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Diaquabis{4-[(pyridin-2-yl)methylideneamino]benzenesulfonato-κ(2) N,N′}nickel(II) tetrahydrate
In the title complex, [Ni(C(12)H(9)N(2)O(3)S)(2)(H(2)O)(2)]·4H(2)O, the Ni(II) ion is coordinated by four N atoms from two bidentate chelating 4-[(pyridin-2-yl)methylideneamino]benzenesulfonate ligands and two O atoms from cis-related water molecules in a slightly distorted octahedral environm...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2012
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379134/ https://www.ncbi.nlm.nih.gov/pubmed/22719355 http://dx.doi.org/10.1107/S1600536812022179 |
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author | Li, Chao-Zhu Huang, Xue-Ren |
author_facet | Li, Chao-Zhu Huang, Xue-Ren |
author_sort | Li, Chao-Zhu |
collection | PubMed |
description | In the title complex, [Ni(C(12)H(9)N(2)O(3)S)(2)(H(2)O)(2)]·4H(2)O, the Ni(II) ion is coordinated by four N atoms from two bidentate chelating 4-[(pyridin-2-yl)methylideneamino]benzenesulfonate ligands and two O atoms from cis-related water molecules in a slightly distorted octahedral environment [Ni—N = 2.071 (3)–2.121 (3) Å and Ni—O = 2.071 (2) and 2.073 (3) Å]. In the crystal, the coordinated water molecules and the four water molecules of solvation are involved in intermolecular O—H⋯O hydrogen-bonding interactions with water and sulfonate O-atom acceptors, giving a three-dimensional framework structure. |
format | Online Article Text |
id | pubmed-3379134 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33791342012-06-20 Diaquabis{4-[(pyridin-2-yl)methylideneamino]benzenesulfonato-κ(2) N,N′}nickel(II) tetrahydrate Li, Chao-Zhu Huang, Xue-Ren Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Ni(C(12)H(9)N(2)O(3)S)(2)(H(2)O)(2)]·4H(2)O, the Ni(II) ion is coordinated by four N atoms from two bidentate chelating 4-[(pyridin-2-yl)methylideneamino]benzenesulfonate ligands and two O atoms from cis-related water molecules in a slightly distorted octahedral environment [Ni—N = 2.071 (3)–2.121 (3) Å and Ni—O = 2.071 (2) and 2.073 (3) Å]. In the crystal, the coordinated water molecules and the four water molecules of solvation are involved in intermolecular O—H⋯O hydrogen-bonding interactions with water and sulfonate O-atom acceptors, giving a three-dimensional framework structure. International Union of Crystallography 2012-05-26 /pmc/articles/PMC3379134/ /pubmed/22719355 http://dx.doi.org/10.1107/S1600536812022179 Text en © Li and Huang 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Li, Chao-Zhu Huang, Xue-Ren Diaquabis{4-[(pyridin-2-yl)methylideneamino]benzenesulfonato-κ(2) N,N′}nickel(II) tetrahydrate |
title | Diaquabis{4-[(pyridin-2-yl)methylideneamino]benzenesulfonato-κ(2)
N,N′}nickel(II) tetrahydrate |
title_full | Diaquabis{4-[(pyridin-2-yl)methylideneamino]benzenesulfonato-κ(2)
N,N′}nickel(II) tetrahydrate |
title_fullStr | Diaquabis{4-[(pyridin-2-yl)methylideneamino]benzenesulfonato-κ(2)
N,N′}nickel(II) tetrahydrate |
title_full_unstemmed | Diaquabis{4-[(pyridin-2-yl)methylideneamino]benzenesulfonato-κ(2)
N,N′}nickel(II) tetrahydrate |
title_short | Diaquabis{4-[(pyridin-2-yl)methylideneamino]benzenesulfonato-κ(2)
N,N′}nickel(II) tetrahydrate |
title_sort | diaquabis{4-[(pyridin-2-yl)methylideneamino]benzenesulfonato-κ(2)
n,n′}nickel(ii) tetrahydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379134/ https://www.ncbi.nlm.nih.gov/pubmed/22719355 http://dx.doi.org/10.1107/S1600536812022179 |
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