Cargando…

Tetra­aqua­bis­(N,N-dimethyl­formamide-κO)zinc(II) bis­[(2-{3-[2-(carboxyl­ato­meth­oxy-κ(2) O,O′)phen­yl]pyrazol-1-yl-κN (2)}acetato-κO)chloridozincate(II)]

The asymmetric unit of the title compound, [Zn(C(3)H(7)NO)(2)(H(2)O)(4)][Zn(C(13)H(10)N(2)O(5))Cl](2), is composed of a single anion and half a cation. The Zn(II) atom in the monoanion has a distorted triganol–pyramidal geometry, being coordinated by three O atoms and one N atom from one 2-{3-[2-(ca...

Descripción completa

Detalles Bibliográficos
Autores principales: Yang, Jie, Shen, Lei, Ji, Cheng, Shen, Xiao-Feng, Yang, Gao-Weng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379139/
https://www.ncbi.nlm.nih.gov/pubmed/22719360
http://dx.doi.org/10.1107/S1600536812023045
Descripción
Sumario:The asymmetric unit of the title compound, [Zn(C(3)H(7)NO)(2)(H(2)O)(4)][Zn(C(13)H(10)N(2)O(5))Cl](2), is composed of a single anion and half a cation. The Zn(II) atom in the monoanion has a distorted triganol–pyramidal geometry, being coordinated by three O atoms and one N atom from one 2-{3-[2-(carboxyl­ato­meth­oxy)phen­yl]pyrazol-1-yl}acetate ligand and one Cl atom. In the dication, the Zn(II) atom is located on an inversion center and is coordinated by six O atoms in a slightly distorted octa­hedral geometry. In the crystal, the ions are linked by O—H⋯O hydrogen bonds, forming a two-dimensional network lying parallel to the ab plane. There are also C—H⋯O and C—H⋯Cl inter­actions present, which lead to the formation of a three-dimensional structure.