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Bis[trans-dichloridobis(propane-1,3-diamine-κ(2) N,N′)chromium(III)] tetra­chloridozincate determined using synchrotron radiation

In the title compound, [CrCl(2)(C(3)H(10)N(2))(2)](2)[ZnCl(4)], the Cr(III) atom is coordinated by four N atoms of propane-1,3-diamine (tn) and two Cl atoms in a trans arrangement, displaying a distorted octa­hedral geometry with crystallographic inversion symmetry; the Zn atom in the [ZnCl(4)](2−)...

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Autores principales: Moon, Dohyun, Subhan, Md Abdus, Choi, Jong-Ha
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379173/
https://www.ncbi.nlm.nih.gov/pubmed/22719371
http://dx.doi.org/10.1107/S1600536812023355
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author Moon, Dohyun
Subhan, Md Abdus
Choi, Jong-Ha
author_facet Moon, Dohyun
Subhan, Md Abdus
Choi, Jong-Ha
author_sort Moon, Dohyun
collection PubMed
description In the title compound, [CrCl(2)(C(3)H(10)N(2))(2)](2)[ZnCl(4)], the Cr(III) atom is coordinated by four N atoms of propane-1,3-diamine (tn) and two Cl atoms in a trans arrangement, displaying a distorted octa­hedral geometry with crystallographic inversion symmetry; the Zn atom in the [ZnCl(4)](2−) anion lies on a -4 axis. The orientations of the two six-membered chelate rings in the complex cation are in an anti chair–chair conformation with respect to each other. The Cr—N bond lengths are 2.087 (6) and 2.097 (6) Å. The Cr—Cl and Zn—Cl bond lengths are 2.3151 (16) and 2.3255 (13) Å, respectively. Weak inter­molecular hydrogen bonds involving the tn NH(2) groups as donors and chloride ligands of the anion and cation as acceptors are observed.
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spelling pubmed-33791732012-06-20 Bis[trans-dichloridobis(propane-1,3-diamine-κ(2) N,N′)chromium(III)] tetra­chloridozincate determined using synchrotron radiation Moon, Dohyun Subhan, Md Abdus Choi, Jong-Ha Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [CrCl(2)(C(3)H(10)N(2))(2)](2)[ZnCl(4)], the Cr(III) atom is coordinated by four N atoms of propane-1,3-diamine (tn) and two Cl atoms in a trans arrangement, displaying a distorted octa­hedral geometry with crystallographic inversion symmetry; the Zn atom in the [ZnCl(4)](2−) anion lies on a -4 axis. The orientations of the two six-membered chelate rings in the complex cation are in an anti chair–chair conformation with respect to each other. The Cr—N bond lengths are 2.087 (6) and 2.097 (6) Å. The Cr—Cl and Zn—Cl bond lengths are 2.3151 (16) and 2.3255 (13) Å, respectively. Weak inter­molecular hydrogen bonds involving the tn NH(2) groups as donors and chloride ligands of the anion and cation as acceptors are observed. International Union of Crystallography 2012-05-26 /pmc/articles/PMC3379173/ /pubmed/22719371 http://dx.doi.org/10.1107/S1600536812023355 Text en © Moon et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Moon, Dohyun
Subhan, Md Abdus
Choi, Jong-Ha
Bis[trans-dichloridobis(propane-1,3-diamine-κ(2) N,N′)chromium(III)] tetra­chloridozincate determined using synchrotron radiation
title Bis[trans-dichloridobis(propane-1,3-diamine-κ(2) N,N′)chromium(III)] tetra­chloridozincate determined using synchrotron radiation
title_full Bis[trans-dichloridobis(propane-1,3-diamine-κ(2) N,N′)chromium(III)] tetra­chloridozincate determined using synchrotron radiation
title_fullStr Bis[trans-dichloridobis(propane-1,3-diamine-κ(2) N,N′)chromium(III)] tetra­chloridozincate determined using synchrotron radiation
title_full_unstemmed Bis[trans-dichloridobis(propane-1,3-diamine-κ(2) N,N′)chromium(III)] tetra­chloridozincate determined using synchrotron radiation
title_short Bis[trans-dichloridobis(propane-1,3-diamine-κ(2) N,N′)chromium(III)] tetra­chloridozincate determined using synchrotron radiation
title_sort bis[trans-dichloridobis(propane-1,3-diamine-κ(2) n,n′)chromium(iii)] tetra­chloridozincate determined using synchrotron radiation
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379173/
https://www.ncbi.nlm.nih.gov/pubmed/22719371
http://dx.doi.org/10.1107/S1600536812023355
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