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Hexakis(dimethylformamide-κO)manganese(II) (dimethylformamide-κO)pentakis(thiocyanato-κN)chromate(III)
The title compound, [Mn(C(3)H(7)NO)(6)][Cr(NCS)(5)(C(3)H(7)NO)], was obtained unintentionally as a product of an attempted synthesis of heterometallic complexes based on Reineckes anion using manganese powder, Reineckes salt and 1-(2-hydroxyethyl)tetrazole as starting materials. The crystal stru...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379144/ https://www.ncbi.nlm.nih.gov/pubmed/22719365 http://dx.doi.org/10.1107/S1600536812023069 |
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| author | Semenaka, Valentyna V. Nesterova, Oksana V. Kokozay, Vladimir N. Omelchenko, Irina V. Shishkin, Oleg V. |
| author_facet | Semenaka, Valentyna V. Nesterova, Oksana V. Kokozay, Vladimir N. Omelchenko, Irina V. Shishkin, Oleg V. |
| author_sort | Semenaka, Valentyna V. |
| collection | PubMed |
| description | The title compound, [Mn(C(3)H(7)NO)(6)][Cr(NCS)(5)(C(3)H(7)NO)], was obtained unintentionally as a product of an attempted synthesis of heterometallic complexes based on Reineckes anion using manganese powder, Reineckes salt and 1-(2-hydroxyethyl)tetrazole as starting materials. The crystal structure of the complex consists of an [Mn(dmf)(6)](2+) cation and a [Cr(NCS)(5)(dmf)](2−) anion (dmf = dimethylformamide). The Mn(II) and Cr(III) atoms show a slightly distorted octahedral MnO(6) and CrN(5)O coordination geometries with adjacent angles in the range 85.29 (13)–95.96 (14)°. |
| format | Online Article Text |
| id | pubmed-3379144 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-33791442012-06-20 Hexakis(dimethylformamide-κO)manganese(II) (dimethylformamide-κO)pentakis(thiocyanato-κN)chromate(III) Semenaka, Valentyna V. Nesterova, Oksana V. Kokozay, Vladimir N. Omelchenko, Irina V. Shishkin, Oleg V. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Mn(C(3)H(7)NO)(6)][Cr(NCS)(5)(C(3)H(7)NO)], was obtained unintentionally as a product of an attempted synthesis of heterometallic complexes based on Reineckes anion using manganese powder, Reineckes salt and 1-(2-hydroxyethyl)tetrazole as starting materials. The crystal structure of the complex consists of an [Mn(dmf)(6)](2+) cation and a [Cr(NCS)(5)(dmf)](2−) anion (dmf = dimethylformamide). The Mn(II) and Cr(III) atoms show a slightly distorted octahedral MnO(6) and CrN(5)O coordination geometries with adjacent angles in the range 85.29 (13)–95.96 (14)°. International Union of Crystallography 2012-05-26 /pmc/articles/PMC3379144/ /pubmed/22719365 http://dx.doi.org/10.1107/S1600536812023069 Text en © Semenaka et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Semenaka, Valentyna V. Nesterova, Oksana V. Kokozay, Vladimir N. Omelchenko, Irina V. Shishkin, Oleg V. Hexakis(dimethylformamide-κO)manganese(II) (dimethylformamide-κO)pentakis(thiocyanato-κN)chromate(III) |
| title | Hexakis(dimethylformamide-κO)manganese(II) (dimethylformamide-κO)pentakis(thiocyanato-κN)chromate(III) |
| title_full | Hexakis(dimethylformamide-κO)manganese(II) (dimethylformamide-κO)pentakis(thiocyanato-κN)chromate(III) |
| title_fullStr | Hexakis(dimethylformamide-κO)manganese(II) (dimethylformamide-κO)pentakis(thiocyanato-κN)chromate(III) |
| title_full_unstemmed | Hexakis(dimethylformamide-κO)manganese(II) (dimethylformamide-κO)pentakis(thiocyanato-κN)chromate(III) |
| title_short | Hexakis(dimethylformamide-κO)manganese(II) (dimethylformamide-κO)pentakis(thiocyanato-κN)chromate(III) |
| title_sort | hexakis(dimethylformamide-κo)manganese(ii) (dimethylformamide-κo)pentakis(thiocyanato-κn)chromate(iii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379144/ https://www.ncbi.nlm.nih.gov/pubmed/22719365 http://dx.doi.org/10.1107/S1600536812023069 |
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