Cargando…
Dibromido{N′-[1-(pyridin-2-yl)ethylidene]picolinohydrazide-κ(2) N′,O}cadmium
The title compound, [CdBr(2)(C(13)H(12)N(4)O)], was obtained from the reaction of Cd(NO(3))(2)·4H(2)O with methyl(pyridin-2-yl)methanone picolinoylhydrazone and sodium bromide. The Cd(2+) cation is ligated by one O atom and two N atoms of the tridentate ligand and two bromide anions, forming a Br(2...
| Autores principales: | , , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379182/ https://www.ncbi.nlm.nih.gov/pubmed/22719380 http://dx.doi.org/10.1107/S1600536812023185 |
| _version_ | 1782236141131399168 |
|---|---|
| author | Akkurt, Mehmet Khandar, Ali Akbar Tahir, Muhammad Nawaz Yazdi, Seyed Abolfazl Hosseini Afkhami, Farhad Akbari |
| author_facet | Akkurt, Mehmet Khandar, Ali Akbar Tahir, Muhammad Nawaz Yazdi, Seyed Abolfazl Hosseini Afkhami, Farhad Akbari |
| author_sort | Akkurt, Mehmet |
| collection | PubMed |
| description | The title compound, [CdBr(2)(C(13)H(12)N(4)O)], was obtained from the reaction of Cd(NO(3))(2)·4H(2)O with methyl(pyridin-2-yl)methanone picolinoylhydrazone and sodium bromide. The Cd(2+) cation is ligated by one O atom and two N atoms of the tridentate ligand and two bromide anions, forming a Br(2)CdN(2)O polyhedron with a distorted trigonal–bipyramidal coordination geometry. In the crystal, non-classical C—H⋯Br hydrogen bonds are observed. In addition, π–π stacking interactions [centroid–centroid distance = 3.7455 (19) Å] contribute to the stabilization of the crystal structure. |
| format | Online Article Text |
| id | pubmed-3379182 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-33791822012-06-20 Dibromido{N′-[1-(pyridin-2-yl)ethylidene]picolinohydrazide-κ(2) N′,O}cadmium Akkurt, Mehmet Khandar, Ali Akbar Tahir, Muhammad Nawaz Yazdi, Seyed Abolfazl Hosseini Afkhami, Farhad Akbari Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [CdBr(2)(C(13)H(12)N(4)O)], was obtained from the reaction of Cd(NO(3))(2)·4H(2)O with methyl(pyridin-2-yl)methanone picolinoylhydrazone and sodium bromide. The Cd(2+) cation is ligated by one O atom and two N atoms of the tridentate ligand and two bromide anions, forming a Br(2)CdN(2)O polyhedron with a distorted trigonal–bipyramidal coordination geometry. In the crystal, non-classical C—H⋯Br hydrogen bonds are observed. In addition, π–π stacking interactions [centroid–centroid distance = 3.7455 (19) Å] contribute to the stabilization of the crystal structure. International Union of Crystallography 2012-05-31 /pmc/articles/PMC3379182/ /pubmed/22719380 http://dx.doi.org/10.1107/S1600536812023185 Text en © Akkurt et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Akkurt, Mehmet Khandar, Ali Akbar Tahir, Muhammad Nawaz Yazdi, Seyed Abolfazl Hosseini Afkhami, Farhad Akbari Dibromido{N′-[1-(pyridin-2-yl)ethylidene]picolinohydrazide-κ(2) N′,O}cadmium |
| title | Dibromido{N′-[1-(pyridin-2-yl)ethylidene]picolinohydrazide-κ(2)
N′,O}cadmium |
| title_full | Dibromido{N′-[1-(pyridin-2-yl)ethylidene]picolinohydrazide-κ(2)
N′,O}cadmium |
| title_fullStr | Dibromido{N′-[1-(pyridin-2-yl)ethylidene]picolinohydrazide-κ(2)
N′,O}cadmium |
| title_full_unstemmed | Dibromido{N′-[1-(pyridin-2-yl)ethylidene]picolinohydrazide-κ(2)
N′,O}cadmium |
| title_short | Dibromido{N′-[1-(pyridin-2-yl)ethylidene]picolinohydrazide-κ(2)
N′,O}cadmium |
| title_sort | dibromido{n′-[1-(pyridin-2-yl)ethylidene]picolinohydrazide-κ(2)
n′,o}cadmium |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379182/ https://www.ncbi.nlm.nih.gov/pubmed/22719380 http://dx.doi.org/10.1107/S1600536812023185 |
| work_keys_str_mv | AT akkurtmehmet dibromidon1pyridin2ylethylidenepicolinohydrazidek2nocadmium AT khandaraliakbar dibromidon1pyridin2ylethylidenepicolinohydrazidek2nocadmium AT tahirmuhammadnawaz dibromidon1pyridin2ylethylidenepicolinohydrazidek2nocadmium AT yazdiseyedabolfazlhosseini dibromidon1pyridin2ylethylidenepicolinohydrazidek2nocadmium AT afkhamifarhadakbari dibromidon1pyridin2ylethylidenepicolinohydrazidek2nocadmium |