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[μ-Bis(di-o-tolyl­phosphan­yl)methane-1:2κ(2) P:P′]nona­carbonyl-1κ(3) C,2κ(3) C,3κ(3) C-(triphenyl phosphite-3κP)-triangulo-triruthenium(0) chloro­form disolvate

In the title solvated triangulo-triruthenium compound, [Ru(3)(C(18)H(15)O(3)P)(C(29)H(30)P(2))(CO)(9)]·2CHCl(3), the bis­(di-o-tolyl­phosphan­yl)methane (dtpm) ligand bridges one of the Ru—Ru bonds and the monodentate phosphine ligand bonds to the third Ru atom. All the P atoms are equatorial with r...

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Detalles Bibliográficos
Autores principales: Shawkataly, Omar bin, Khan, Imthyaz Ahmed, Sirat, Siti Syaida, Quah, Ching Kheng, Fun, Hoong-Kun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379136/
https://www.ncbi.nlm.nih.gov/pubmed/22719357
http://dx.doi.org/10.1107/S1600536812023227
Descripción
Sumario:In the title solvated triangulo-triruthenium compound, [Ru(3)(C(18)H(15)O(3)P)(C(29)H(30)P(2))(CO)(9)]·2CHCl(3), the bis­(di-o-tolyl­phosphan­yl)methane (dtpm) ligand bridges one of the Ru—Ru bonds and the monodentate phosphine ligand bonds to the third Ru atom. All the P atoms are equatorial with respect to the Ru(3) triangle: each Ru atom also bears one equatorial and two axial terminal carbonyl ligands. The dihedral angles between the two benzene rings are 75.92 (10) and 78.95 (10)° for the two diphenyl­phosphanyl groups of the dtpm ligand. In the crystal, C—H⋯O hydrogen bonds link the mol­ecules into chains along [010].