structure, but C—H⋯π interactions occur. |
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