Bis[(diphenyl­phosphanylmeth­yl)diphenyl­phosphane sulfide-κ(2) P,S]copper(I) hexa­fluoridophosphate

In the title compound, [Cu(C(25)H(22)P(2)S)(2)]PF(6), the Cu(I) atom, lying on a twofold rotation axis, adopts a distorted tetra­hedral geometry. The (diphenyl­phosphanylmeth­yl)diphenyl­phos­phane sulfide ligand coordinates to the Cu(I) atom through one S and one P atom, forming a stable five-membe...

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Detalles Bibliográficos
Autores principales: Zhang, Jing-Jing, Hu, Feng, Duan, Tai-Ke, Chen, Qun, Zhang, Qian-Feng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379181/
https://www.ncbi.nlm.nih.gov/pubmed/22719379
http://dx.doi.org/10.1107/S160053681202346X
Descripción
Sumario:In the title compound, [Cu(C(25)H(22)P(2)S)(2)]PF(6), the Cu(I) atom, lying on a twofold rotation axis, adopts a distorted tetra­hedral geometry. The (diphenyl­phosphanylmeth­yl)diphenyl­phos­phane sulfide ligand coordinates to the Cu(I) atom through one S and one P atom, forming a stable five-membered chelate ring. The P atom of the PF(6) (−) anion also lies on a twofold rotation axis.

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