Bis(triethyl­ammonium) tetra­chlorido­cobaltate(II)

The crystal structure of the title compound, (C(6)H(16)N)(2)[CoCl(4)], is comprised of a tetrahedral [CoCl(4)](2−) anion and two independent triethyl­ammonium cations. The latter are featureless while the [CoCl(4)](2−) anion exhibits typical Co—Cl bond lengths [2.2428 (15)–2.2847 (16) Å] and a Cl—Co...

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Detalles Bibliográficos
Autores principales: Azadbakht, Reza, Hadadzadeh, Hassan, Amiri Rudbari, Hadi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379194/
https://www.ncbi.nlm.nih.gov/pubmed/22719392
http://dx.doi.org/10.1107/S1600536812022441
Descripción
Sumario:The crystal structure of the title compound, (C(6)H(16)N)(2)[CoCl(4)], is comprised of a tetrahedral [CoCl(4)](2−) anion and two independent triethyl­ammonium cations. The latter are featureless while the [CoCl(4)](2−) anion exhibits typical Co—Cl bond lengths [2.2428 (15)–2.2847 (16) Å] and a Cl—Co—Cl angular range of 107.58 (6)–112.73 (7)°. In the crystal, N—H⋯Cl hydrogen bonds between the two crystallographically independent cations and the [CoCl(4)](2−) anion generate discrete ion triplets. The two Co—Cl bonds involved in these inter­actions are slightly longer than the remaining two.

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