Bis(2-amino-1,3-benzothia­zol-3-ium) bis­(7-oxabicyclo­[2.2.1]heptane-2,3-dicarboxyl­ato)cadmate hexa­hydrate

In the structure of the title complex, (C(7)H(7)N(2)S)(2)[Cd(C(8)H(8)O(5))(2)]·6H(2)O, the Cd(II) atom is located on an inversion center and is O,O′,O′′-chelated by two symmetry-related 7-oxabicyclo­[2.2.1]heptane-2,3-dicarboxyl­ate ligands in a distorted octa­hedral geometry. The 2-amino­benzothia­...

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Detalles Bibliográficos
Autores principales: Zhang, Fan, Lin, Qiu-Yue, Chen, Ling-Ling, Ke, Jun-Gang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379140/
https://www.ncbi.nlm.nih.gov/pubmed/22719361
http://dx.doi.org/10.1107/S1600536812022593
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author Zhang, Fan
Lin, Qiu-Yue
Chen, Ling-Ling
Ke, Jun-Gang
author_facet Zhang, Fan
Lin, Qiu-Yue
Chen, Ling-Ling
Ke, Jun-Gang
author_sort Zhang, Fan
collection PubMed
description In the structure of the title complex, (C(7)H(7)N(2)S)(2)[Cd(C(8)H(8)O(5))(2)]·6H(2)O, the Cd(II) atom is located on an inversion center and is O,O′,O′′-chelated by two symmetry-related 7-oxabicyclo­[2.2.1]heptane-2,3-dicarboxyl­ate ligands in a distorted octa­hedral geometry. The 2-amino­benzothia­zolium cation links with the Cd complex anion via N—H⋯O hydrogen bonding. Extensive O—H⋯O and N—H⋯O hydrogen bonds involving lattice water mol­ecules occur in the crystal structure.
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spelling pubmed-33791402012-06-20 Bis(2-amino-1,3-benzothia­zol-3-ium) bis­(7-oxabicyclo­[2.2.1]heptane-2,3-dicarboxyl­ato)cadmate hexa­hydrate Zhang, Fan Lin, Qiu-Yue Chen, Ling-Ling Ke, Jun-Gang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the structure of the title complex, (C(7)H(7)N(2)S)(2)[Cd(C(8)H(8)O(5))(2)]·6H(2)O, the Cd(II) atom is located on an inversion center and is O,O′,O′′-chelated by two symmetry-related 7-oxabicyclo­[2.2.1]heptane-2,3-dicarboxyl­ate ligands in a distorted octa­hedral geometry. The 2-amino­benzothia­zolium cation links with the Cd complex anion via N—H⋯O hydrogen bonding. Extensive O—H⋯O and N—H⋯O hydrogen bonds involving lattice water mol­ecules occur in the crystal structure. International Union of Crystallography 2012-05-26 /pmc/articles/PMC3379140/ /pubmed/22719361 http://dx.doi.org/10.1107/S1600536812022593 Text en © Zhang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Fan
Lin, Qiu-Yue
Chen, Ling-Ling
Ke, Jun-Gang
Bis(2-amino-1,3-benzothia­zol-3-ium) bis­(7-oxabicyclo­[2.2.1]heptane-2,3-dicarboxyl­ato)cadmate hexa­hydrate
title Bis(2-amino-1,3-benzothia­zol-3-ium) bis­(7-oxabicyclo­[2.2.1]heptane-2,3-dicarboxyl­ato)cadmate hexa­hydrate
title_full Bis(2-amino-1,3-benzothia­zol-3-ium) bis­(7-oxabicyclo­[2.2.1]heptane-2,3-dicarboxyl­ato)cadmate hexa­hydrate
title_fullStr Bis(2-amino-1,3-benzothia­zol-3-ium) bis­(7-oxabicyclo­[2.2.1]heptane-2,3-dicarboxyl­ato)cadmate hexa­hydrate
title_full_unstemmed Bis(2-amino-1,3-benzothia­zol-3-ium) bis­(7-oxabicyclo­[2.2.1]heptane-2,3-dicarboxyl­ato)cadmate hexa­hydrate
title_short Bis(2-amino-1,3-benzothia­zol-3-ium) bis­(7-oxabicyclo­[2.2.1]heptane-2,3-dicarboxyl­ato)cadmate hexa­hydrate
title_sort bis(2-amino-1,3-benzothia­zol-3-ium) bis­(7-oxabicyclo­[2.2.1]heptane-2,3-dicarboxyl­ato)cadmate hexa­hydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379140/
https://www.ncbi.nlm.nih.gov/pubmed/22719361
http://dx.doi.org/10.1107/S1600536812022593
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