Bis[(diphenyl­phosphanylmeth­yl)diphenyl­phosphane sulfide-κ(2) P,S]copper(I) hexa­fluoridophosphate

In the title compound, [Cu(C(25)H(22)P(2)S)(2)]PF(6), the Cu(I) atom, lying on a twofold rotation axis, adopts a distorted tetra­hedral geometry. The (diphenyl­phosphanylmeth­yl)diphenyl­phos­phane sulfide ligand coordinates to the Cu(I) atom through one S and one P atom, forming a stable five-membe...

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Detalles Bibliográficos
Autores principales: Zhang, Jing-Jing, Hu, Feng, Duan, Tai-Ke, Chen, Qun, Zhang, Qian-Feng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379181/
https://www.ncbi.nlm.nih.gov/pubmed/22719379
http://dx.doi.org/10.1107/S160053681202346X
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author Zhang, Jing-Jing
Hu, Feng
Duan, Tai-Ke
Chen, Qun
Zhang, Qian-Feng
author_facet Zhang, Jing-Jing
Hu, Feng
Duan, Tai-Ke
Chen, Qun
Zhang, Qian-Feng
author_sort Zhang, Jing-Jing
collection PubMed
description In the title compound, [Cu(C(25)H(22)P(2)S)(2)]PF(6), the Cu(I) atom, lying on a twofold rotation axis, adopts a distorted tetra­hedral geometry. The (diphenyl­phosphanylmeth­yl)diphenyl­phos­phane sulfide ligand coordinates to the Cu(I) atom through one S and one P atom, forming a stable five-membered chelate ring. The P atom of the PF(6) (−) anion also lies on a twofold rotation axis.
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spelling pubmed-33791812012-06-20 Bis[(diphenyl­phosphanylmeth­yl)diphenyl­phosphane sulfide-κ(2) P,S]copper(I) hexa­fluoridophosphate Zhang, Jing-Jing Hu, Feng Duan, Tai-Ke Chen, Qun Zhang, Qian-Feng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(25)H(22)P(2)S)(2)]PF(6), the Cu(I) atom, lying on a twofold rotation axis, adopts a distorted tetra­hedral geometry. The (diphenyl­phosphanylmeth­yl)diphenyl­phos­phane sulfide ligand coordinates to the Cu(I) atom through one S and one P atom, forming a stable five-membered chelate ring. The P atom of the PF(6) (−) anion also lies on a twofold rotation axis. International Union of Crystallography 2012-05-31 /pmc/articles/PMC3379181/ /pubmed/22719379 http://dx.doi.org/10.1107/S160053681202346X Text en © Zhang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Jing-Jing
Hu, Feng
Duan, Tai-Ke
Chen, Qun
Zhang, Qian-Feng
Bis[(diphenyl­phosphanylmeth­yl)diphenyl­phosphane sulfide-κ(2) P,S]copper(I) hexa­fluoridophosphate
title Bis[(diphenyl­phosphanylmeth­yl)diphenyl­phosphane sulfide-κ(2) P,S]copper(I) hexa­fluoridophosphate
title_full Bis[(diphenyl­phosphanylmeth­yl)diphenyl­phosphane sulfide-κ(2) P,S]copper(I) hexa­fluoridophosphate
title_fullStr Bis[(diphenyl­phosphanylmeth­yl)diphenyl­phosphane sulfide-κ(2) P,S]copper(I) hexa­fluoridophosphate
title_full_unstemmed Bis[(diphenyl­phosphanylmeth­yl)diphenyl­phosphane sulfide-κ(2) P,S]copper(I) hexa­fluoridophosphate
title_short Bis[(diphenyl­phosphanylmeth­yl)diphenyl­phosphane sulfide-κ(2) P,S]copper(I) hexa­fluoridophosphate
title_sort bis[(diphenyl­phosphanylmeth­yl)diphenyl­phosphane sulfide-κ(2) p,s]copper(i) hexa­fluoridophosphate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379181/
https://www.ncbi.nlm.nih.gov/pubmed/22719379
http://dx.doi.org/10.1107/S160053681202346X
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