Hexa­kis­(dimethyl­formamide-κO)manganese(II) (dimethyl­formamide-κO)pentakis(­thio­cyanato­-κN)chromate(III)

The title compound, [Mn(C(3)H(7)NO)(6)][Cr(NCS)(5)(C(3)H(7)NO)], was obtained unintentionally as a product of an attempted synthesis of heterometallic complexes based on Reineckes anion using manganese powder, Reineckes salt and 1-(2-hy­droxy­eth­yl)tetra­zole as starting materials. The crystal stru...

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Detalles Bibliográficos
Autores principales: Semenaka, Valentyna V., Nesterova, Oksana V., Kokozay, Vladimir N., Omelchenko, Irina V., Shishkin, Oleg V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379144/
https://www.ncbi.nlm.nih.gov/pubmed/22719365
http://dx.doi.org/10.1107/S1600536812023069
Descripción
Sumario:The title compound, [Mn(C(3)H(7)NO)(6)][Cr(NCS)(5)(C(3)H(7)NO)], was obtained unintentionally as a product of an attempted synthesis of heterometallic complexes based on Reineckes anion using manganese powder, Reineckes salt and 1-(2-hy­droxy­eth­yl)tetra­zole as starting materials. The crystal structure of the complex consists of an [Mn(dmf)(6)](2+) cation and a [Cr(NCS)(5)(dmf)](2−) anion (dmf = dimethyl­formamide). The Mn(II) and Cr(III) atoms show a slightly distorted octa­hedral MnO(6) and CrN(5)O coordination geometries with adjacent angles in the range 85.29 (13)–95.96 (14)°.

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