catena-Poly[[[bis­(nitrato-κO)copper(II)]-bis­[μ-1,3-bis­(imidazol-1-yl)-5-methyl­benzene-κ(2) N (3):N (3′)]] dihydrate]

In the title complex, {[Cu(NO(3))(2)(C(13)H(12)N(4))(2)]·2H(2)O}(n), the Cu(II) atom is located on a crystallographic center of symmetry and adopts an N(4)O(2) octa­hedral coordination geometry with four imidazole N atoms in the equatorial sites and two O atoms in the axial sites. The dihedral angle...

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Detalles Bibliográficos
Autor principal: Liu, Guang-Xiang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379180/
https://www.ncbi.nlm.nih.gov/pubmed/22719378
http://dx.doi.org/10.1107/S1600536812023628
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author Liu, Guang-Xiang
author_facet Liu, Guang-Xiang
author_sort Liu, Guang-Xiang
collection PubMed
description In the title complex, {[Cu(NO(3))(2)(C(13)H(12)N(4))(2)]·2H(2)O}(n), the Cu(II) atom is located on a crystallographic center of symmetry and adopts an N(4)O(2) octa­hedral coordination geometry with four imidazole N atoms in the equatorial sites and two O atoms in the axial sites. The dihedral angles between the central benzene ring and the imidazole rings are 4.93 (11) and 46.08 (12)°. The 1,3-bis­(imidazol-1-yl)-5-methyl­benzene ligand is bis-monodentate, linking symmetry-related Cu(II) atoms into sheets in the bc plane. These sheets are further bridged into a three-dimensional supra­molecular structure by O—H⋯O and C—H⋯O hydrogen bonds.
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spelling pubmed-33791802012-06-20 catena-Poly[[[bis­(nitrato-κO)copper(II)]-bis­[μ-1,3-bis­(imidazol-1-yl)-5-methyl­benzene-κ(2) N (3):N (3′)]] dihydrate] Liu, Guang-Xiang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, {[Cu(NO(3))(2)(C(13)H(12)N(4))(2)]·2H(2)O}(n), the Cu(II) atom is located on a crystallographic center of symmetry and adopts an N(4)O(2) octa­hedral coordination geometry with four imidazole N atoms in the equatorial sites and two O atoms in the axial sites. The dihedral angles between the central benzene ring and the imidazole rings are 4.93 (11) and 46.08 (12)°. The 1,3-bis­(imidazol-1-yl)-5-methyl­benzene ligand is bis-monodentate, linking symmetry-related Cu(II) atoms into sheets in the bc plane. These sheets are further bridged into a three-dimensional supra­molecular structure by O—H⋯O and C—H⋯O hydrogen bonds. International Union of Crystallography 2012-05-31 /pmc/articles/PMC3379180/ /pubmed/22719378 http://dx.doi.org/10.1107/S1600536812023628 Text en © Guang-Xiang Liu 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liu, Guang-Xiang
catena-Poly[[[bis­(nitrato-κO)copper(II)]-bis­[μ-1,3-bis­(imidazol-1-yl)-5-methyl­benzene-κ(2) N (3):N (3′)]] dihydrate]
title catena-Poly[[[bis­(nitrato-κO)copper(II)]-bis­[μ-1,3-bis­(imidazol-1-yl)-5-methyl­benzene-κ(2) N (3):N (3′)]] dihydrate]
title_full catena-Poly[[[bis­(nitrato-κO)copper(II)]-bis­[μ-1,3-bis­(imidazol-1-yl)-5-methyl­benzene-κ(2) N (3):N (3′)]] dihydrate]
title_fullStr catena-Poly[[[bis­(nitrato-κO)copper(II)]-bis­[μ-1,3-bis­(imidazol-1-yl)-5-methyl­benzene-κ(2) N (3):N (3′)]] dihydrate]
title_full_unstemmed catena-Poly[[[bis­(nitrato-κO)copper(II)]-bis­[μ-1,3-bis­(imidazol-1-yl)-5-methyl­benzene-κ(2) N (3):N (3′)]] dihydrate]
title_short catena-Poly[[[bis­(nitrato-κO)copper(II)]-bis­[μ-1,3-bis­(imidazol-1-yl)-5-methyl­benzene-κ(2) N (3):N (3′)]] dihydrate]
title_sort catena-poly[[[bis­(nitrato-κo)copper(ii)]-bis­[μ-1,3-bis­(imidazol-1-yl)-5-methyl­benzene-κ(2) n (3):n (3′)]] dihydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379180/
https://www.ncbi.nlm.nih.gov/pubmed/22719378
http://dx.doi.org/10.1107/S1600536812023628
work_keys_str_mv AT liuguangxiang catenapolybisnitratokocopperiibism13bisimidazol1yl5methylbenzenek2n3n3dihydrate

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