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Bis[trans-dichloridobis(propane-1,3-diamine-κ(2) N,N′)chromium(III)] tetrachloridozincate determined using synchrotron radiation
In the title compound, [CrCl(2)(C(3)H(10)N(2))(2)](2)[ZnCl(4)], the Cr(III) atom is coordinated by four N atoms of propane-1,3-diamine (tn) and two Cl atoms in a trans arrangement, displaying a distorted octahedral geometry with crystallographic inversion symmetry; the Zn atom in the [ZnCl(4)](2−)...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379173/ https://www.ncbi.nlm.nih.gov/pubmed/22719371 http://dx.doi.org/10.1107/S1600536812023355 |
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author | Moon, Dohyun Subhan, Md Abdus Choi, Jong-Ha |
author_facet | Moon, Dohyun Subhan, Md Abdus Choi, Jong-Ha |
author_sort | Moon, Dohyun |
collection | PubMed |
description | In the title compound, [CrCl(2)(C(3)H(10)N(2))(2)](2)[ZnCl(4)], the Cr(III) atom is coordinated by four N atoms of propane-1,3-diamine (tn) and two Cl atoms in a trans arrangement, displaying a distorted octahedral geometry with crystallographic inversion symmetry; the Zn atom in the [ZnCl(4)](2−) anion lies on a -4 axis. The orientations of the two six-membered chelate rings in the complex cation are in an anti chair–chair conformation with respect to each other. The Cr—N bond lengths are 2.087 (6) and 2.097 (6) Å. The Cr—Cl and Zn—Cl bond lengths are 2.3151 (16) and 2.3255 (13) Å, respectively. Weak intermolecular hydrogen bonds involving the tn NH(2) groups as donors and chloride ligands of the anion and cation as acceptors are observed. |
format | Online Article Text |
id | pubmed-3379173 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33791732012-06-20 Bis[trans-dichloridobis(propane-1,3-diamine-κ(2) N,N′)chromium(III)] tetrachloridozincate determined using synchrotron radiation Moon, Dohyun Subhan, Md Abdus Choi, Jong-Ha Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [CrCl(2)(C(3)H(10)N(2))(2)](2)[ZnCl(4)], the Cr(III) atom is coordinated by four N atoms of propane-1,3-diamine (tn) and two Cl atoms in a trans arrangement, displaying a distorted octahedral geometry with crystallographic inversion symmetry; the Zn atom in the [ZnCl(4)](2−) anion lies on a -4 axis. The orientations of the two six-membered chelate rings in the complex cation are in an anti chair–chair conformation with respect to each other. The Cr—N bond lengths are 2.087 (6) and 2.097 (6) Å. The Cr—Cl and Zn—Cl bond lengths are 2.3151 (16) and 2.3255 (13) Å, respectively. Weak intermolecular hydrogen bonds involving the tn NH(2) groups as donors and chloride ligands of the anion and cation as acceptors are observed. International Union of Crystallography 2012-05-26 /pmc/articles/PMC3379173/ /pubmed/22719371 http://dx.doi.org/10.1107/S1600536812023355 Text en © Moon et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Moon, Dohyun Subhan, Md Abdus Choi, Jong-Ha Bis[trans-dichloridobis(propane-1,3-diamine-κ(2) N,N′)chromium(III)] tetrachloridozincate determined using synchrotron radiation |
title | Bis[trans-dichloridobis(propane-1,3-diamine-κ(2)
N,N′)chromium(III)] tetrachloridozincate determined using synchrotron radiation |
title_full | Bis[trans-dichloridobis(propane-1,3-diamine-κ(2)
N,N′)chromium(III)] tetrachloridozincate determined using synchrotron radiation |
title_fullStr | Bis[trans-dichloridobis(propane-1,3-diamine-κ(2)
N,N′)chromium(III)] tetrachloridozincate determined using synchrotron radiation |
title_full_unstemmed | Bis[trans-dichloridobis(propane-1,3-diamine-κ(2)
N,N′)chromium(III)] tetrachloridozincate determined using synchrotron radiation |
title_short | Bis[trans-dichloridobis(propane-1,3-diamine-κ(2)
N,N′)chromium(III)] tetrachloridozincate determined using synchrotron radiation |
title_sort | bis[trans-dichloridobis(propane-1,3-diamine-κ(2)
n,n′)chromium(iii)] tetrachloridozincate determined using synchrotron radiation |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379173/ https://www.ncbi.nlm.nih.gov/pubmed/22719371 http://dx.doi.org/10.1107/S1600536812023355 |
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