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[(Pyridine-2,6-dicarboxyl­ato)copper(II)]-μ-(pyridine-2,6-dicarboxyl­ato)-[bis­(ethyl­enediamine)­copper(II)]-μ-(pyridine-2,6-dicarboxyl­ato)-[(pyridine-2,6-dicarboxyl­ato)copper(II)] ethyl­enediamine monosolvate tetra­hydrate

The title compound, [Cu(3)(C(7)H(3)NO(4))(4)(C(2)H(8)N(2))(2)]·C(2)H(8)N(2)·4H(2)O, was obtained by the reaction of copper(II) acetate dihydrate with pyridine-2,6-dicarb­oxy­lic acid (H(2)dipic) and ethyl­enediamine (en) in an aqueous solution. All of the Cu(II) atoms in the trinuclear centrosymmetr...

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Autores principales: Shokooh Saljooghi, Amir, Amiri Rudbari, Hadi, Nicolò, Francesco, Zahmati, Maliheh, Delavar Mendi, Fatemeh
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379149/
https://www.ncbi.nlm.nih.gov/pubmed/22719370
http://dx.doi.org/10.1107/S1600536812022039
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author Shokooh Saljooghi, Amir
Amiri Rudbari, Hadi
Nicolò, Francesco
Zahmati, Maliheh
Delavar Mendi, Fatemeh
author_facet Shokooh Saljooghi, Amir
Amiri Rudbari, Hadi
Nicolò, Francesco
Zahmati, Maliheh
Delavar Mendi, Fatemeh
author_sort Shokooh Saljooghi, Amir
collection PubMed
description The title compound, [Cu(3)(C(7)H(3)NO(4))(4)(C(2)H(8)N(2))(2)]·C(2)H(8)N(2)·4H(2)O, was obtained by the reaction of copper(II) acetate dihydrate with pyridine-2,6-dicarb­oxy­lic acid (H(2)dipic) and ethyl­enediamine (en) in an aqueous solution. All of the Cu(II) atoms in the trinuclear centrosymmetric title complex are six-coordinated in a distorted octa­hedral geometry with N(2)O(4) and N(4)O(2) environments for the outer and central Cu(II) atoms, respectively. Various inter­actions, including numerous O—H⋯O and C—H⋯O hydrogen bonds and C—O⋯π stacking of the pyridine and carboxyl­ate groups [O⋯centroid distances = 3.669 (2) and 3.668 (2) Å] are observed in the crystal structure.
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spelling pubmed-33791492012-06-20 [(Pyridine-2,6-dicarboxyl­ato)copper(II)]-μ-(pyridine-2,6-dicarboxyl­ato)-[bis­(ethyl­enediamine)­copper(II)]-μ-(pyridine-2,6-dicarboxyl­ato)-[(pyridine-2,6-dicarboxyl­ato)copper(II)] ethyl­enediamine monosolvate tetra­hydrate Shokooh Saljooghi, Amir Amiri Rudbari, Hadi Nicolò, Francesco Zahmati, Maliheh Delavar Mendi, Fatemeh Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cu(3)(C(7)H(3)NO(4))(4)(C(2)H(8)N(2))(2)]·C(2)H(8)N(2)·4H(2)O, was obtained by the reaction of copper(II) acetate dihydrate with pyridine-2,6-dicarb­oxy­lic acid (H(2)dipic) and ethyl­enediamine (en) in an aqueous solution. All of the Cu(II) atoms in the trinuclear centrosymmetric title complex are six-coordinated in a distorted octa­hedral geometry with N(2)O(4) and N(4)O(2) environments for the outer and central Cu(II) atoms, respectively. Various inter­actions, including numerous O—H⋯O and C—H⋯O hydrogen bonds and C—O⋯π stacking of the pyridine and carboxyl­ate groups [O⋯centroid distances = 3.669 (2) and 3.668 (2) Å] are observed in the crystal structure. International Union of Crystallography 2012-05-26 /pmc/articles/PMC3379149/ /pubmed/22719370 http://dx.doi.org/10.1107/S1600536812022039 Text en © Shokooh Saljooghi et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Shokooh Saljooghi, Amir
Amiri Rudbari, Hadi
Nicolò, Francesco
Zahmati, Maliheh
Delavar Mendi, Fatemeh
[(Pyridine-2,6-dicarboxyl­ato)copper(II)]-μ-(pyridine-2,6-dicarboxyl­ato)-[bis­(ethyl­enediamine)­copper(II)]-μ-(pyridine-2,6-dicarboxyl­ato)-[(pyridine-2,6-dicarboxyl­ato)copper(II)] ethyl­enediamine monosolvate tetra­hydrate
title [(Pyridine-2,6-dicarboxyl­ato)copper(II)]-μ-(pyridine-2,6-dicarboxyl­ato)-[bis­(ethyl­enediamine)­copper(II)]-μ-(pyridine-2,6-dicarboxyl­ato)-[(pyridine-2,6-dicarboxyl­ato)copper(II)] ethyl­enediamine monosolvate tetra­hydrate
title_full [(Pyridine-2,6-dicarboxyl­ato)copper(II)]-μ-(pyridine-2,6-dicarboxyl­ato)-[bis­(ethyl­enediamine)­copper(II)]-μ-(pyridine-2,6-dicarboxyl­ato)-[(pyridine-2,6-dicarboxyl­ato)copper(II)] ethyl­enediamine monosolvate tetra­hydrate
title_fullStr [(Pyridine-2,6-dicarboxyl­ato)copper(II)]-μ-(pyridine-2,6-dicarboxyl­ato)-[bis­(ethyl­enediamine)­copper(II)]-μ-(pyridine-2,6-dicarboxyl­ato)-[(pyridine-2,6-dicarboxyl­ato)copper(II)] ethyl­enediamine monosolvate tetra­hydrate
title_full_unstemmed [(Pyridine-2,6-dicarboxyl­ato)copper(II)]-μ-(pyridine-2,6-dicarboxyl­ato)-[bis­(ethyl­enediamine)­copper(II)]-μ-(pyridine-2,6-dicarboxyl­ato)-[(pyridine-2,6-dicarboxyl­ato)copper(II)] ethyl­enediamine monosolvate tetra­hydrate
title_short [(Pyridine-2,6-dicarboxyl­ato)copper(II)]-μ-(pyridine-2,6-dicarboxyl­ato)-[bis­(ethyl­enediamine)­copper(II)]-μ-(pyridine-2,6-dicarboxyl­ato)-[(pyridine-2,6-dicarboxyl­ato)copper(II)] ethyl­enediamine monosolvate tetra­hydrate
title_sort [(pyridine-2,6-dicarboxyl­ato)copper(ii)]-μ-(pyridine-2,6-dicarboxyl­ato)-[bis­(ethyl­enediamine)­copper(ii)]-μ-(pyridine-2,6-dicarboxyl­ato)-[(pyridine-2,6-dicarboxyl­ato)copper(ii)] ethyl­enediamine monosolvate tetra­hydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379149/
https://www.ncbi.nlm.nih.gov/pubmed/22719370
http://dx.doi.org/10.1107/S1600536812022039
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