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Tetraaquabis(N,N-dimethylformamide-κO)zinc(II) bis[(2-{3-[2-(carboxylatomethoxy-κ(2) O,O′)phenyl]pyrazol-1-yl-κN (2)}acetato-κO)chloridozincate(II)]
The asymmetric unit of the title compound, [Zn(C(3)H(7)NO)(2)(H(2)O)(4)][Zn(C(13)H(10)N(2)O(5))Cl](2), is composed of a single anion and half a cation. The Zn(II) atom in the monoanion has a distorted triganol–pyramidal geometry, being coordinated by three O atoms and one N atom from one 2-{3-[2-(ca...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379139/ https://www.ncbi.nlm.nih.gov/pubmed/22719360 http://dx.doi.org/10.1107/S1600536812023045 |
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author | Yang, Jie Shen, Lei Ji, Cheng Shen, Xiao-Feng Yang, Gao-Weng |
author_facet | Yang, Jie Shen, Lei Ji, Cheng Shen, Xiao-Feng Yang, Gao-Weng |
author_sort | Yang, Jie |
collection | PubMed |
description | The asymmetric unit of the title compound, [Zn(C(3)H(7)NO)(2)(H(2)O)(4)][Zn(C(13)H(10)N(2)O(5))Cl](2), is composed of a single anion and half a cation. The Zn(II) atom in the monoanion has a distorted triganol–pyramidal geometry, being coordinated by three O atoms and one N atom from one 2-{3-[2-(carboxylatomethoxy)phenyl]pyrazol-1-yl}acetate ligand and one Cl atom. In the dication, the Zn(II) atom is located on an inversion center and is coordinated by six O atoms in a slightly distorted octahedral geometry. In the crystal, the ions are linked by O—H⋯O hydrogen bonds, forming a two-dimensional network lying parallel to the ab plane. There are also C—H⋯O and C—H⋯Cl interactions present, which lead to the formation of a three-dimensional structure. |
format | Online Article Text |
id | pubmed-3379139 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33791392012-06-20 Tetraaquabis(N,N-dimethylformamide-κO)zinc(II) bis[(2-{3-[2-(carboxylatomethoxy-κ(2) O,O′)phenyl]pyrazol-1-yl-κN (2)}acetato-κO)chloridozincate(II)] Yang, Jie Shen, Lei Ji, Cheng Shen, Xiao-Feng Yang, Gao-Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Zn(C(3)H(7)NO)(2)(H(2)O)(4)][Zn(C(13)H(10)N(2)O(5))Cl](2), is composed of a single anion and half a cation. The Zn(II) atom in the monoanion has a distorted triganol–pyramidal geometry, being coordinated by three O atoms and one N atom from one 2-{3-[2-(carboxylatomethoxy)phenyl]pyrazol-1-yl}acetate ligand and one Cl atom. In the dication, the Zn(II) atom is located on an inversion center and is coordinated by six O atoms in a slightly distorted octahedral geometry. In the crystal, the ions are linked by O—H⋯O hydrogen bonds, forming a two-dimensional network lying parallel to the ab plane. There are also C—H⋯O and C—H⋯Cl interactions present, which lead to the formation of a three-dimensional structure. International Union of Crystallography 2012-05-26 /pmc/articles/PMC3379139/ /pubmed/22719360 http://dx.doi.org/10.1107/S1600536812023045 Text en © Yang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Yang, Jie Shen, Lei Ji, Cheng Shen, Xiao-Feng Yang, Gao-Weng Tetraaquabis(N,N-dimethylformamide-κO)zinc(II) bis[(2-{3-[2-(carboxylatomethoxy-κ(2) O,O′)phenyl]pyrazol-1-yl-κN (2)}acetato-κO)chloridozincate(II)] |
title | Tetraaquabis(N,N-dimethylformamide-κO)zinc(II) bis[(2-{3-[2-(carboxylatomethoxy-κ(2)
O,O′)phenyl]pyrazol-1-yl-κN
(2)}acetato-κO)chloridozincate(II)] |
title_full | Tetraaquabis(N,N-dimethylformamide-κO)zinc(II) bis[(2-{3-[2-(carboxylatomethoxy-κ(2)
O,O′)phenyl]pyrazol-1-yl-κN
(2)}acetato-κO)chloridozincate(II)] |
title_fullStr | Tetraaquabis(N,N-dimethylformamide-κO)zinc(II) bis[(2-{3-[2-(carboxylatomethoxy-κ(2)
O,O′)phenyl]pyrazol-1-yl-κN
(2)}acetato-κO)chloridozincate(II)] |
title_full_unstemmed | Tetraaquabis(N,N-dimethylformamide-κO)zinc(II) bis[(2-{3-[2-(carboxylatomethoxy-κ(2)
O,O′)phenyl]pyrazol-1-yl-κN
(2)}acetato-κO)chloridozincate(II)] |
title_short | Tetraaquabis(N,N-dimethylformamide-κO)zinc(II) bis[(2-{3-[2-(carboxylatomethoxy-κ(2)
O,O′)phenyl]pyrazol-1-yl-κN
(2)}acetato-κO)chloridozincate(II)] |
title_sort | tetraaquabis(n,n-dimethylformamide-κo)zinc(ii) bis[(2-{3-[2-(carboxylatomethoxy-κ(2)
o,o′)phenyl]pyrazol-1-yl-κn
(2)}acetato-κo)chloridozincate(ii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379139/ https://www.ncbi.nlm.nih.gov/pubmed/22719360 http://dx.doi.org/10.1107/S1600536812023045 |
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