catena-Poly[[bis­(nitrato-κO)cadmium]bis­[μ-1,3-bis­[(1H-1,2,4-triazol-1-yl)meth­yl]benzene-κ(2) N (4):N (4′)]]

In the title compound, [Cd(NO(3))(2)(C(12)H(12)N(6))(2)](n), the Cd(II) cation is located on an inversion center and is six-coordinated by four N atoms from four 1,3-bis­[(1H-1,2,4-triazol-1-yl)meth­yl]benzene (L) ligands and two O atoms from two nitrate anions in a slightly distorted octa­hedral ge...

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Detalles Bibliográficos
Autores principales: Zhang, Hong-Kun, Wang, Xin, Wang, Shuai, Wang, Xiao-Dan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379191/
https://www.ncbi.nlm.nih.gov/pubmed/22719389
http://dx.doi.org/10.1107/S1600536812023288
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author Zhang, Hong-Kun
Wang, Xin
Wang, Shuai
Wang, Xiao-Dan
author_facet Zhang, Hong-Kun
Wang, Xin
Wang, Shuai
Wang, Xiao-Dan
author_sort Zhang, Hong-Kun
collection PubMed
description In the title compound, [Cd(NO(3))(2)(C(12)H(12)N(6))(2)](n), the Cd(II) cation is located on an inversion center and is six-coordinated by four N atoms from four 1,3-bis­[(1H-1,2,4-triazol-1-yl)meth­yl]benzene (L) ligands and two O atoms from two nitrate anions in a slightly distorted octa­hedral geometry. The ligands link different Cd(II) ions into a ribbon-like structure along [001]. Two O atoms of the nitrate anion are disordered over two sets of sites with site occupancies of 0.575 (8) and 0.425 (8).
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spelling pubmed-33791912012-06-20 catena-Poly[[bis­(nitrato-κO)cadmium]bis­[μ-1,3-bis­[(1H-1,2,4-triazol-1-yl)meth­yl]benzene-κ(2) N (4):N (4′)]] Zhang, Hong-Kun Wang, Xin Wang, Shuai Wang, Xiao-Dan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cd(NO(3))(2)(C(12)H(12)N(6))(2)](n), the Cd(II) cation is located on an inversion center and is six-coordinated by four N atoms from four 1,3-bis­[(1H-1,2,4-triazol-1-yl)meth­yl]benzene (L) ligands and two O atoms from two nitrate anions in a slightly distorted octa­hedral geometry. The ligands link different Cd(II) ions into a ribbon-like structure along [001]. Two O atoms of the nitrate anion are disordered over two sets of sites with site occupancies of 0.575 (8) and 0.425 (8). International Union of Crystallography 2012-05-31 /pmc/articles/PMC3379191/ /pubmed/22719389 http://dx.doi.org/10.1107/S1600536812023288 Text en © Zhang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Hong-Kun
Wang, Xin
Wang, Shuai
Wang, Xiao-Dan
catena-Poly[[bis­(nitrato-κO)cadmium]bis­[μ-1,3-bis­[(1H-1,2,4-triazol-1-yl)meth­yl]benzene-κ(2) N (4):N (4′)]]
title catena-Poly[[bis­(nitrato-κO)cadmium]bis­[μ-1,3-bis­[(1H-1,2,4-triazol-1-yl)meth­yl]benzene-κ(2) N (4):N (4′)]]
title_full catena-Poly[[bis­(nitrato-κO)cadmium]bis­[μ-1,3-bis­[(1H-1,2,4-triazol-1-yl)meth­yl]benzene-κ(2) N (4):N (4′)]]
title_fullStr catena-Poly[[bis­(nitrato-κO)cadmium]bis­[μ-1,3-bis­[(1H-1,2,4-triazol-1-yl)meth­yl]benzene-κ(2) N (4):N (4′)]]
title_full_unstemmed catena-Poly[[bis­(nitrato-κO)cadmium]bis­[μ-1,3-bis­[(1H-1,2,4-triazol-1-yl)meth­yl]benzene-κ(2) N (4):N (4′)]]
title_short catena-Poly[[bis­(nitrato-κO)cadmium]bis­[μ-1,3-bis­[(1H-1,2,4-triazol-1-yl)meth­yl]benzene-κ(2) N (4):N (4′)]]
title_sort catena-poly[[bis­(nitrato-κo)cadmium]bis­[μ-1,3-bis­[(1h-1,2,4-triazol-1-yl)meth­yl]benzene-κ(2) n (4):n (4′)]]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379191/
https://www.ncbi.nlm.nih.gov/pubmed/22719389
http://dx.doi.org/10.1107/S1600536812023288
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