Cargando…
Dichloridobis(methanol-κO)[cis-(±)-2,4,5-tris(pyridin-2-yl)-2-imidazoline-κ(3) N (2),N (3),N (4)]ytterbium(III) chloride
In the crystal structure of the title complex, [YbCl(2)(C(18)H(15)N(5))(CH(3)OH)(2)]Cl, the pseudo-pentagonal–bipyramidal coordination geometry of the Yb(III) cation is composed of three N atoms from one cis-(±)-2,4,5-tris(pyridin-2-yl)imidazoline (HL) ligand, two O atoms from two methanol molecu...
| Autores principales: | , , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379138/ https://www.ncbi.nlm.nih.gov/pubmed/22719359 http://dx.doi.org/10.1107/S1600536812022052 |
| _version_ | 1782236134738231296 |
|---|---|
| author | Baez-Castro, Alberto Höpfl, Herbert Parra-Hake, Miguel Cruz-Enriquez, Adriana Campos-Gaxiola, Jose J. |
| author_facet | Baez-Castro, Alberto Höpfl, Herbert Parra-Hake, Miguel Cruz-Enriquez, Adriana Campos-Gaxiola, Jose J. |
| author_sort | Baez-Castro, Alberto |
| collection | PubMed |
| description | In the crystal structure of the title complex, [YbCl(2)(C(18)H(15)N(5))(CH(3)OH)(2)]Cl, the pseudo-pentagonal–bipyramidal coordination geometry of the Yb(III) cation is composed of three N atoms from one cis-(±)-2,4,5-tris(pyridin-2-yl)imidazoline (HL) ligand, two O atoms from two methanol molecules and two Cl(−) anions. Chains are formed along [010] through N—H⋯Cl, O—H⋯Cl and O—H⋯N hydrogen bonds. |
| format | Online Article Text |
| id | pubmed-3379138 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-33791382012-06-20 Dichloridobis(methanol-κO)[cis-(±)-2,4,5-tris(pyridin-2-yl)-2-imidazoline-κ(3) N (2),N (3),N (4)]ytterbium(III) chloride Baez-Castro, Alberto Höpfl, Herbert Parra-Hake, Miguel Cruz-Enriquez, Adriana Campos-Gaxiola, Jose J. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title complex, [YbCl(2)(C(18)H(15)N(5))(CH(3)OH)(2)]Cl, the pseudo-pentagonal–bipyramidal coordination geometry of the Yb(III) cation is composed of three N atoms from one cis-(±)-2,4,5-tris(pyridin-2-yl)imidazoline (HL) ligand, two O atoms from two methanol molecules and two Cl(−) anions. Chains are formed along [010] through N—H⋯Cl, O—H⋯Cl and O—H⋯N hydrogen bonds. International Union of Crystallography 2012-05-26 /pmc/articles/PMC3379138/ /pubmed/22719359 http://dx.doi.org/10.1107/S1600536812022052 Text en © Baez-Castro et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Baez-Castro, Alberto Höpfl, Herbert Parra-Hake, Miguel Cruz-Enriquez, Adriana Campos-Gaxiola, Jose J. Dichloridobis(methanol-κO)[cis-(±)-2,4,5-tris(pyridin-2-yl)-2-imidazoline-κ(3) N (2),N (3),N (4)]ytterbium(III) chloride |
| title | Dichloridobis(methanol-κO)[cis-(±)-2,4,5-tris(pyridin-2-yl)-2-imidazoline-κ(3)
N
(2),N
(3),N
(4)]ytterbium(III) chloride |
| title_full | Dichloridobis(methanol-κO)[cis-(±)-2,4,5-tris(pyridin-2-yl)-2-imidazoline-κ(3)
N
(2),N
(3),N
(4)]ytterbium(III) chloride |
| title_fullStr | Dichloridobis(methanol-κO)[cis-(±)-2,4,5-tris(pyridin-2-yl)-2-imidazoline-κ(3)
N
(2),N
(3),N
(4)]ytterbium(III) chloride |
| title_full_unstemmed | Dichloridobis(methanol-κO)[cis-(±)-2,4,5-tris(pyridin-2-yl)-2-imidazoline-κ(3)
N
(2),N
(3),N
(4)]ytterbium(III) chloride |
| title_short | Dichloridobis(methanol-κO)[cis-(±)-2,4,5-tris(pyridin-2-yl)-2-imidazoline-κ(3)
N
(2),N
(3),N
(4)]ytterbium(III) chloride |
| title_sort | dichloridobis(methanol-κo)[cis-(±)-2,4,5-tris(pyridin-2-yl)-2-imidazoline-κ(3)
n
(2),n
(3),n
(4)]ytterbium(iii) chloride |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379138/ https://www.ncbi.nlm.nih.gov/pubmed/22719359 http://dx.doi.org/10.1107/S1600536812022052 |
| work_keys_str_mv | AT baezcastroalberto dichloridobismethanolkocis245trispyridin2yl2imidazolinek3n2n3n4ytterbiumiiichloride AT hopflherbert dichloridobismethanolkocis245trispyridin2yl2imidazolinek3n2n3n4ytterbiumiiichloride AT parrahakemiguel dichloridobismethanolkocis245trispyridin2yl2imidazolinek3n2n3n4ytterbiumiiichloride AT cruzenriquezadriana dichloridobismethanolkocis245trispyridin2yl2imidazolinek3n2n3n4ytterbiumiiichloride AT camposgaxiolajosej dichloridobismethanolkocis245trispyridin2yl2imidazolinek3n2n3n4ytterbiumiiichloride |