Bis[4-(2-aza­niumyleth­yl)piperazin-1-ium] di-μ-sulfido-bis­[disulfido­germanate(II)]

In the title compound, (C(6)H(17)N(3))(2)[Ge(2)S(6)], the dimeric [Ge(2)S(6)](4−) anion is formed by two edge-sharing GeS(4) tetra­hedral units. The average terminal and bridging Ge—S bond lengths are 2.164 (2) and 2.272 (8) Å, respectively. The dimeric inorganic anions and the organic piperazinium...

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Detalles Bibliográficos
Autores principales: Zhang, Bei-Bei, Xu, Chao, Duan, Taike, Chen, Qun, Zhang, Qian-Feng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379143/
https://www.ncbi.nlm.nih.gov/pubmed/22719364
http://dx.doi.org/10.1107/S1600536812022040
Descripción
Sumario:In the title compound, (C(6)H(17)N(3))(2)[Ge(2)S(6)], the dimeric [Ge(2)S(6)](4−) anion is formed by two edge-sharing GeS(4) tetra­hedral units. The average terminal and bridging Ge—S bond lengths are 2.164 (2) and 2.272 (8) Å, respectively. The dimeric inorganic anions and the organic piperazinium cations are organized into a three-dimensional network by N—H⋯S hydrogen bonds.

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