Bis(μ-diisopropyl­phosphanido-κ(2) P:P)bis­[hydrido(triisopropyl­phosphane-κP)platinum(II)]

In the centrosymmetric mol­ecular structure of the title compound [Pt(2)(C(6)H(14)P)(2)H(2)(C(9)H(21)P)(2)], each Pt(II) atom is bound on one side to a phosphane ligand (PiPr(3)) and a hydrido ligand. On the other side, it is bound to two phosphanide ligands (μ-PiPr(2)), which engage a bridging posi...

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Detalles Bibliográficos
Autores principales: Arnold, Nicole, Braunschweig, Holger, Damme, Alexander
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379133/
https://www.ncbi.nlm.nih.gov/pubmed/22719354
http://dx.doi.org/10.1107/S1600536812022829
Descripción
Sumario:In the centrosymmetric mol­ecular structure of the title compound [Pt(2)(C(6)H(14)P)(2)H(2)(C(9)H(21)P)(2)], each Pt(II) atom is bound on one side to a phosphane ligand (PiPr(3)) and a hydrido ligand. On the other side, it is bound to two phosphanide ligands (μ-PiPr(2)), which engage a bridging position between the two Pt(II) atoms, forming a distorted square-planar structure motif. The Pt⋯Pt distance is 3.6755 (2) Å. A comparable mol­ecular structure was observed for bis­(μ-di-tert-butyl­phosphanido)bis­[hydrido(triethyl­phosphane)platinum(II)] [Itazaki et al. (2004 ▶). Organometallics, 23, 1610–1621].

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