Tris(3-chloro­pentane-2,4-dionato-κ(2) O,O′)aluminium

In the title compound, [Al(C(5)H(6)ClO(2))(3)], the Al(III) cation is situated on a twofold rotation axis and is coordinated by six O atoms from three 3-chloro­pentane-2,4-dionate ligands in an octa­hedral environment. Al—O bond lengths are in the range 1.8741 (14)–1.8772 (14) Å. In the crystal, mol...

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Detalles Bibliográficos
Autor principal: Perdih, Franc
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379131/
https://www.ncbi.nlm.nih.gov/pubmed/22719352
http://dx.doi.org/10.1107/S1600536812023203
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author Perdih, Franc
author_facet Perdih, Franc
author_sort Perdih, Franc
collection PubMed
description In the title compound, [Al(C(5)H(6)ClO(2))(3)], the Al(III) cation is situated on a twofold rotation axis and is coordinated by six O atoms from three 3-chloro­pentane-2,4-dionate ligands in an octa­hedral environment. Al—O bond lengths are in the range 1.8741 (14)–1.8772 (14) Å. In the crystal, mol­ecules are linked via C—H⋯Cl contacts.
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spelling pubmed-33791312012-06-20 Tris(3-chloro­pentane-2,4-dionato-κ(2) O,O′)aluminium Perdih, Franc Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Al(C(5)H(6)ClO(2))(3)], the Al(III) cation is situated on a twofold rotation axis and is coordinated by six O atoms from three 3-chloro­pentane-2,4-dionate ligands in an octa­hedral environment. Al—O bond lengths are in the range 1.8741 (14)–1.8772 (14) Å. In the crystal, mol­ecules are linked via C—H⋯Cl contacts. International Union of Crystallography 2012-05-26 /pmc/articles/PMC3379131/ /pubmed/22719352 http://dx.doi.org/10.1107/S1600536812023203 Text en © Franc Perdih 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Perdih, Franc
Tris(3-chloro­pentane-2,4-dionato-κ(2) O,O′)aluminium
title Tris(3-chloro­pentane-2,4-dionato-κ(2) O,O′)aluminium
title_full Tris(3-chloro­pentane-2,4-dionato-κ(2) O,O′)aluminium
title_fullStr Tris(3-chloro­pentane-2,4-dionato-κ(2) O,O′)aluminium
title_full_unstemmed Tris(3-chloro­pentane-2,4-dionato-κ(2) O,O′)aluminium
title_short Tris(3-chloro­pentane-2,4-dionato-κ(2) O,O′)aluminium
title_sort tris(3-chloro­pentane-2,4-dionato-κ(2) o,o′)aluminium
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379131/
https://www.ncbi.nlm.nih.gov/pubmed/22719352
http://dx.doi.org/10.1107/S1600536812023203
work_keys_str_mv AT perdihfranc tris3chloropentane24dionatok2ooaluminium

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