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Tris(3-chloropentane-2,4-dionato-κ(2) O,O′)iron(III)
In the title compound, [Fe(C(5)H(6)ClO(2))(3)], the Fe(III) cation is situated on a twofold rotation axis and is coordinated by six O atoms from three 3-chloropentane-2,4-dionate ligands in a slightly distorted octahedral environment. Fe—O bond lengths are in the range 1.9818 (18)–1.9957 (18) Å. T...
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379132/ https://www.ncbi.nlm.nih.gov/pubmed/22719353 http://dx.doi.org/10.1107/S1600536812023215 |
| Sumario: | In the title compound, [Fe(C(5)H(6)ClO(2))(3)], the Fe(III) cation is situated on a twofold rotation axis and is coordinated by six O atoms from three 3-chloropentane-2,4-dionate ligands in a slightly distorted octahedral environment. Fe—O bond lengths are in the range 1.9818 (18)–1.9957 (18) Å. The trans O—Fe—O angles are 169.06 (13) and 171.54 (8)°, whereas the corresponding cis angles are in the range 84.81 (10)–100.68 (12)°. In the crystal, molecules are linked via C—H⋯Cl interactions. |
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