2-{2-[4-(Dimethyl­amino)­phen­yl]diazen-1-ium-1-yl}pyridinium tetra­chlorido­zincate

The title compound, (C(13)H(16)N(4))[ZnCl(4)], consists of a tetra­hedral [ZnCl(4)](2−) anion and a 2-{2-[4-(dimethyl­amino)­phen­yl]diazen-1-ium-1-yl}pyridinium dication. The pyridinium-N atom is syn to the azo bond which allows for the formation of an intramolecular N—H⋯N hydrogen bond. In the cry...

Descripción completa

Detalles Bibliográficos
Autores principales: Leesakul, Nararak, Runrueng, Wassana, Saithong, Saowanit, Pakawatchai, Chaveng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379178/
https://www.ncbi.nlm.nih.gov/pubmed/22719376
http://dx.doi.org/10.1107/S1600536812023689
_version_ 1782236140212846592
author Leesakul, Nararak
Runrueng, Wassana
Saithong, Saowanit
Pakawatchai, Chaveng
author_facet Leesakul, Nararak
Runrueng, Wassana
Saithong, Saowanit
Pakawatchai, Chaveng
author_sort Leesakul, Nararak
collection PubMed
description The title compound, (C(13)H(16)N(4))[ZnCl(4)], consists of a tetra­hedral [ZnCl(4)](2−) anion and a 2-{2-[4-(dimethyl­amino)­phen­yl]diazen-1-ium-1-yl}pyridinium dication. The pyridinium-N atom is syn to the azo bond which allows for the formation of an intramolecular N—H⋯N hydrogen bond. In the crystal, the cation and anion are held together by N—H⋯Cl hydrogen-bond inter­actions involving the pyridinium and diazen-1-ium N atoms. π–π stacking inter­actions occur between the pyridine and benzene rings of adjacent cations [centroid–centroid distances = 3.6270 (18) and 3.8685 (18) Å]; the stacks are parallel to the a axis.
format Online
Article
Text
id pubmed-3379178
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-33791782012-06-20 2-{2-[4-(Dimethyl­amino)­phen­yl]diazen-1-ium-1-yl}pyridinium tetra­chlorido­zincate Leesakul, Nararak Runrueng, Wassana Saithong, Saowanit Pakawatchai, Chaveng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, (C(13)H(16)N(4))[ZnCl(4)], consists of a tetra­hedral [ZnCl(4)](2−) anion and a 2-{2-[4-(dimethyl­amino)­phen­yl]diazen-1-ium-1-yl}pyridinium dication. The pyridinium-N atom is syn to the azo bond which allows for the formation of an intramolecular N—H⋯N hydrogen bond. In the crystal, the cation and anion are held together by N—H⋯Cl hydrogen-bond inter­actions involving the pyridinium and diazen-1-ium N atoms. π–π stacking inter­actions occur between the pyridine and benzene rings of adjacent cations [centroid–centroid distances = 3.6270 (18) and 3.8685 (18) Å]; the stacks are parallel to the a axis. International Union of Crystallography 2012-05-31 /pmc/articles/PMC3379178/ /pubmed/22719376 http://dx.doi.org/10.1107/S1600536812023689 Text en © Leesakul et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Leesakul, Nararak
Runrueng, Wassana
Saithong, Saowanit
Pakawatchai, Chaveng
2-{2-[4-(Dimethyl­amino)­phen­yl]diazen-1-ium-1-yl}pyridinium tetra­chlorido­zincate
title 2-{2-[4-(Dimethyl­amino)­phen­yl]diazen-1-ium-1-yl}pyridinium tetra­chlorido­zincate
title_full 2-{2-[4-(Dimethyl­amino)­phen­yl]diazen-1-ium-1-yl}pyridinium tetra­chlorido­zincate
title_fullStr 2-{2-[4-(Dimethyl­amino)­phen­yl]diazen-1-ium-1-yl}pyridinium tetra­chlorido­zincate
title_full_unstemmed 2-{2-[4-(Dimethyl­amino)­phen­yl]diazen-1-ium-1-yl}pyridinium tetra­chlorido­zincate
title_short 2-{2-[4-(Dimethyl­amino)­phen­yl]diazen-1-ium-1-yl}pyridinium tetra­chlorido­zincate
title_sort 2-{2-[4-(dimethyl­amino)­phen­yl]diazen-1-ium-1-yl}pyridinium tetra­chlorido­zincate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379178/
https://www.ncbi.nlm.nih.gov/pubmed/22719376
http://dx.doi.org/10.1107/S1600536812023689
work_keys_str_mv AT leesakulnararak 224dimethylaminophenyldiazen1ium1ylpyridiniumtetrachloridozincate
AT runruengwassana 224dimethylaminophenyldiazen1ium1ylpyridiniumtetrachloridozincate
AT saithongsaowanit 224dimethylaminophenyldiazen1ium1ylpyridiniumtetrachloridozincate
AT pakawatchaichaveng 224dimethylaminophenyldiazen1ium1ylpyridiniumtetrachloridozincate

Ejemplares similares