Tris(2-{[2-(4-meth­oxy­phen­yl)eth­yl]imino­meth­yl}phenolato-κ(2) N,O (1))cobalt(III)

In the title compound, [Co(C(16)H(16)NO(2))(3)], the Co(III) atom is six-coordinated in an irregular octa­hedral geometry by three N,O-chelating 2-{[2-(4-meth­oxy­phen­yl)eth­yl]imino­meth­yl}phenolate groups. One of the three meth­oxy group is disordered over two sets of sites with an occupancy rat...

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Detalles Bibliográficos
Autores principales: Ourari, Ali, Ouennoughi, Yasmina, Bouacida, Sofiane
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379129/
https://www.ncbi.nlm.nih.gov/pubmed/22719350
http://dx.doi.org/10.1107/S1600536812023033
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author Ourari, Ali
Ouennoughi, Yasmina
Bouacida, Sofiane
author_facet Ourari, Ali
Ouennoughi, Yasmina
Bouacida, Sofiane
author_sort Ourari, Ali
collection PubMed
description In the title compound, [Co(C(16)H(16)NO(2))(3)], the Co(III) atom is six-coordinated in an irregular octa­hedral geometry by three N,O-chelating 2-{[2-(4-meth­oxy­phen­yl)eth­yl]imino­meth­yl}phenolate groups. One of the three meth­oxy group is disordered over two sets of sites with an occupancy ratio of 0.768 (5):0.232 (5). The crystal packing can be described by alternating zigzag layers of organic ligands and CoN(3)O(3) octa­hedra along the c axis. There are no classical hydrogen bonds in the structure, but C—H⋯π inter­actions occur.
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spelling pubmed-33791292012-06-20 Tris(2-{[2-(4-meth­oxy­phen­yl)eth­yl]imino­meth­yl}phenolato-κ(2) N,O (1))cobalt(III) Ourari, Ali Ouennoughi, Yasmina Bouacida, Sofiane Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(C(16)H(16)NO(2))(3)], the Co(III) atom is six-coordinated in an irregular octa­hedral geometry by three N,O-chelating 2-{[2-(4-meth­oxy­phen­yl)eth­yl]imino­meth­yl}phenolate groups. One of the three meth­oxy group is disordered over two sets of sites with an occupancy ratio of 0.768 (5):0.232 (5). The crystal packing can be described by alternating zigzag layers of organic ligands and CoN(3)O(3) octa­hedra along the c axis. There are no classical hydrogen bonds in the structure, but C—H⋯π inter­actions occur. International Union of Crystallography 2012-05-26 /pmc/articles/PMC3379129/ /pubmed/22719350 http://dx.doi.org/10.1107/S1600536812023033 Text en © Ourari et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ourari, Ali
Ouennoughi, Yasmina
Bouacida, Sofiane
Tris(2-{[2-(4-meth­oxy­phen­yl)eth­yl]imino­meth­yl}phenolato-κ(2) N,O (1))cobalt(III)
title Tris(2-{[2-(4-meth­oxy­phen­yl)eth­yl]imino­meth­yl}phenolato-κ(2) N,O (1))cobalt(III)
title_full Tris(2-{[2-(4-meth­oxy­phen­yl)eth­yl]imino­meth­yl}phenolato-κ(2) N,O (1))cobalt(III)
title_fullStr Tris(2-{[2-(4-meth­oxy­phen­yl)eth­yl]imino­meth­yl}phenolato-κ(2) N,O (1))cobalt(III)
title_full_unstemmed Tris(2-{[2-(4-meth­oxy­phen­yl)eth­yl]imino­meth­yl}phenolato-κ(2) N,O (1))cobalt(III)
title_short Tris(2-{[2-(4-meth­oxy­phen­yl)eth­yl]imino­meth­yl}phenolato-κ(2) N,O (1))cobalt(III)
title_sort tris(2-{[2-(4-meth­oxy­phen­yl)eth­yl]imino­meth­yl}phenolato-κ(2) n,o (1))cobalt(iii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379129/
https://www.ncbi.nlm.nih.gov/pubmed/22719350
http://dx.doi.org/10.1107/S1600536812023033
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AT bouacidasofiane tris224methoxyphenylethyliminomethylphenolatok2no1cobaltiii

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