[μ-Bis(di-o-tolyl­phosphan­yl)methane-1:2κ(2) P:P′]nona­carbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[tris­(2-chloro­eth­yl) phosphite-3κP]-triangulo-triruthenium(0)

In the title compound, [Ru(3)(C(6)H(12)Cl(3)O(3)P)(C(29)H(30)P(2))(CO)(9)], the bis­(di-o-tolyl­phosphan­yl)methane ligand bridges one Ru—Ru bond and the monodentate phosphite ligand bonds to the third Ru atom. Both ligands are equatorial with respect to the Ru(3) triangle. Each Ru atom bears one eq...

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Detalles Bibliográficos
Autores principales: Shawkataly, Omar bin, Khan, Imthyaz Ahmed, Sirat, Siti Syaida, Quah, Ching Kheng, Fun, Hoong-Kun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379179/
https://www.ncbi.nlm.nih.gov/pubmed/22719377
http://dx.doi.org/10.1107/S1600536812023707
Descripción
Sumario:In the title compound, [Ru(3)(C(6)H(12)Cl(3)O(3)P)(C(29)H(30)P(2))(CO)(9)], the bis­(di-o-tolyl­phosphan­yl)methane ligand bridges one Ru—Ru bond and the monodentate phosphite ligand bonds to the third Ru atom. Both ligands are equatorial with respect to the Ru(3) triangle. Each Ru atom bears one equatorial and two axial terminal carbonyl ligands. The dihedral angles between the two benzene rings in the diphenyl­phosphanyl groups are 79.52 (10) and 69.88 (10)°. In the crystal, mol­ecules are linked via C—H⋯O hydrogen bonds into chains along [100].

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