Diaqua­bis­(2,2′-bi-1H-imidazole)­man­ganese(II) benzene-1,4-di­carboxyl­ate

The asymmetric unit of the title compound, [Mn(C(6)H(6)N(4))(2)(H(2)O)(2)](C(8)H(4)O(4)), contains one-half each of the centrosymmetric cation and anion. The Mn(II) atom is coordinated by four N atoms [Mn—N = 2.2168 (14) and 2.2407 (14) Å] from two 2,2′-biimidazole ligands and two water mol­ecules [...

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Detalles Bibliográficos
Autores principales: Yang, Lining, Zhi, Yanxiang, Hei, Jiahui, Miao, Yanqing
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379148/
https://www.ncbi.nlm.nih.gov/pubmed/22719369
http://dx.doi.org/10.1107/S160053681202199X
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author Yang, Lining
Zhi, Yanxiang
Hei, Jiahui
Miao, Yanqing
author_facet Yang, Lining
Zhi, Yanxiang
Hei, Jiahui
Miao, Yanqing
author_sort Yang, Lining
collection PubMed
description The asymmetric unit of the title compound, [Mn(C(6)H(6)N(4))(2)(H(2)O)(2)](C(8)H(4)O(4)), contains one-half each of the centrosymmetric cation and anion. The Mn(II) atom is coordinated by four N atoms [Mn—N = 2.2168 (14) and 2.2407 (14) Å] from two 2,2′-biimidazole ligands and two water mol­ecules [Mn—O = 2.2521 (14) Å] in a distorted octa­hedral geometry. Inter­molecular N—H⋯O and O—H⋯O hydrogen bonds consol­idate the crystal packing, which also exhibits π–π inter­actions between five-membered rings, with a centroid–centroid distance of 3.409 (2) Å.
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spelling pubmed-33791482012-06-20 Diaqua­bis­(2,2′-bi-1H-imidazole)­man­ganese(II) benzene-1,4-di­carboxyl­ate Yang, Lining Zhi, Yanxiang Hei, Jiahui Miao, Yanqing Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Mn(C(6)H(6)N(4))(2)(H(2)O)(2)](C(8)H(4)O(4)), contains one-half each of the centrosymmetric cation and anion. The Mn(II) atom is coordinated by four N atoms [Mn—N = 2.2168 (14) and 2.2407 (14) Å] from two 2,2′-biimidazole ligands and two water mol­ecules [Mn—O = 2.2521 (14) Å] in a distorted octa­hedral geometry. Inter­molecular N—H⋯O and O—H⋯O hydrogen bonds consol­idate the crystal packing, which also exhibits π–π inter­actions between five-membered rings, with a centroid–centroid distance of 3.409 (2) Å. International Union of Crystallography 2012-05-26 /pmc/articles/PMC3379148/ /pubmed/22719369 http://dx.doi.org/10.1107/S160053681202199X Text en © Yang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yang, Lining
Zhi, Yanxiang
Hei, Jiahui
Miao, Yanqing
Diaqua­bis­(2,2′-bi-1H-imidazole)­man­ganese(II) benzene-1,4-di­carboxyl­ate
title Diaqua­bis­(2,2′-bi-1H-imidazole)­man­ganese(II) benzene-1,4-di­carboxyl­ate
title_full Diaqua­bis­(2,2′-bi-1H-imidazole)­man­ganese(II) benzene-1,4-di­carboxyl­ate
title_fullStr Diaqua­bis­(2,2′-bi-1H-imidazole)­man­ganese(II) benzene-1,4-di­carboxyl­ate
title_full_unstemmed Diaqua­bis­(2,2′-bi-1H-imidazole)­man­ganese(II) benzene-1,4-di­carboxyl­ate
title_short Diaqua­bis­(2,2′-bi-1H-imidazole)­man­ganese(II) benzene-1,4-di­carboxyl­ate
title_sort diaqua­bis­(2,2′-bi-1h-imidazole)­man­ganese(ii) benzene-1,4-di­carboxyl­ate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379148/
https://www.ncbi.nlm.nih.gov/pubmed/22719369
http://dx.doi.org/10.1107/S160053681202199X
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AT miaoyanqing diaquabis22bi1himidazolemanganeseiibenzene14dicarboxylate

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