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[μ-Bis(di-o-tolylphosphanyl)methane-1:2κ(2) P:P′]nonacarbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[tris(2-chloroethyl) phosphite-3κP]-triangulo-triruthenium(0)
In the title compound, [Ru(3)(C(6)H(12)Cl(3)O(3)P)(C(29)H(30)P(2))(CO)(9)], the bis(di-o-tolylphosphanyl)methane ligand bridges one Ru—Ru bond and the monodentate phosphite ligand bonds to the third Ru atom. Both ligands are equatorial with respect to the Ru(3) triangle. Each Ru atom bears one eq...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379179/ https://www.ncbi.nlm.nih.gov/pubmed/22719377 http://dx.doi.org/10.1107/S1600536812023707 |
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| author | Shawkataly, Omar bin Khan, Imthyaz Ahmed Sirat, Siti Syaida Quah, Ching Kheng Fun, Hoong-Kun |
| author_facet | Shawkataly, Omar bin Khan, Imthyaz Ahmed Sirat, Siti Syaida Quah, Ching Kheng Fun, Hoong-Kun |
| author_sort | Shawkataly, Omar bin |
| collection | PubMed |
| description | In the title compound, [Ru(3)(C(6)H(12)Cl(3)O(3)P)(C(29)H(30)P(2))(CO)(9)], the bis(di-o-tolylphosphanyl)methane ligand bridges one Ru—Ru bond and the monodentate phosphite ligand bonds to the third Ru atom. Both ligands are equatorial with respect to the Ru(3) triangle. Each Ru atom bears one equatorial and two axial terminal carbonyl ligands. The dihedral angles between the two benzene rings in the diphenylphosphanyl groups are 79.52 (10) and 69.88 (10)°. In the crystal, molecules are linked via C—H⋯O hydrogen bonds into chains along [100]. |
| format | Online Article Text |
| id | pubmed-3379179 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-33791792012-06-20 [μ-Bis(di-o-tolylphosphanyl)methane-1:2κ(2) P:P′]nonacarbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[tris(2-chloroethyl) phosphite-3κP]-triangulo-triruthenium(0) Shawkataly, Omar bin Khan, Imthyaz Ahmed Sirat, Siti Syaida Quah, Ching Kheng Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ru(3)(C(6)H(12)Cl(3)O(3)P)(C(29)H(30)P(2))(CO)(9)], the bis(di-o-tolylphosphanyl)methane ligand bridges one Ru—Ru bond and the monodentate phosphite ligand bonds to the third Ru atom. Both ligands are equatorial with respect to the Ru(3) triangle. Each Ru atom bears one equatorial and two axial terminal carbonyl ligands. The dihedral angles between the two benzene rings in the diphenylphosphanyl groups are 79.52 (10) and 69.88 (10)°. In the crystal, molecules are linked via C—H⋯O hydrogen bonds into chains along [100]. International Union of Crystallography 2012-05-31 /pmc/articles/PMC3379179/ /pubmed/22719377 http://dx.doi.org/10.1107/S1600536812023707 Text en © Shawkataly et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Shawkataly, Omar bin Khan, Imthyaz Ahmed Sirat, Siti Syaida Quah, Ching Kheng Fun, Hoong-Kun [μ-Bis(di-o-tolylphosphanyl)methane-1:2κ(2) P:P′]nonacarbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[tris(2-chloroethyl) phosphite-3κP]-triangulo-triruthenium(0) |
| title | [μ-Bis(di-o-tolylphosphanyl)methane-1:2κ(2)
P:P′]nonacarbonyl-1κ(3)
C,2κ(3)
C,3κ(3)
C-[tris(2-chloroethyl) phosphite-3κP]-triangulo-triruthenium(0) |
| title_full | [μ-Bis(di-o-tolylphosphanyl)methane-1:2κ(2)
P:P′]nonacarbonyl-1κ(3)
C,2κ(3)
C,3κ(3)
C-[tris(2-chloroethyl) phosphite-3κP]-triangulo-triruthenium(0) |
| title_fullStr | [μ-Bis(di-o-tolylphosphanyl)methane-1:2κ(2)
P:P′]nonacarbonyl-1κ(3)
C,2κ(3)
C,3κ(3)
C-[tris(2-chloroethyl) phosphite-3κP]-triangulo-triruthenium(0) |
| title_full_unstemmed | [μ-Bis(di-o-tolylphosphanyl)methane-1:2κ(2)
P:P′]nonacarbonyl-1κ(3)
C,2κ(3)
C,3κ(3)
C-[tris(2-chloroethyl) phosphite-3κP]-triangulo-triruthenium(0) |
| title_short | [μ-Bis(di-o-tolylphosphanyl)methane-1:2κ(2)
P:P′]nonacarbonyl-1κ(3)
C,2κ(3)
C,3κ(3)
C-[tris(2-chloroethyl) phosphite-3κP]-triangulo-triruthenium(0) |
| title_sort | [μ-bis(di-o-tolylphosphanyl)methane-1:2κ(2)
p:p′]nonacarbonyl-1κ(3)
c,2κ(3)
c,3κ(3)
c-[tris(2-chloroethyl) phosphite-3κp]-triangulo-triruthenium(0) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379179/ https://www.ncbi.nlm.nih.gov/pubmed/22719377 http://dx.doi.org/10.1107/S1600536812023707 |
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