Tris(3-chloro­pentane-2,4-dionato-κ(2) O,O′)iron(III)

In the title compound, [Fe(C(5)H(6)ClO(2))(3)], the Fe(III) cation is situated on a twofold rotation axis and is coordinated by six O atoms from three 3-chloro­pentane-2,4-dionate ligands in a slightly distorted octa­hedral environment. Fe—O bond lengths are in the range 1.9818 (18)–1.9957 (18) Å. T...

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Detalles Bibliográficos
Autor principal: Perdih, Franc
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379132/
https://www.ncbi.nlm.nih.gov/pubmed/22719353
http://dx.doi.org/10.1107/S1600536812023215
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author Perdih, Franc
author_facet Perdih, Franc
author_sort Perdih, Franc
collection PubMed
description In the title compound, [Fe(C(5)H(6)ClO(2))(3)], the Fe(III) cation is situated on a twofold rotation axis and is coordinated by six O atoms from three 3-chloro­pentane-2,4-dionate ligands in a slightly distorted octa­hedral environment. Fe—O bond lengths are in the range 1.9818 (18)–1.9957 (18) Å. The trans O—Fe—O angles are 169.06 (13) and 171.54 (8)°, whereas the corresponding cis angles are in the range 84.81 (10)–100.68 (12)°. In the crystal, mol­ecules are linked via C—H⋯Cl inter­actions.
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spelling pubmed-33791322012-06-20 Tris(3-chloro­pentane-2,4-dionato-κ(2) O,O′)iron(III) Perdih, Franc Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Fe(C(5)H(6)ClO(2))(3)], the Fe(III) cation is situated on a twofold rotation axis and is coordinated by six O atoms from three 3-chloro­pentane-2,4-dionate ligands in a slightly distorted octa­hedral environment. Fe—O bond lengths are in the range 1.9818 (18)–1.9957 (18) Å. The trans O—Fe—O angles are 169.06 (13) and 171.54 (8)°, whereas the corresponding cis angles are in the range 84.81 (10)–100.68 (12)°. In the crystal, mol­ecules are linked via C—H⋯Cl inter­actions. International Union of Crystallography 2012-05-26 /pmc/articles/PMC3379132/ /pubmed/22719353 http://dx.doi.org/10.1107/S1600536812023215 Text en © Franc Perdih 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Perdih, Franc
Tris(3-chloro­pentane-2,4-dionato-κ(2) O,O′)iron(III)
title Tris(3-chloro­pentane-2,4-dionato-κ(2) O,O′)iron(III)
title_full Tris(3-chloro­pentane-2,4-dionato-κ(2) O,O′)iron(III)
title_fullStr Tris(3-chloro­pentane-2,4-dionato-κ(2) O,O′)iron(III)
title_full_unstemmed Tris(3-chloro­pentane-2,4-dionato-κ(2) O,O′)iron(III)
title_short Tris(3-chloro­pentane-2,4-dionato-κ(2) O,O′)iron(III)
title_sort tris(3-chloro­pentane-2,4-dionato-κ(2) o,o′)iron(iii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379132/
https://www.ncbi.nlm.nih.gov/pubmed/22719353
http://dx.doi.org/10.1107/S1600536812023215
work_keys_str_mv AT perdihfranc tris3chloropentane24dionatok2ooironiii

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