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Diaqua­bis­{4-[(pyridin-2-yl)methyl­idene­amino]­benzene­sulfonato-κ(2) N,N′}nickel(II) tetra­hydrate

In the title complex, [Ni(C(12)H(9)N(2)O(3)S)(2)(H(2)O)(2)]·4H(2)O, the Ni(II) ion is coordinated by four N atoms from two bidentate chelating 4-[(pyridin-2-yl)methyl­idene­amino]­benzene­sulfonate ligands and two O atoms from cis-related water mol­ecules in a slightly distorted octa­hedral environm...

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Detalles Bibliográficos
Autores principales: Li, Chao-Zhu, Huang, Xue-Ren
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379134/
https://www.ncbi.nlm.nih.gov/pubmed/22719355
http://dx.doi.org/10.1107/S1600536812022179
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author Li, Chao-Zhu
Huang, Xue-Ren
author_facet Li, Chao-Zhu
Huang, Xue-Ren
author_sort Li, Chao-Zhu
collection PubMed
description In the title complex, [Ni(C(12)H(9)N(2)O(3)S)(2)(H(2)O)(2)]·4H(2)O, the Ni(II) ion is coordinated by four N atoms from two bidentate chelating 4-[(pyridin-2-yl)methyl­idene­amino]­benzene­sulfonate ligands and two O atoms from cis-related water mol­ecules in a slightly distorted octa­hedral environment [Ni—N = 2.071 (3)–2.121 (3) Å and Ni—O = 2.071 (2) and 2.073 (3) Å]. In the crystal, the coordinated water mol­ecules and the four water mol­ecules of solvation are involved in inter­molecular O—H⋯O hydrogen-bonding inter­actions with water and sulfon­ate O-atom acceptors, giving a three-dimensional framework structure.
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spelling pubmed-33791342012-06-20 Diaqua­bis­{4-[(pyridin-2-yl)methyl­idene­amino]­benzene­sulfonato-κ(2) N,N′}nickel(II) tetra­hydrate Li, Chao-Zhu Huang, Xue-Ren Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Ni(C(12)H(9)N(2)O(3)S)(2)(H(2)O)(2)]·4H(2)O, the Ni(II) ion is coordinated by four N atoms from two bidentate chelating 4-[(pyridin-2-yl)methyl­idene­amino]­benzene­sulfonate ligands and two O atoms from cis-related water mol­ecules in a slightly distorted octa­hedral environment [Ni—N = 2.071 (3)–2.121 (3) Å and Ni—O = 2.071 (2) and 2.073 (3) Å]. In the crystal, the coordinated water mol­ecules and the four water mol­ecules of solvation are involved in inter­molecular O—H⋯O hydrogen-bonding inter­actions with water and sulfon­ate O-atom acceptors, giving a three-dimensional framework structure. International Union of Crystallography 2012-05-26 /pmc/articles/PMC3379134/ /pubmed/22719355 http://dx.doi.org/10.1107/S1600536812022179 Text en © Li and Huang 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Chao-Zhu
Huang, Xue-Ren
Diaqua­bis­{4-[(pyridin-2-yl)methyl­idene­amino]­benzene­sulfonato-κ(2) N,N′}nickel(II) tetra­hydrate
title Diaqua­bis­{4-[(pyridin-2-yl)methyl­idene­amino]­benzene­sulfonato-κ(2) N,N′}nickel(II) tetra­hydrate
title_full Diaqua­bis­{4-[(pyridin-2-yl)methyl­idene­amino]­benzene­sulfonato-κ(2) N,N′}nickel(II) tetra­hydrate
title_fullStr Diaqua­bis­{4-[(pyridin-2-yl)methyl­idene­amino]­benzene­sulfonato-κ(2) N,N′}nickel(II) tetra­hydrate
title_full_unstemmed Diaqua­bis­{4-[(pyridin-2-yl)methyl­idene­amino]­benzene­sulfonato-κ(2) N,N′}nickel(II) tetra­hydrate
title_short Diaqua­bis­{4-[(pyridin-2-yl)methyl­idene­amino]­benzene­sulfonato-κ(2) N,N′}nickel(II) tetra­hydrate
title_sort diaqua­bis­{4-[(pyridin-2-yl)methyl­idene­amino]­benzene­sulfonato-κ(2) n,n′}nickel(ii) tetra­hydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379134/
https://www.ncbi.nlm.nih.gov/pubmed/22719355
http://dx.doi.org/10.1107/S1600536812022179
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