Poly[bis­(μ(6)-benzene-1,3,5-tricarboxyl­ato-κ(7) O (1),O (1′):O (1′):O (3):O (3′):O (5):O (5′))tetra­kis­(dimethyl­formamide-κO)trimagnesium(II)]

The asymmetric unit of the polymeric title compound, [Mg(3)(C(9)H(3)O(6))(2)(C(3)H(7)NO)(4)](n), contains three Mg(II) ions bridged by carboxyl­ate O atoms from two fully deprotonated benzene-1,3,5-tricarboxyl­ate (BTC) trianions and four metal-coordinated dimethyl­formamide (DMF) mol­ecules. One Mg...

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Detalles Bibliográficos
Autores principales: Łuczyńska-Szymczak, Katarzyna, Starosta, Wojciech, Leciejewicz, Janusz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379189/
https://www.ncbi.nlm.nih.gov/pubmed/22719387
http://dx.doi.org/10.1107/S1600536812023240
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author Łuczyńska-Szymczak, Katarzyna
Starosta, Wojciech
Leciejewicz, Janusz
author_facet Łuczyńska-Szymczak, Katarzyna
Starosta, Wojciech
Leciejewicz, Janusz
author_sort Łuczyńska-Szymczak, Katarzyna
collection PubMed
description The asymmetric unit of the polymeric title compound, [Mg(3)(C(9)H(3)O(6))(2)(C(3)H(7)NO)(4)](n), contains three Mg(II) ions bridged by carboxyl­ate O atoms from two fully deprotonated benzene-1,3,5-tricarboxyl­ate (BTC) trianions and four metal-coordinated dimethyl­formamide (DMF) mol­ecules. One Mg(II) ion is octa­hedrally coordinated by six carboxyl­ate O atoms. The other two cations are each octa­hedrally coordinated by four carboxyl­ate O atoms and two O atoms donated by two DMF mol­ecules: in one, the DMF mol­ecules are cis and in the other they are trans. The three Mg(II) octa­hedra form clusters, which are bridged by the BTC trianions, generating a three-dimensional structure.
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spelling pubmed-33791892012-06-20 Poly[bis­(μ(6)-benzene-1,3,5-tricarboxyl­ato-κ(7) O (1),O (1′):O (1′):O (3):O (3′):O (5):O (5′))tetra­kis­(dimethyl­formamide-κO)trimagnesium(II)] Łuczyńska-Szymczak, Katarzyna Starosta, Wojciech Leciejewicz, Janusz Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the polymeric title compound, [Mg(3)(C(9)H(3)O(6))(2)(C(3)H(7)NO)(4)](n), contains three Mg(II) ions bridged by carboxyl­ate O atoms from two fully deprotonated benzene-1,3,5-tricarboxyl­ate (BTC) trianions and four metal-coordinated dimethyl­formamide (DMF) mol­ecules. One Mg(II) ion is octa­hedrally coordinated by six carboxyl­ate O atoms. The other two cations are each octa­hedrally coordinated by four carboxyl­ate O atoms and two O atoms donated by two DMF mol­ecules: in one, the DMF mol­ecules are cis and in the other they are trans. The three Mg(II) octa­hedra form clusters, which are bridged by the BTC trianions, generating a three-dimensional structure. International Union of Crystallography 2012-05-31 /pmc/articles/PMC3379189/ /pubmed/22719387 http://dx.doi.org/10.1107/S1600536812023240 Text en © Łuczyńska-Szymczak et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Łuczyńska-Szymczak, Katarzyna
Starosta, Wojciech
Leciejewicz, Janusz
Poly[bis­(μ(6)-benzene-1,3,5-tricarboxyl­ato-κ(7) O (1),O (1′):O (1′):O (3):O (3′):O (5):O (5′))tetra­kis­(dimethyl­formamide-κO)trimagnesium(II)]
title Poly[bis­(μ(6)-benzene-1,3,5-tricarboxyl­ato-κ(7) O (1),O (1′):O (1′):O (3):O (3′):O (5):O (5′))tetra­kis­(dimethyl­formamide-κO)trimagnesium(II)]
title_full Poly[bis­(μ(6)-benzene-1,3,5-tricarboxyl­ato-κ(7) O (1),O (1′):O (1′):O (3):O (3′):O (5):O (5′))tetra­kis­(dimethyl­formamide-κO)trimagnesium(II)]
title_fullStr Poly[bis­(μ(6)-benzene-1,3,5-tricarboxyl­ato-κ(7) O (1),O (1′):O (1′):O (3):O (3′):O (5):O (5′))tetra­kis­(dimethyl­formamide-κO)trimagnesium(II)]
title_full_unstemmed Poly[bis­(μ(6)-benzene-1,3,5-tricarboxyl­ato-κ(7) O (1),O (1′):O (1′):O (3):O (3′):O (5):O (5′))tetra­kis­(dimethyl­formamide-κO)trimagnesium(II)]
title_short Poly[bis­(μ(6)-benzene-1,3,5-tricarboxyl­ato-κ(7) O (1),O (1′):O (1′):O (3):O (3′):O (5):O (5′))tetra­kis­(dimethyl­formamide-κO)trimagnesium(II)]
title_sort poly[bis­(μ(6)-benzene-1,3,5-tricarboxyl­ato-κ(7) o (1),o (1′):o (1′):o (3):o (3′):o (5):o (5′))tetra­kis­(dimethyl­formamide-κo)trimagnesium(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379189/
https://www.ncbi.nlm.nih.gov/pubmed/22719387
http://dx.doi.org/10.1107/S1600536812023240
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