Tris(3-chloro­pentane-2,4-dionato-κ(2) O,O′)aluminium

In the title compound, [Al(C(5)H(6)ClO(2))(3)], the Al(III) cation is situated on a twofold rotation axis and is coordinated by six O atoms from three 3-chloro­pentane-2,4-dionate ligands in an octa­hedral environment. Al—O bond lengths are in the range 1.8741 (14)–1.8772 (14) Å. In the crystal, mol...

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Detalles Bibliográficos
Autor principal: Perdih, Franc
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379131/
https://www.ncbi.nlm.nih.gov/pubmed/22719352
http://dx.doi.org/10.1107/S1600536812023203
Descripción
Sumario:In the title compound, [Al(C(5)H(6)ClO(2))(3)], the Al(III) cation is situated on a twofold rotation axis and is coordinated by six O atoms from three 3-chloro­pentane-2,4-dionate ligands in an octa­hedral environment. Al—O bond lengths are in the range 1.8741 (14)–1.8772 (14) Å. In the crystal, mol­ecules are linked via C—H⋯Cl contacts.

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