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(2,3-Di-2-pyridylpyrazine-κ(2) N (2),N (3))diiodidoplatinum(II)
The Pt(II) ion in the title complex, [PtI(2)(C(14)H(10)N(4))], exists in a distorted square-planar environment defined by the two pyridine N atoms of the chelating 2,3-di-2-pyridylpyrazine ligand and two iodide anions. The pyridine rings are inclined to the least-squares plane of the PtI(2)N(2) uni...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2012
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379175/ https://www.ncbi.nlm.nih.gov/pubmed/22719373 http://dx.doi.org/10.1107/S1600536812023501 |
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author | Ha, Kwang |
author_facet | Ha, Kwang |
author_sort | Ha, Kwang |
collection | PubMed |
description | The Pt(II) ion in the title complex, [PtI(2)(C(14)H(10)N(4))], exists in a distorted square-planar environment defined by the two pyridine N atoms of the chelating 2,3-di-2-pyridylpyrazine ligand and two iodide anions. The pyridine rings are inclined to the least-squares plane of the PtI(2)N(2) unit [maximum deviation = 0.070 (3) Å] at 66.1 (2) and 65.9 (2)°; the pyrazine ring is perpendicular to this plane [dihedral angle = 89.7 (2)°]. Two intermolecular C—H⋯I hydrogen bonds, both involving the same I atom as hydrogen-bond acceptor, generate a layer structure extending parallel to (001). Molecules are stacked in columns along the a axis. Along the b axis, successive molecules stack in opposite directions. |
format | Online Article Text |
id | pubmed-3379175 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33791752012-06-20 (2,3-Di-2-pyridylpyrazine-κ(2) N (2),N (3))diiodidoplatinum(II) Ha, Kwang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Pt(II) ion in the title complex, [PtI(2)(C(14)H(10)N(4))], exists in a distorted square-planar environment defined by the two pyridine N atoms of the chelating 2,3-di-2-pyridylpyrazine ligand and two iodide anions. The pyridine rings are inclined to the least-squares plane of the PtI(2)N(2) unit [maximum deviation = 0.070 (3) Å] at 66.1 (2) and 65.9 (2)°; the pyrazine ring is perpendicular to this plane [dihedral angle = 89.7 (2)°]. Two intermolecular C—H⋯I hydrogen bonds, both involving the same I atom as hydrogen-bond acceptor, generate a layer structure extending parallel to (001). Molecules are stacked in columns along the a axis. Along the b axis, successive molecules stack in opposite directions. International Union of Crystallography 2012-05-31 /pmc/articles/PMC3379175/ /pubmed/22719373 http://dx.doi.org/10.1107/S1600536812023501 Text en © Kwang Ha 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Ha, Kwang (2,3-Di-2-pyridylpyrazine-κ(2) N (2),N (3))diiodidoplatinum(II) |
title | (2,3-Di-2-pyridylpyrazine-κ(2)
N
(2),N
(3))diiodidoplatinum(II) |
title_full | (2,3-Di-2-pyridylpyrazine-κ(2)
N
(2),N
(3))diiodidoplatinum(II) |
title_fullStr | (2,3-Di-2-pyridylpyrazine-κ(2)
N
(2),N
(3))diiodidoplatinum(II) |
title_full_unstemmed | (2,3-Di-2-pyridylpyrazine-κ(2)
N
(2),N
(3))diiodidoplatinum(II) |
title_short | (2,3-Di-2-pyridylpyrazine-κ(2)
N
(2),N
(3))diiodidoplatinum(II) |
title_sort | (2,3-di-2-pyridylpyrazine-κ(2)
n
(2),n
(3))diiodidoplatinum(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379175/ https://www.ncbi.nlm.nih.gov/pubmed/22719373 http://dx.doi.org/10.1107/S1600536812023501 |
work_keys_str_mv | AT hakwang 23di2pyridylpyrazinek2n2n3diiodidoplatinumii |