Bis(triethyl­ammonium) tetra­chlorido­cobaltate(II)

The crystal structure of the title compound, (C(6)H(16)N)(2)[CoCl(4)], is comprised of a tetrahedral [CoCl(4)](2−) anion and two independent triethyl­ammonium cations. The latter are featureless while the [CoCl(4)](2−) anion exhibits typical Co—Cl bond lengths [2.2428 (15)–2.2847 (16) Å] and a Cl—Co...

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Detalles Bibliográficos
Autores principales: Azadbakht, Reza, Hadadzadeh, Hassan, Amiri Rudbari, Hadi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379194/
https://www.ncbi.nlm.nih.gov/pubmed/22719392
http://dx.doi.org/10.1107/S1600536812022441
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author Azadbakht, Reza
Hadadzadeh, Hassan
Amiri Rudbari, Hadi
author_facet Azadbakht, Reza
Hadadzadeh, Hassan
Amiri Rudbari, Hadi
author_sort Azadbakht, Reza
collection PubMed
description The crystal structure of the title compound, (C(6)H(16)N)(2)[CoCl(4)], is comprised of a tetrahedral [CoCl(4)](2−) anion and two independent triethyl­ammonium cations. The latter are featureless while the [CoCl(4)](2−) anion exhibits typical Co—Cl bond lengths [2.2428 (15)–2.2847 (16) Å] and a Cl—Co—Cl angular range of 107.58 (6)–112.73 (7)°. In the crystal, N—H⋯Cl hydrogen bonds between the two crystallographically independent cations and the [CoCl(4)](2−) anion generate discrete ion triplets. The two Co—Cl bonds involved in these inter­actions are slightly longer than the remaining two.
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spelling pubmed-33791942012-06-20 Bis(triethyl­ammonium) tetra­chlorido­cobaltate(II) Azadbakht, Reza Hadadzadeh, Hassan Amiri Rudbari, Hadi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The crystal structure of the title compound, (C(6)H(16)N)(2)[CoCl(4)], is comprised of a tetrahedral [CoCl(4)](2−) anion and two independent triethyl­ammonium cations. The latter are featureless while the [CoCl(4)](2−) anion exhibits typical Co—Cl bond lengths [2.2428 (15)–2.2847 (16) Å] and a Cl—Co—Cl angular range of 107.58 (6)–112.73 (7)°. In the crystal, N—H⋯Cl hydrogen bonds between the two crystallographically independent cations and the [CoCl(4)](2−) anion generate discrete ion triplets. The two Co—Cl bonds involved in these inter­actions are slightly longer than the remaining two. International Union of Crystallography 2012-05-31 /pmc/articles/PMC3379194/ /pubmed/22719392 http://dx.doi.org/10.1107/S1600536812022441 Text en © Azadbakht et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Azadbakht, Reza
Hadadzadeh, Hassan
Amiri Rudbari, Hadi
Bis(triethyl­ammonium) tetra­chlorido­cobaltate(II)
title Bis(triethyl­ammonium) tetra­chlorido­cobaltate(II)
title_full Bis(triethyl­ammonium) tetra­chlorido­cobaltate(II)
title_fullStr Bis(triethyl­ammonium) tetra­chlorido­cobaltate(II)
title_full_unstemmed Bis(triethyl­ammonium) tetra­chlorido­cobaltate(II)
title_short Bis(triethyl­ammonium) tetra­chlorido­cobaltate(II)
title_sort bis(triethyl­ammonium) tetra­chlorido­cobaltate(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379194/
https://www.ncbi.nlm.nih.gov/pubmed/22719392
http://dx.doi.org/10.1107/S1600536812022441
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