Poly[(μ(3)-quinoline-6-carboxyl­ato-κ(3) N:O:O′)silver(I)]

In the title coordination polymer, [Ag(C(10)H(6)NO(2))](n), the Ag(I) cation is coordinated by two O atoms and one N atom from three 6-quinoline­carboxyl­ate anions in a distorted T-shaped AgNO(2) geometry, in which the O—Ag—O angle is 160.44 (9)°. The 6-quinoline­carboxyl­ate anion bridges three Ag...

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Autores principales: Yeh, Chun-Wei, Jong, Ay, Tsou, Chi-Hui, Huang, Fu-Chang, Suen, Maw-Cherng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379188/
https://www.ncbi.nlm.nih.gov/pubmed/22719386
http://dx.doi.org/10.1107/S1600536812023835
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author Yeh, Chun-Wei
Jong, Ay
Tsou, Chi-Hui
Huang, Fu-Chang
Suen, Maw-Cherng
author_facet Yeh, Chun-Wei
Jong, Ay
Tsou, Chi-Hui
Huang, Fu-Chang
Suen, Maw-Cherng
author_sort Yeh, Chun-Wei
collection PubMed
description In the title coordination polymer, [Ag(C(10)H(6)NO(2))](n), the Ag(I) cation is coordinated by two O atoms and one N atom from three 6-quinoline­carboxyl­ate anions in a distorted T-shaped AgNO(2) geometry, in which the O—Ag—O angle is 160.44 (9)°. The 6-quinoline­carboxyl­ate anion bridges three Ag(+) cations, forming a nearly planar polymeric sheet parallel to (101). The distance between Ag(+) cations bridged by the carboxyl group is 2.9200 (5) Å. In the crystal, π–π stacking is observed between parallel quinoline ring systems, the centroid–centroid distance being 3.7735 (16) Å.
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spelling pubmed-33791882012-06-20 Poly[(μ(3)-quinoline-6-carboxyl­ato-κ(3) N:O:O′)silver(I)] Yeh, Chun-Wei Jong, Ay Tsou, Chi-Hui Huang, Fu-Chang Suen, Maw-Cherng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title coordination polymer, [Ag(C(10)H(6)NO(2))](n), the Ag(I) cation is coordinated by two O atoms and one N atom from three 6-quinoline­carboxyl­ate anions in a distorted T-shaped AgNO(2) geometry, in which the O—Ag—O angle is 160.44 (9)°. The 6-quinoline­carboxyl­ate anion bridges three Ag(+) cations, forming a nearly planar polymeric sheet parallel to (101). The distance between Ag(+) cations bridged by the carboxyl group is 2.9200 (5) Å. In the crystal, π–π stacking is observed between parallel quinoline ring systems, the centroid–centroid distance being 3.7735 (16) Å. International Union of Crystallography 2012-05-31 /pmc/articles/PMC3379188/ /pubmed/22719386 http://dx.doi.org/10.1107/S1600536812023835 Text en © Yeh et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yeh, Chun-Wei
Jong, Ay
Tsou, Chi-Hui
Huang, Fu-Chang
Suen, Maw-Cherng
Poly[(μ(3)-quinoline-6-carboxyl­ato-κ(3) N:O:O′)silver(I)]
title Poly[(μ(3)-quinoline-6-carboxyl­ato-κ(3) N:O:O′)silver(I)]
title_full Poly[(μ(3)-quinoline-6-carboxyl­ato-κ(3) N:O:O′)silver(I)]
title_fullStr Poly[(μ(3)-quinoline-6-carboxyl­ato-κ(3) N:O:O′)silver(I)]
title_full_unstemmed Poly[(μ(3)-quinoline-6-carboxyl­ato-κ(3) N:O:O′)silver(I)]
title_short Poly[(μ(3)-quinoline-6-carboxyl­ato-κ(3) N:O:O′)silver(I)]
title_sort poly[(μ(3)-quinoline-6-carboxyl­ato-κ(3) n:o:o′)silver(i)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379188/
https://www.ncbi.nlm.nih.gov/pubmed/22719386
http://dx.doi.org/10.1107/S1600536812023835
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