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[μ-Bis(di-o-tolylphosphanyl)methane-1:2κ(2) P:P′]nonacarbonyl-1κ(3) C,2κ(3) C,3κ(3) C-(triphenyl phosphite-3κP)-triangulo-triruthenium(0) chloroform disolvate
In the title solvated triangulo-triruthenium compound, [Ru(3)(C(18)H(15)O(3)P)(C(29)H(30)P(2))(CO)(9)]·2CHCl(3), the bis(di-o-tolylphosphanyl)methane (dtpm) ligand bridges one of the Ru—Ru bonds and the monodentate phosphine ligand bonds to the third Ru atom. All the P atoms are equatorial with r...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379136/ https://www.ncbi.nlm.nih.gov/pubmed/22719357 http://dx.doi.org/10.1107/S1600536812023227 |
| _version_ | 1782236134278955008 |
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| author | Shawkataly, Omar bin Khan, Imthyaz Ahmed Sirat, Siti Syaida Quah, Ching Kheng Fun, Hoong-Kun |
| author_facet | Shawkataly, Omar bin Khan, Imthyaz Ahmed Sirat, Siti Syaida Quah, Ching Kheng Fun, Hoong-Kun |
| author_sort | Shawkataly, Omar bin |
| collection | PubMed |
| description | In the title solvated triangulo-triruthenium compound, [Ru(3)(C(18)H(15)O(3)P)(C(29)H(30)P(2))(CO)(9)]·2CHCl(3), the bis(di-o-tolylphosphanyl)methane (dtpm) ligand bridges one of the Ru—Ru bonds and the monodentate phosphine ligand bonds to the third Ru atom. All the P atoms are equatorial with respect to the Ru(3) triangle: each Ru atom also bears one equatorial and two axial terminal carbonyl ligands. The dihedral angles between the two benzene rings are 75.92 (10) and 78.95 (10)° for the two diphenylphosphanyl groups of the dtpm ligand. In the crystal, C—H⋯O hydrogen bonds link the molecules into chains along [010]. |
| format | Online Article Text |
| id | pubmed-3379136 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-33791362012-06-20 [μ-Bis(di-o-tolylphosphanyl)methane-1:2κ(2) P:P′]nonacarbonyl-1κ(3) C,2κ(3) C,3κ(3) C-(triphenyl phosphite-3κP)-triangulo-triruthenium(0) chloroform disolvate Shawkataly, Omar bin Khan, Imthyaz Ahmed Sirat, Siti Syaida Quah, Ching Kheng Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title solvated triangulo-triruthenium compound, [Ru(3)(C(18)H(15)O(3)P)(C(29)H(30)P(2))(CO)(9)]·2CHCl(3), the bis(di-o-tolylphosphanyl)methane (dtpm) ligand bridges one of the Ru—Ru bonds and the monodentate phosphine ligand bonds to the third Ru atom. All the P atoms are equatorial with respect to the Ru(3) triangle: each Ru atom also bears one equatorial and two axial terminal carbonyl ligands. The dihedral angles between the two benzene rings are 75.92 (10) and 78.95 (10)° for the two diphenylphosphanyl groups of the dtpm ligand. In the crystal, C—H⋯O hydrogen bonds link the molecules into chains along [010]. International Union of Crystallography 2012-05-26 /pmc/articles/PMC3379136/ /pubmed/22719357 http://dx.doi.org/10.1107/S1600536812023227 Text en © Shawkataly et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Shawkataly, Omar bin Khan, Imthyaz Ahmed Sirat, Siti Syaida Quah, Ching Kheng Fun, Hoong-Kun [μ-Bis(di-o-tolylphosphanyl)methane-1:2κ(2) P:P′]nonacarbonyl-1κ(3) C,2κ(3) C,3κ(3) C-(triphenyl phosphite-3κP)-triangulo-triruthenium(0) chloroform disolvate |
| title | [μ-Bis(di-o-tolylphosphanyl)methane-1:2κ(2)
P:P′]nonacarbonyl-1κ(3)
C,2κ(3)
C,3κ(3)
C-(triphenyl phosphite-3κP)-triangulo-triruthenium(0) chloroform disolvate |
| title_full | [μ-Bis(di-o-tolylphosphanyl)methane-1:2κ(2)
P:P′]nonacarbonyl-1κ(3)
C,2κ(3)
C,3κ(3)
C-(triphenyl phosphite-3κP)-triangulo-triruthenium(0) chloroform disolvate |
| title_fullStr | [μ-Bis(di-o-tolylphosphanyl)methane-1:2κ(2)
P:P′]nonacarbonyl-1κ(3)
C,2κ(3)
C,3κ(3)
C-(triphenyl phosphite-3κP)-triangulo-triruthenium(0) chloroform disolvate |
| title_full_unstemmed | [μ-Bis(di-o-tolylphosphanyl)methane-1:2κ(2)
P:P′]nonacarbonyl-1κ(3)
C,2κ(3)
C,3κ(3)
C-(triphenyl phosphite-3κP)-triangulo-triruthenium(0) chloroform disolvate |
| title_short | [μ-Bis(di-o-tolylphosphanyl)methane-1:2κ(2)
P:P′]nonacarbonyl-1κ(3)
C,2κ(3)
C,3κ(3)
C-(triphenyl phosphite-3κP)-triangulo-triruthenium(0) chloroform disolvate |
| title_sort | [μ-bis(di-o-tolylphosphanyl)methane-1:2κ(2)
p:p′]nonacarbonyl-1κ(3)
c,2κ(3)
c,3κ(3)
c-(triphenyl phosphite-3κp)-triangulo-triruthenium(0) chloroform disolvate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379136/ https://www.ncbi.nlm.nih.gov/pubmed/22719357 http://dx.doi.org/10.1107/S1600536812023227 |
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