Bis(μ-diisopropyl­phosphanido-κ(2) P:P)bis­[hydrido(triisopropyl­phosphane-κP)platinum(II)]

In the centrosymmetric mol­ecular structure of the title compound [Pt(2)(C(6)H(14)P)(2)H(2)(C(9)H(21)P)(2)], each Pt(II) atom is bound on one side to a phosphane ligand (PiPr(3)) and a hydrido ligand. On the other side, it is bound to two phosphanide ligands (μ-PiPr(2)), which engage a bridging posi...

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Detalles Bibliográficos
Autores principales: Arnold, Nicole, Braunschweig, Holger, Damme, Alexander
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379133/
https://www.ncbi.nlm.nih.gov/pubmed/22719354
http://dx.doi.org/10.1107/S1600536812022829
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author Arnold, Nicole
Braunschweig, Holger
Damme, Alexander
author_facet Arnold, Nicole
Braunschweig, Holger
Damme, Alexander
author_sort Arnold, Nicole
collection PubMed
description In the centrosymmetric mol­ecular structure of the title compound [Pt(2)(C(6)H(14)P)(2)H(2)(C(9)H(21)P)(2)], each Pt(II) atom is bound on one side to a phosphane ligand (PiPr(3)) and a hydrido ligand. On the other side, it is bound to two phosphanide ligands (μ-PiPr(2)), which engage a bridging position between the two Pt(II) atoms, forming a distorted square-planar structure motif. The Pt⋯Pt distance is 3.6755 (2) Å. A comparable mol­ecular structure was observed for bis­(μ-di-tert-butyl­phosphanido)bis­[hydrido(triethyl­phosphane)platinum(II)] [Itazaki et al. (2004 ▶). Organometallics, 23, 1610–1621].
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spelling pubmed-33791332012-06-20 Bis(μ-diisopropyl­phosphanido-κ(2) P:P)bis­[hydrido(triisopropyl­phosphane-κP)platinum(II)] Arnold, Nicole Braunschweig, Holger Damme, Alexander Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the centrosymmetric mol­ecular structure of the title compound [Pt(2)(C(6)H(14)P)(2)H(2)(C(9)H(21)P)(2)], each Pt(II) atom is bound on one side to a phosphane ligand (PiPr(3)) and a hydrido ligand. On the other side, it is bound to two phosphanide ligands (μ-PiPr(2)), which engage a bridging position between the two Pt(II) atoms, forming a distorted square-planar structure motif. The Pt⋯Pt distance is 3.6755 (2) Å. A comparable mol­ecular structure was observed for bis­(μ-di-tert-butyl­phosphanido)bis­[hydrido(triethyl­phosphane)platinum(II)] [Itazaki et al. (2004 ▶). Organometallics, 23, 1610–1621]. International Union of Crystallography 2012-05-26 /pmc/articles/PMC3379133/ /pubmed/22719354 http://dx.doi.org/10.1107/S1600536812022829 Text en © Arnold et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Arnold, Nicole
Braunschweig, Holger
Damme, Alexander
Bis(μ-diisopropyl­phosphanido-κ(2) P:P)bis­[hydrido(triisopropyl­phosphane-κP)platinum(II)]
title Bis(μ-diisopropyl­phosphanido-κ(2) P:P)bis­[hydrido(triisopropyl­phosphane-κP)platinum(II)]
title_full Bis(μ-diisopropyl­phosphanido-κ(2) P:P)bis­[hydrido(triisopropyl­phosphane-κP)platinum(II)]
title_fullStr Bis(μ-diisopropyl­phosphanido-κ(2) P:P)bis­[hydrido(triisopropyl­phosphane-κP)platinum(II)]
title_full_unstemmed Bis(μ-diisopropyl­phosphanido-κ(2) P:P)bis­[hydrido(triisopropyl­phosphane-κP)platinum(II)]
title_short Bis(μ-diisopropyl­phosphanido-κ(2) P:P)bis­[hydrido(triisopropyl­phosphane-κP)platinum(II)]
title_sort bis(μ-diisopropyl­phosphanido-κ(2) p:p)bis­[hydrido(triisopropyl­phosphane-κp)platinum(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379133/
https://www.ncbi.nlm.nih.gov/pubmed/22719354
http://dx.doi.org/10.1107/S1600536812022829
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