Dibromido(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)zinc

The reaction of equimolar amounts of zinc bromide and 2,9-dimethyl-1,10-phenanthroline in dry methanol provided the title compound, [ZnBr(2)(C(14)H(12)N(2))], in good yield. The Zn(II) ion is coordinated in a distorted tetra­hedral environment by two N atoms from the chelating 2,9-dimethyl-1,10-phen...

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Autores principales: Dehghani, Ali, M. Amini, Mostafa, Najafi, Ezzatollah, Tadjarodi, Azadeh, Notash, Behrouz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379135/
https://www.ncbi.nlm.nih.gov/pubmed/22719356
http://dx.doi.org/10.1107/S1600536812022738
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author Dehghani, Ali
M. Amini, Mostafa
Najafi, Ezzatollah
Tadjarodi, Azadeh
Notash, Behrouz
author_facet Dehghani, Ali
M. Amini, Mostafa
Najafi, Ezzatollah
Tadjarodi, Azadeh
Notash, Behrouz
author_sort Dehghani, Ali
collection PubMed
description The reaction of equimolar amounts of zinc bromide and 2,9-dimethyl-1,10-phenanthroline in dry methanol provided the title compound, [ZnBr(2)(C(14)H(12)N(2))], in good yield. The Zn(II) ion is coordinated in a distorted tetra­hedral environment by two N atoms from the chelating 2,9-dimethyl-1,10-phenanthroline ligand and two bromide ions. There is inter­molecular π–π stacking between adjacent phenanthroline units, with centroid–centroid distances of 3.594 (3) and 3.652 (3) Å.
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spelling pubmed-33791352012-06-20 Dibromido(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)zinc Dehghani, Ali M. Amini, Mostafa Najafi, Ezzatollah Tadjarodi, Azadeh Notash, Behrouz Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The reaction of equimolar amounts of zinc bromide and 2,9-dimethyl-1,10-phenanthroline in dry methanol provided the title compound, [ZnBr(2)(C(14)H(12)N(2))], in good yield. The Zn(II) ion is coordinated in a distorted tetra­hedral environment by two N atoms from the chelating 2,9-dimethyl-1,10-phenanthroline ligand and two bromide ions. There is inter­molecular π–π stacking between adjacent phenanthroline units, with centroid–centroid distances of 3.594 (3) and 3.652 (3) Å. International Union of Crystallography 2012-05-26 /pmc/articles/PMC3379135/ /pubmed/22719356 http://dx.doi.org/10.1107/S1600536812022738 Text en © Dehghani et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Dehghani, Ali
M. Amini, Mostafa
Najafi, Ezzatollah
Tadjarodi, Azadeh
Notash, Behrouz
Dibromido(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)zinc
title Dibromido(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)zinc
title_full Dibromido(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)zinc
title_fullStr Dibromido(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)zinc
title_full_unstemmed Dibromido(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)zinc
title_short Dibromido(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)zinc
title_sort dibromido(2,9-dimethyl-1,10-phenanthroline-κ(2) n,n′)zinc
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379135/
https://www.ncbi.nlm.nih.gov/pubmed/22719356
http://dx.doi.org/10.1107/S1600536812022738
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